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34595-26-1

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34595-26-1 Usage

General Description

2-PIPERIDIN-1-YL-BENZALDEHYDE, also known as N-(2-Formylphenyl)piperidine, is a chemical compound with the molecular formula C13H15NO. It is a pale yellow liquid with a strong, sweet, floral odor. It is commonly used as a building block in the synthesis of pharmaceuticals and organic compounds. This chemical is also a key intermediate in the production of various products, including dyes, perfumes, and other specialty chemicals. In addition, 2-PIPERIDIN-1-YL-BENZALDEHYDE has potential applications in the development of new materials and chemical processes. It is important to handle this chemical with care and follow proper safety regulations and guidelines when working with it.

Check Digit Verification of cas no

The CAS Registry Mumber 34595-26-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,4,5,9 and 5 respectively; the second part has 2 digits, 2 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 34595-26:
(7*3)+(6*4)+(5*5)+(4*9)+(3*5)+(2*2)+(1*6)=131
131 % 10 = 1
So 34595-26-1 is a valid CAS Registry Number.
InChI:InChI=1/C12H15NO/c14-10-11-6-2-3-7-12(11)13-8-4-1-5-9-13/h2-3,6-7,10H,1,4-5,8-9H2

34595-26-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-Piperidinobenzenecarbaldehyde

1.2 Other means of identification

Product number -
Other names 2-Piperidin-1-yl-benzaldehyde

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:34595-26-1 SDS

34595-26-1Relevant articles and documents

tert-Amino effect in heterocyclic chemistry. Synthesis of hydrogenated spiro derivatives of quinolines

D'yachenko,Glukhareva,Nikolaenko,Tkachev,Morzherin

, p. 1240 - 1247 (2004)

A new method was developed for the one-step synthesis of spiro derivatives of fused quinolines by the reactions of ortho-amino derivatives of benzaldehyde with Meldrum's acid, cyclohexane-1,3-dione, or N,N′-disubstituted barbituric acids.

Hexafluoroisopropanol-Mediated Redox-Neutral α-C(sp3)-H Functionalization of Cyclic Amines via Hydride Transfer

Shen, Yao-Bin,Wang, Lin-Xuan,Sun, Yun-Ming,Dong, Feng-Ying,Yu, Liping,Liu, Qing,Xiao, Jian

, p. 1915 - 1926 (2020/02/04)

Hexafluoroisopropanol has been demonstrated as the versatile promoter for redox-neutral α-C(sp3)-H functionalization of cyclic amines via the cascade [1,5]-hydride transfer/cyclization strategy. A wide range of cyclic amines are functionalized

Catalyst-free photodecarbonylation ofortho-amino benzaldehyde

Li, Lamei,Wang, Songping,Wei, Wentao,Yan, Ming,Zhou, Jingwei

supporting information, p. 3421 - 3426 (2020/06/25)

It is almost a consensus that decarbonylation of the aldehyde group (-CHO) needs to not only be mediated by transition metal catalysts, but also requires severe reaction conditions (high temperature and long reaction time). In this work, inspired by the “conformational-selectivity-based” design strategy, we broke this consensus and discovered a catalyst-free photodecarbonylation of the aldehyde group. It revealed that decarbonylation can be easily achieved with visible light irradiation by introducing a tertiary amine into theortho-position of the aldehyde group. A diverse array of tertiary amines is tolerated by our photodecarbonylation under mild conditions. Furthermore, the (QM) computations of the mechanism and the experiments on well-designed special substrates revealed that our photodecarbonylation depends on the conformational specificity of the aldehyde group and tertiary amine, and occurs through an unusual [1,4]-H shift and a subsequent [1,3]-H shift.

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