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3347-22-6

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3347-22-6 Usage

Description

Dithianone is an anthraquinone derivative, used as a fungicide. With cymoxanil, it is contained in Aktuan. Cases have been sparsely reported for agricultural workers.

History

The ethylenebisdithiocarbamates were rediscovered in 1945 when Dimond et al. (2) reported a “new water soluble protectant fungicide.” The parent compound, disodium ethylenebisdithiocarbamate, was highly soluble in water and was unstable in air, and it might have been only a laboratory curiosity and remained unnoticed but for the applications developed by Heuberger and Manns (3), who stabilized it by converting it into zinc salt by the addition of zinc sulfate–lime mixture. This was followed by the introduction of zineb as fungicide by the Rohm and Haas Company, USA. The same phenomenon was later confirmed by Barratt and Horsfall (4), who attributed the stabilizing effect as due to zinc salt formation. From the numerous compounds suggested by Hester (5), only disodium ethylenebisdithiocarbamate and its zinc and manganese salts are largely accepted for practical application. Research on these dithiocarbamates led to some promising variants.

Uses

Fungicide.

Definition

ChEBI: A naphthodithiin that is 5,10-dioxo-5,10-dihydronaphtho[2,3-b][1,4]dithiin which is substituted by nitrile groups at positions 2 and 3. It is a broad spectrum fungicide used to control scab, downy mildew, rust, and leaf spot in the commercial rowing of grapes and other fruit, citrus, coffee, and vegetables.

Agricultural Uses

Fungicide: Fungicide used to control certain mildews. A seed dressing; used to attack foliar diseases of fruits (pome, stone, etc,), coffeee, wine, and vegetables. Not currently registered for use in the U.S. Approved for use in most EU countries.

Trade name

DELAN?; DELAN-COL?; DELAN 70WG?; DITHIANON FLOWABLE?; DITHIANONWG?; IT 931?; MV 119A?; STAUFFER MV-119A?; THYNON?

Contact allergens

Dithianon is an anthraquinone derivative, used as a fungicide agent. With cymoxanil, it is contained in Aktuan. Cases in agricultural workers were reported sparsely.

Check Digit Verification of cas no

The CAS Registry Mumber 3347-22-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,3,4 and 7 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 3347-22:
(6*3)+(5*3)+(4*4)+(3*7)+(2*2)+(1*2)=76
76 % 10 = 6
So 3347-22-6 is a valid CAS Registry Number.
InChI:InChI=1/C14H4N2O2S2/c15-5-9-10(6-16)20-14-12(18)8-4-2-1-3-7(8)11(17)13(14)19-9/h1-4H

3347-22-6SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name dithianon

1.2 Other means of identification

Product number -
Other names Thynon

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Fungicide
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3347-22-6 SDS

3347-22-6Synthetic route

morpholine
110-91-8

morpholine

dithianon
3347-22-6

dithianon

Morpholino-1,2-dicyan-2-(1,4-dihydro-1,4-dioxo-3-morpholino-naphthyl-(2)-thio)-ethylenthiolat-(1)
22200-66-4

Morpholino-1,2-dicyan-2-(1,4-dihydro-1,4-dioxo-3-morpholino-naphthyl-(2)-thio)-ethylenthiolat-(1)

Conditions
ConditionsYield
In chloroform at 40℃;
morpholine
110-91-8

morpholine

dithianon
3347-22-6

dithianon

methyl iodide
74-88-4

methyl iodide

methylsulfanyl-(3-morpholin-4-yl-1,4-dioxo-1,4-dihydro-naphthalen-2-ylsulfanyl)-butenedinitrile
22200-67-5

methylsulfanyl-(3-morpholin-4-yl-1,4-dioxo-1,4-dihydro-naphthalen-2-ylsulfanyl)-butenedinitrile

Conditions
ConditionsYield
(i) MeCN, (ii) /BRN= 969135/; Multistep reaction;
dithianon
3347-22-6

dithianon

4-cyclopropyl-6-methyl-N-phenylpyrimidin-2-amine
121552-61-2

4-cyclopropyl-6-methyl-N-phenylpyrimidin-2-amine

C14H4N2O2S2*(x)C14H15N3

C14H4N2O2S2*(x)C14H15N3

Conditions
ConditionsYield
In ethanol for 0.5h;

3347-22-6Upstream product

3347-22-6Downstream Products

3347-22-6Relevant articles and documents

Synergistic Combinations Of Active Ingredients

-

, (2012/02/15)

The present invention relates to novel active compound combinations comprising, firstly, at least one known compound of the formula (I) in which R1 and A have the meanings given in the description and, secondly, at least one further known active compound from groups (2) to (27) listed in the description, which combinations are highly suitable for controlling animal pests such as insects and unwanted acarids and also phytopathogenic fungi.

4-Nitro-2-trichloromethylphenylsulfenamides

-

, (2008/06/13)

New 4-nitro-2-trichloromethylphenylsulfenamides having a fungicidal and bactericidal action, processes for their manufacture, fungicides containing these compounds as active ingredients, and a process for combating fungi with these compounds.

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