34918-76-8

Basic information

• Product Name: Benzenecarboximidoyl chloride, N-(4-chlorophenyl)-
• CAS NO: 34918-76-8
• Molecular Formula: C13H9Cl2N
• Molecular Weight: 250.127
• Mol File: 34918-76-8.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: Benzenecarboximidoyl chloride, N-(4-chlorophenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenecarboximidoyl chloride, N-(4-chlorophenyl)-(34918-76-8)
• EPA Substance Registry System: Benzenecarboximidoyl chloride, N-(4-chlorophenyl)-(34918-76-8)

Safety Data

• Hazardous Substances Data: 34918-76-8(Hazardous Substances Data)

Upstream product

• 40339-43-3 N-Benzylidene-p-chloroaniline 
• 2866-82-2 N-(4-chlorophenyl)benzamide 
• 106-47-8 4-chloro-aniline 
• 76711-20-1 chlore-methylene-di(tert-butyle)phosphorane 

Downstream Products

• 98888-79-0 (4-Chloro-phenyl)-thiobenzoyl-thiocarbamic acid O-methyl ester 
• 98888-80-3 (4-Chloro-phenyl)-thiobenzoyl-thiocarbamic acid O-ethyl ester 
• 98888-81-4 (4-Chloro-phenyl)-thiobenzoyl-thiocarbamic acid O-propyl ester 
• 2866-82-2 N-(4-chlorophenyl)benzamide 
• 78752-63-3 (4-Chloro-phenyl)-[1-phenyl-1-trimethylsilanyl-meth-(Z)-ylidene]-amine 
• 76173-06-3 (4-Chloro-phenyl)-[1-phenyl-pent-4-en-(E)-ylidene]-amine 
• 79508-04-6 5-(4-Chloro-phenyl)-1-{[(Z)-4-chloro-phenylimino]-phenyl-methyl}-1H-pyrazole-3-carboxylic acid methyl ester 
• 76173-12-1 (Z)-3-{[(E)-4-Chloro-phenylimino]-phenyl-methyl}-hexa-2,5-dien-2-ol 
• 53085-41-9 N¹-Phenyl-benzohydrazid- 
• 98762-42-6 N³-(4-Chlorphenyl)-N¹-phenyl-benzamidrazon 
• 76173-13-2 (4-Chloro-phenyl)-methyl-((E)-1-phenyl-penta-1,4-dienyl)-amine 
• 780-21-2 N-(4-chlorobenzylidene)aniline 
• 57761-72-5 1-(4-chloro-phenyl)-5-phenyl-1H-tetrazole 
• 103753-07-7 3-(4-chloro-phenyl)-6-methyl-2-phenyl-5-propyl-3H-pyrimidin-4-one 

Relevant articles and documents

N-alkylation of α-iminophosphonates and application to Horner-Wadsworth-Emmons reaction

N-Alkylation of α-iminophosphonates with Grignard reagents gives α-N-alkylaminophosphonates. A subsequent Horner-Wadsworth-Emmons reaction of the intermediary α-metalated phosphonate takes place with aldehydes to give enamines. The enamine thus prepared reacts with MVK to give a four-component coupling product.

Synthesis of Imidoyl Chlorides Using Phosphorus Trichloride

Abstract: The reaction of carboxamides with phosphorus trichloride under heating at 75–80°C for 1 h in the presence of a 4-dimethylaminopyridine catalyst was used to synthesize imidoyl chlorides in yields of 63–99%.

α-Imino Iridium Carbenes from Imidoyl Sulfoxonium Ylides: Application in the One-Step Synthesis of Indoles

Imidoyl sulfoxonium ylides are presented for the first time as potential precursors to generate α-imino metal-carbene intermediates and applied in direct C-H functionalization reactions catalyzed by [Ir(cod)Cl]2 (4 mol %) to provide 2-substituted indoles (up to 70% yield) in just one step. This class of sulfur ylide is successfully obtained from imidoyl chloride and dimethylsulfoxonium methylide (23 new examples in 45-85% yield) or by imino group formation from the corresponding β-keto sulfoxonium ylides and anilines in the presence of TiCl4 as a Lewis acid (9 examples in 33-94% yield).