3376-26-9

Basic information

• Product Name: N-benzyl-N-benzylideneamine oxide
• CAS NO: 3376-26-9
• Molecular Formula: C₁₄H₁₃NO
• Molecular Weight: 211.2591
• Mol File: 3376-26-9.mol
• Article Data: 113

Chemical Properties

• Boiling Point: 379.5°C at 760 mmHg
• Flash Point: 180.2°C
• Density: 1.111g/cm³
• Vapor Pressure: 1.27E-05mmHg at 25°C
• Refractive Index: 1.632
• CAS DataBase Reference: N-benzyl-N-benzylideneamine oxide(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl-N-benzylideneamine oxide(3376-26-9)
• EPA Substance Registry System: N-benzyl-N-benzylideneamine oxide(3376-26-9)

Safety Data

• Hazardous Substances Data: 3376-26-9(Hazardous Substances Data)

Usage

General Description

N-benzyl-N-benzylideneamine oxide is a chemical compound with the molecular formula C15H15NO. It is a powerful oxidizing agent that is commonly used as a co-catalyst in epoxy resin systems. Its primary function is to help improve the adhesion and mechanical properties of the epoxy resin, making it suitable for use in various industrial applications, including adhesives, coatings, and composites. N-benzyl-N-benzylideneamine oxide is known for its high thermal stability, low volatility, and excellent color stability, making it a popular choice for enhancing the performance of epoxy resins, particularly in high-temperature and demanding environments. Additionally, the compound has been evaluated for its potential as a flame retardant due to its ability to release radical scavengers during combustion, making it a promising candidate for improving the fire resistance of polymeric materials.

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Relevant articles and documents

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S -Tetrazine: Robust and Green Photoorganocatalyst for Aerobic Oxidation of N,N-Disubstituted Hydroxylamines to Nitrones

Efficient photocatalytic aerobic oxidative dehydrogenation reactions of N,N-disubstituted hydroxylamines to nitrones were developed with an in situ generated photocatalyst based on commercially available 3,6-dichlorotetrazine. This process affords a wide range of nitrones in high yields under mild conditions. In addition, an oxidative (3+3) cycloaddition between an oxyallyl cation precursor and a hydroxylamine was also developed.

Method for preparing N -benzylhydroxylamine hydrochloride with high yield

The invention discloses a method for preparing N - benzylhydroxylamine hydrochloride in a high yield, which comprises the following steps: S01, taking dibenzylamine as a starting raw material, adding a solvent, a catalyst and dropwise adding first oxidant

Dynamics in Catalytic Asymmetric Diastereoconvergent (3 + 2) Cycloadditions with Isomerizable Nitrones and α-Keto Ester Enolates

Reaction design in asymmetric catalysis has traditionally been predicated on a structurally robust scaffold in both substrates and catalysts, to reduce the number of possible diastereomeric transition states. Herein, we present the stereochemical dynamics in the Ni(II)-catalyzed diastereoconvergent (3 + 2) cycloadditions of isomerizable nitrile-conjugated nitrones with α-keto ester enolates. Even in the presence of multiple equilibrating species, the catalytic protocol displays a wide substrate scope to access a range of CN-containing building blocks bearing adjacent stereocenters with high enantio- and diastereoselectivities. Our computational investigations suggest that the enantioselectivity is governed in the deprotonation process to form (Z)-Ni-enolates, while the unique syn addition is mainly controlled by weak noncovalent bonding interactions between the nitrone and ligand.