3315-16-0Relevant articles and documents
Fixation of CO2 by magnesium cations: A reinterpretation
Phull, Harminder,Alberti, Davide,Korobkov, Ilia,Gambarotta, Sandro,Budzelaar, Peter H. M.
, p. 5331 - 5334 (2006)
(Chemical Equation Presented) OCO or NCO? The case of irreversible CO 2 coordination to Mg cations has been revisited and reinterpreted as a more straightforward case of reaction of CO2 with silazanate ligands and formation of coordinated NCO ligands on the basis of DFT calculations, NMR, and chemical-degradation experiments.
Davis, T. L.,Logan, A. V.
, p. 2493 - 2499 (1928)
Billmann, J.,Kovacs, G.,Otto, A.
, p. 153 - 173 (1980)
VIBRATIONAL STUDY ON AgNCO SINGLE CRYSTAL
Popitsch, A.,Nachbaur, E.,Fritzer, H. P.
, p. 41 - 46 (1986)
AgNCO shows polymorphic behaviour as revealed by X-ray studies.In this communication we present single crystal IR transmission spectra of the well established a-form.Under certain preparation conditions a new form (b-form) was isolated.Powder Raman and X-ray data are presented and discussed comparatively.A suggestion of order-dis-order appearance in the anionic lattice is made.
Synthesis and structures of triorganotelluronium pseudohalides
Klapoetke, Thomas M.,Krumm, Burkhard,Mayer, Peter,Piotrowski, Holger,Schwab, Ingo,Vogt, Martin
, p. 2701 - 2709 (2007/10/03)
The syntheses of [(CH3)3Te]X {X = N3 (1), OCN (2), SCN (3), SeCN (4), [Ag(CN)2] (5)} and [(C6H5)3Te]X {X = N3 (6), SeCN (7), [Ag(CN)2] (8)}, their NMR spectroscopic data, vibrational spectra and single crystal structures are described. Compounds 1-4 are the first trimethyltelluronium pseudohalides, while the known compounds 6 and 7 have been prepared for completion of their analytical and structural properties. The occurrence of intermolecular Te···N, Te···O, Te···S and Te···Se contacts is thoroughly studied. The dicyanoargentates 5 and 8 were obtained in an attempt to prepare telluronium cyanides. Low-temperature 13C NMR spectroscopy of the [Ag(CN)2]- ion in solution has been carried out, with determination of the 13C-107/109Ag coupling. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.
