3324-58-1

Basic information

• Product Name: Sodium 2,4,6-trinitrophenate
• Synonyms: Sodium 2,4,6-trinitrophenate;Sodium picrate;Sodium 2,4,6-trinitrophenolate;EZNA KIT MAG-BIND SOIL DNA
• CAS NO: 3324-58-1
• Molecular Formula: C₆H₂N₃O₇*Na
• Molecular Weight: 251.08575
• EINECS: 222-038-9
• Mol File: 3324-58-1.mol
• Article Data: 20

Chemical Properties

• Boiling Point: 303.6°Cat760mmHg
• Flash Point: 133.9°C
• Appearance: /
• Density: 1.856g/cm³
• Vapor Pressure: 0.000514mmHg at 25°C
• CAS DataBase Reference: Sodium 2,4,6-trinitrophenate(CAS DataBase Reference)
• NIST Chemistry Reference: Sodium 2,4,6-trinitrophenate(3324-58-1)
• EPA Substance Registry System: Sodium 2,4,6-trinitrophenate(3324-58-1)

Safety Data

• Hazardous Substances Data: 3324-58-1(Hazardous Substances Data)

Usage

General Description

Sodium 2,4,6-trinitrophenate is a chemical compound consisting of sodium and the 2,4,6-trinitrophenate anion. It is commonly used as a reagent in analytical chemistry for the determination of various metal ions. Sodium 2,4,6-trinitrophenate is a yellow to orange crystalline solid that is insoluble in water but soluble in ethanol and acetone. It has a wide range of applications, including as a colorimetric reagent for the detection of zinc, and as a precursor for the synthesis of other organic compounds. However, it is also classified as an explosive and can be hazardous if mishandled.

InChI:InChI=1/C6H3N3O7.Na/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16;/h1-2,10H;/q;+1/p-1

Upstream product

• 124-41-4 sodium methylate 
• 3698-53-1 1,2,3,5-tetranitrobenzene 
• 99-35-4 1,3,5-trinitrobenzene 
• 88-88-0 2,4,6-trinitrochlorobenzene 
• 364-44-3 picryl fluoride 
• 4185-53-9 picryl bromide 
• 4436-27-5 picryl iodide 
• 4732-14-3 2,4,6-trinitro-phenetole 
• 115828-60-9 (E)-O-Picrylbenzaldoxime 
• 115828-61-0 4-methoxy-benzaldehyde-(O-picryl-seqtrans-oxime ) 
• 115828-63-2 4-nitro-benzaldehyde-(O-picryl-seqtrans-oxime ) 
• 107047-08-5 Sodium 1,1-dimethoxy-2,4,6-trinitrocyclohexadienate-2,5 
• 127-09-3 sodium acetate 
• 606-35-9 1-methoxy-2,4,6-trinitrobenzene 

Downstream Products

• 109500-56-3 1,2-dihydro-quinolizinylium; picrate 
• 650-51-1 sodium trichloroacetate 
• 139554-54-4 2-(2,4,6-Trinitro-phenoxy)-propionyl chloride 
• 134145-69-0 1-Carbazol-9-yl-2-(2,4,6-trinitro-phenoxy)-ethanone 
• 134145-77-0 1-Carbazol-9-yl-2-(2,4,6-trinitro-phenoxy)-propan-1-one 

Relevant articles and documents

Effect of solvating additives on anion-exchange extraction of trichloroacetate anions from aqueous solutions with trinonyloctadecylammonium picrate in toluene

The solvation effect of trifluoroacetophenone derivatives on anion-exchange extraction of trichloroacetate anions from aqueous phase with trinonyloctadecylammonium picrate in toluene was studied. Pleiades Publishing, Inc., 2006.

Biferrocene triazole ligand and ion type metal complex and preparation method thereof

The invention discloses a biferrocene triazole ligand and an ion type metal complex and a preparation method thereof. The biferrocene triazole ligand has a formula shown in the description; the energy-containing ion type metal complex with the ligand has a formula shown in the description, wherein in the formula, M is Cu, Co, Ni, Mn, Zn or Pb; when the L is the carbazotic acid monovalence anion, m is 1, and n is 4; when the L is styphnic acid diatomic anion, m is 1, and n is 2; when the L is the trinitrophloroglucinol trivalent anion, m is 3, and n is 4; r is the number of free water molecules in the compelx. The complex provided by the invention is not liable to volatilize under the natural condition; the thermal stability is high; high generation heat and combustion heat are realized; high combustion catalysis performance is realized on ammonium perchlorate. The preparation method of the complex has the advantages that the operation is simple and convenient; the target product yield is high.

A study of C-F···M+ interaction: Alkali metal complexes of the fluorine-containing cage compound

The C-F···M+ interaction was investigated by employing a cage compound 1 that has four fluorobenzene units. The NMR (1H, 13C, and 19F) spectra and X-ray crystallographic analyses of 1 and its metal complexes showed clear evidence of the interaction. Short C-F···M+ distances (CF···K+, 2.755 and 2.727 A; C-F···Cs+ 2.944 and 2.954 A) were observed in the crystalline state of K+ ? 1 and Cs+ ? 1. Furthermore, the C-F bond lengths were elongated by the interaction with the metal cations. By calculating Brown's bond valence, it is shown that the contribution of the C-F unit to cation binding is comparable or greater than the ether oxygen in the crystalline state. Representative spectroscopic changes implying the C-F···M+ interaction were observed in the NMR (1H, 13C, and 19F) spectra. In particular, 133Cs-19F spin coupling (J = 54.9 Hz) was observed in the Cs+ complex.