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Cas Database

34570-16-6

34570-16-6

Identification

  • Product Name:2-Propenoic acid,3-amino-3-ethoxy-, ethyl ester, hydrochloride (1:1)

  • CAS Number: 34570-16-6

  • EINECS:

  • Molecular Weight:195.646

  • Molecular Formula: C7H13NO3.HCl

  • HS Code:2922509090

  • Mol File:34570-16-6.mol

Synonyms:2-Propenoicacid, 3-amino-3-ethoxy-, ethyl ester, hydrochloride (9CI);Acrylic acid,3-amino-3-ethoxy-, ethyl ester, hydrochloride (8CI);Ethyl3-amino-3-ethoxyacrylate hydrochloride;Ethyl 3-amino-3-ethoxypropenoatehydrochloride;Ethyl b-amino-b-ethoxyacrylatehydrochloride;[1-Ethoxy-2-(ethoxycarbonyl)vinyl]ammonium chloride;b-Amino-b-ethoxyacrylic acid ethyl esterhydrochloride;b-Ethoxy-b-aminoacrylic acid ethyl esterhydrochloride;

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Safety information and MSDS view more

  • Pictogram(s):IrritantXi

  • Hazard Codes:Xi

  • Signal Word:Warning

  • Hazard Statement:H315 Causes skin irritationH319 Causes serious eye irritation H335 May cause respiratory irritation

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
  • Delivery
  • Purchase
  • Manufacture/Brand:Usbiological
  • Product Description:Ethyl 3-Amino-3-ethoxyacrylate Hydrochloride
  • Packaging:1g
  • Price:$ 326
  • Delivery:In stock
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  • Manufacture/Brand:TRC
  • Product Description:Ethyl 3-amino-3-ethoxyacrylate hydrochloride
  • Packaging:5g
  • Price:$ 105
  • Delivery:In stock
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Ethyl 3-amino-3-ethoxyacrylate hydrochloride 95%
  • Packaging:25g
  • Price:$ 135
  • Delivery:In stock
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:Ethyl 3-amino-3-ethoxyacrylate hydrochloride
  • Packaging:1000g
  • Price:$ 1561
  • Delivery:In stock
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  • Manufacture/Brand:Matrix Scientific
  • Product Description:Ethyl 3-amino-3-ethoxyacrylate hydrochloride
  • Packaging:250g
  • Price:$ 592
  • Delivery:In stock
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  • Manufacture/Brand:Crysdot
  • Product Description:Ethyl 3-amino-3-ethoxyacrylate hydrochloride 95+%
  • Packaging:100g
  • Price:$ 156
  • Delivery:In stock
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  • Manufacture/Brand:Crysdot
  • Product Description:Ethyl 3-amino-3-ethoxyacrylate hydrochloride 95+%
  • Packaging:25g
  • Price:$ 57
  • Delivery:In stock
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  • Manufacture/Brand:Atlantic Research Chemicals
  • Product Description:Ethyl 3-amino-3-ethoxyacrylate hydrochloride 95%
  • Packaging:1gm:
  • Price:$ 24.74
  • Delivery:In stock
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:(1,3-DIETHOXY-3-OXOPROP-1-ENYL)AMMONIUM CHLORIDE 95.00%
  • Packaging:25G
  • Price:$ 750
  • Delivery:In stock
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  • Manufacture/Brand:American Custom Chemicals Corporation
  • Product Description:(1,3-DIETHOXY-3-OXOPROP-1-ENYL)AMMONIUM CHLORIDE 95.00%
  • Packaging:5G
  • Price:$ 495
  • Delivery:In stock
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Relevant articles and documentsAll total 4 Articles be found

Synthesis of novel nicotinohydrazide and (1,3,4-oxadiazol-2-yl)-6-(trifluoromethyl)pyridine derivatives as potential anticancer agents

Naresh Kumar,Poornachandra,Nagender,Santhosh Kumar,Krishna Swaroop,Ganesh Kumar,Narsaiah

, p. 4829 - 4831 (2016)

A series of novel nicotinohydrazide derivatives 6a–g and 1,3,4-oxadiazole functionalized pyridine derivatives 7a–k and 8a–d were prepared in series of steps. All the compounds were screened for cytotoxicity against HeLa (cervical), DU145 (prostate), HepG2

PYRANO-QUINOLINES, PYRANO-QUINOLINONES, COMBINATIONS THEREOF, PHOTOCHROMIC COMPOSITIONS AND ARTICLES

-

Page/Page column 42, (2010/02/12)

Described are compositions of at least one material represented by a pyrano[3,2-c]quinoline structure, a pyrano[3,2-c]quinolinone structure or mixtures thereof. The pyrano[3,2-c]quinoline structure is characterized by having a nitrogen atom at the 6-position ring atom and an oxy-substituent at the 5-position ring atom. The pyrano[3,2-c]quinolinone structure is characterized by having a substituted nitrogen atom at the 6-position ring atom and an oxo-substituent at the 5-position ring atom, the nitrogen atom substituents being hydrogen, aliphatic substituents, cycloaliphatic substituents, aromatic substituents, heteroaromatic substituents or a combination thereof. Both of the pyrano[3,2-c]quinoline and pyrano[3,2-c]quinolinone structures are characterized by having two substituents at the 2-position ring atom, each substituent being independently chosen from aliphatic substituents, cycloaliphatic substituents, aromatic substituents, heteroaromatic substituents or a combination thereof, provided that both substituents at the 2-position are not aliphatic. Alternatively, the two substituents at the 2-position can combine to form a spirocyclic group, provided that the spirocyclic group is not norbornylidene or bicyclo[3.3.1]9-nonylidene. The ring atoms have been numbered according to the International Union of Pure and Applied Chemistry rules of nomenclature starting with the 1-position ring atom being the oxygen atom of the pyran ring and numbering counterclockwise therefrom. Also described are photochromic articles that contain or that have coatings or films containing at least one of the novel compositions or combinations thereof with other photochromic materials.

