34159-46-1Relevant articles and documents
STUDIES DIRECTED TOWARD THE PREPARATION OF POLYENE MACROLIDE MIMICS
Floyd, David M.,Fritz, Alan W.
, p. 2847 - 2850 (1981)
Cyclodimerization of two symmetrical but dissimilar fragments provides a facile route to macrocyclic dilactones containing conjugated polyolefins.Methods have been developed for the stereoselective synthesis of cis-2,4,6-triacetoxyheptanedial and the simple acylation of alcohols with dimethyl phosphonoacetic acid.
Synthesis of the C1-C11 western fragment of madeirolide A
Paterson, Ian,Haslett, Gregory W.
supporting information, p. 1338 - 1341 (2013/05/09)
The stereocontrolled synthesis of a fully elaborated C1-11 subunit of madeirolide A is described, utilizing an asymmetric boron aldol reaction and a cis-selective hetero-Michael cyclization to form the tetrahydropyran ring, followed by efficient formation of the required C5 α-glycoside.
An efficient preparation of β-aryl-β-ketophosphonates by the TFAA/H3PO4-mediated acylation of arenes with phosphonoacetic acids
Luke, George P.,Seekamp, Christopher K.,Wang, Zhe-Qing,Chenard, Bertrand L.
, p. 6397 - 6400 (2008/12/21)
(Chemical Equation Presented) β-Aryl-β-ketophosphonates can be efficiently prepared in good yield by using a TFAA/85% H3PO 4-mediated acylation of electron-rich arenes with phosphonoacetic acids. The conditions offer advantages over
Reactions of trialkyl phosphites with mono- and diacylals of halo-substituted acetic acids
Gazizov,Gaisin,Khairullin,Safina,Karimova,Petrova
, p. 1738 - 1741 (2007/10/03)
Trialkyl phosphites react with diacylals of di- and trichloroacetic acids by the pathway of the Perkow reaction; with monoacylals of bromo- and iodoacetic acids, by the pathway of the classical Arbuzov reaction; and with monoacylals of di- and trichloroacetic acids, by the pathway of the nonclassical Arbuzov reaction.
