32555-96-7Relevant articles and documents
Synthesis and catalytic activities of 1-alkoxycarbonyl- and 1-carbamoylmethyl-5-phenyl-3-aryl-3H-imidazol-1-yliden-Pd(II) complexes
Koruk?u, Meliha ?etin,Co?kun, Necdet
, p. 47 - 56 (2017)
4-Phenyl-1-aryl-1H-imidazoles were reacted with α-haloesters and amides to give the corresponding imidazolium salts. The latter were used as starting materials for the synthesis of Pd(NHC) complexes. The catalytic activities of the newly prepared compounds were screened in a model coupling reaction. 1-Alkoxycarbonyl-5-phenyl-3-aryl-3H-imidazol-1-yliden-Pd(II) were shown to be better catalyst than the 1-carbamoylmethyl-5-phenyl-3-aryl-3H-imidazol-1-yliden-Pd(II) complexes. The catalysts were shown to be insensitive to the air oxygen and water.
Efficient and ligand free palladium catalyst for Suzuki and Heck cross-coupling reactions
Luo, Bin,Wang, Jiaqing,Ge, Danhua,Li, Xinming,Cao, Xueqin,Pan, Yue,Gu, Hongwei
, p. 1310 - 1314,5 (2014)
A simple and efficient system for Suzuki cross-coupling reactions was developed using a ligandless catalyst of Pd nanoclusters generated in situ from Pd(acac)2. The cross-coupling reactions proceeded under mild reaction conditions with a high reaction rate (5 min) to give various biaryls in high yields. The system also exhibited catalytic potential for Heck reaction between aryl bromides and styrene.
5-Nitrobenzimidazole containing Pd(II)catalyzed C[sbnd]C cross-coupling reactions: The effect of the N-substituent of the benzimidazole structure on catalyst activity
Buldurun, Kenan,?zdemir, ?smail
, p. 172 - 177 (2019)
A series of Pd(II)complexes (1a-e)were successfully synthesized by reaction of N-substituted 5-nitrobenzimidazole with [PdCl2(CNCH3)2]in toluene under argon reflux condition. Their catalytic activity in the Suzuki-Miyaura
Microwave-assisted synthesis of novel perimidinium salts as N-heterocyclic carbene precursors: Involvement in palladium-catalyzed cross-coupling reactions
Onar, Gulnihan,Karatas, Mert Olgun,Alici, Bülent,Cetinkaya, Engin
, p. 563 - 567 (2015)
[Figure not available: see fulltext.] In the current study, five novel perimidinium chlorides were synthesized in good yields by reaction of 1-(3-methylbenzyl)perimidine with five different alkyl chlorides under microwave irradiation in 30 minutes. Synthe
Synthesis and catalytic application of palladium complexes with picoline-functionalized benzimidazolin-2-ylidene ligands
Jahnke, Mareike C.,Pape, Tania,Hahn, F. Ekkehardt
, p. 1960 - 1969 (2009)
The picoline-functionalized benzimidazolium salts N-alkyl- N'-picolylbenzimidazolium bromide [alkyl = methyl (1), ethyl (2), n-propyl (3), n-butyl (4)] and the dipicoline-function-alized benzimidazolium bromide 5 have been synthesized. Reaction of the sal
Palladium Loaded Dendronized Polymer as Efficient Polymeric Sustainable Catalyst for Heck Coupling Reaction
Hiba, K.,Krishna, G. Anjali,Prathapan, S.,Sreekumar, K.
, (2021/08/18)
The palladium incorporated amine-functionalized dendronized polymer was synthesized by the addition of palladium acetate to dendronized polymer in methanol at room temperature. Palladium species are immobilized onto the dendritic structure by their coordination with amino functional groups. The newly developed dendritic system showed high palladium content in the low generation level itself, which was found to be 4.19?mmol/g. This was fairly higher than, the other palladium-based catalysts. Energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy, UV–Visible spectroscopy, and X-ray photoelectron spectroscopy were used to confirm the successful synthesis of the new catalyst. It was used as a homogeneous palladium catalyst for Heck coupling reaction between olefins and differently substituted aryl halides and the products were isolated in high yield. The products isolated were in trans configuration, which indicated the selectivity of the newly developed catalytic system. Also, this catalyst system was reused up to nine times without a significant decrease in its catalytic activity. The easy accessibility of catalytic sites, stability, resistance to metal leaching, high catalytic activity and remarkable stereoselectivity with a low amount of catalyst are all due to the dendritic support. The docking study was carried out for all the stilbene derivatives obtained by the Heck coupling reaction against DprE1 protein to study its potential antitubercular activity. All the compounds displayed superior docking score values over the range ??6.5 to ??8.2?kcal/mol, compared to the standard drug isoniazid with docking score of ??6.1?kcal/mol against DprE1. Graphic Abstract: [Figure not available: see fulltext.]
Coordination from Heteroscorpionate Ligand Towards Pd(II) via Pd???Hδ?C(sp3) Interaction: Structural and Catalytic Studies
Castillo-Moreno, Miguel ángel,Cruz-Borbolla, Julián,González-Montiel, Simplicio,Ignacio Sandoval-Chávez, César,Manuel Vásquez-Pérez, José,Mendoza-Espinosa, Daniel,Salazar-Pereda, Verónica
supporting information, p. 2661 - 2668 (2021/07/06)
The coordination ability of the heteroscorpionate ligand 2,2-bis(3,5-dimethylpyrazol-1-yl)-1-p-tolylethanol (1) towards palladium (II) dihalides was evaluated. The structures of the respective palladium complexes (2 and 3) were elucidated in solution by NMR spectroscopy, and their molecular structures were established by single crystal X-ray diffraction analyses. Both studies revealed the existence of Pd???Hδ?C(sp3) anagostic interactions. The molecular structure of complexes 2 and 3 displays coordination of ligand 1 to palladium in a κ3-NNH tridentate fashion via two nitrogen atoms and one δ-anagostic H???Pd interaction. The metal center exhibits a square pyramidal geometry. The distances of anagostic Hδ???Pd interactions ranged from 2.566 to 2.576 ?. The δ-anagostic H???Pd interactions in complexes 2 and 3 were also identified by Bader's quantum theory of atoms in molecules (QTAIM) and non-covalent interaction (NCI) analysis. The catalytic efficiencies of complexes 2 and 3 in the Suzuki-Miyaura cross-coupling reactions were evaluated and the results showed that palladium (II) dibromide complex is the most efficient of the series. Complex 3 was also evaluated in Mizoroki-Heck cross-coupling reactions.