Pyrimidinecarbamate derivatives as intermediates

-

, (2008/06/13)

2,4-Disubstituted 6-[3,6-dihydro-1(2H)-pyridyl]pyrimidine-3-oxides of the formula STR1 wherein R1 is lower alkyl or lower alkoxy-lower alkyl, R2 is hydrogen or --COOR3 wherein R3 is lower alkyl or lower alkoxy-l

80. A New Route to the Synthesis of 2-Amino-6-(methoxycarbonyl)amino-4-(tetrahydropyridyl)pyrimidine 1-Oxide

Muller, Jean-Claude,Ramuz, Henri,Wagner, Hans-Peter

, p. 809 - 813 (2007/10/02)

A new approach to 2-amino-6-(methoxycarbonyl)amino-4-(1,2,3,6-tetrahydro-1-pyridyl)pyrimidine 1-oxide (3) is described.Methyl carbamate (5) reacted with guanidine to the pyrimidinecarbamate 6, which was successively

Process route upstream and downstream products

Process route

ethanol
64-17-5

ethanol

ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

ethyl β-amino-β-ethoxyacrylate hydrochloride
34570-16-6

ethyl β-amino-β-ethoxyacrylate hydrochloride

Conditions
Conditions Yield
With hydrogenchloride; In diethyl ether; at 0 ℃; for 24h;
With hydrogenchloride; In diethyl ether; at 0 ℃; for 2h;
tert-butyl methyl ether
1634-04-4

tert-butyl methyl ether

ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

ethyl 3-amino-3-ethoxyacrylate hydrochloride
34570-16-6

ethyl 3-amino-3-ethoxyacrylate hydrochloride

Conditions
Conditions Yield
With hydrogenchloride; In ethanol;
ethanol
64-17-5

ethanol

ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

ethyl 3-amino-3-ethoxyacrylate hydrochloride
34570-16-6

ethyl 3-amino-3-ethoxyacrylate hydrochloride

Conditions
Conditions Yield
With hydrogenchloride; at 0 ℃;
90%
ethanol
64-17-5

ethanol

ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

ethyl β-amino-β-ethoxyacrylate hydrochloride
34570-16-6

ethyl β-amino-β-ethoxyacrylate hydrochloride

Conditions
Conditions Yield
With hydrogenchloride; In diethyl ether; at 0 ℃; for 24h;
With hydrogenchloride; In diethyl ether; at 0 ℃; for 2h;
tert-butyl methyl ether
1634-04-4

tert-butyl methyl ether

ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

ethyl 3-amino-3-ethoxyacrylate hydrochloride
34570-16-6

ethyl 3-amino-3-ethoxyacrylate hydrochloride

Conditions
Conditions Yield
With hydrogenchloride; In ethanol;
ethanol
64-17-5

ethanol

ethyl 2-cyanoacetate
105-56-6

ethyl 2-cyanoacetate

ethyl 3-amino-3-ethoxyacrylate hydrochloride
34570-16-6

ethyl 3-amino-3-ethoxyacrylate hydrochloride

Conditions
Conditions Yield
With hydrogenchloride; at 0 ℃;
90%

Global suppliers and manufacturers

Global( 46) Suppliers
  • Company Name
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  • Emails
  • Main Products
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  • Simagchem Corporation
  • Business Type:Manufacturers
  • Contact Tel:+86-592-2680277
  • Emails:sale@simagchem.com
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  • Amadis Chemical Co., Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:86-571-89925085
  • Emails:sales@amadischem.com
  • Main Products:29
  • Country:China (Mainland)
  • Shaanxi BLOOM TECH Co.,Ltd
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-29-86470566
  • Emails:sales@bloomtechz.com
  • Main Products:80
  • Country:China (Mainland)
  • LIDE PHARMACEUTICALS LIMITED
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-25-58409506
  • Emails:lide@lidepharma.com
  • Main Products:56
  • Country:China (Mainland)
  • Shanghai AngewChem Co., Ltd.
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-21-50762507
  • Emails:dylan@angewchem.com
  • Main Products:44
  • Country:China (Mainland)
  • SAGECHEM LIMITED
  • Business Type:Lab/Research institutions
  • Contact Tel:+86-571-86818502
  • Emails:will@sagechem.com
  • Main Products:28
  • Country:China (Mainland)
  • GIHI CHEMICALS CO.,LIMITED
  • Business Type:Lab/Research institutions
  • Contact Tel:571-86217390
  • Emails:info@gihichem.com
  • Main Products:66
  • Country:China (Mainland)
  • Aecochem Corp.
  • Business Type:Manufacturers
  • Contact Tel:+86-592 599 8717
  • Emails:sales@aecochemical.com
  • Main Products:70
  • Country:China (Mainland)
  • Finetech Industry Limited
  • Business Type:Trading Company
  • Contact Tel:86-27-87465837
  • Emails:sales@finetechnology-ind.com
  • Main Products:29
  • Country:China (Mainland)
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