35086-59-0

Basic information

• Product Name: 3,5-Diacetoxyacetophenone
• Synonyms: 1-[3,5-Bis(acetyloxy)phenyl]-ethanone;3',5'-DIACETOXYACETOPHENONE;3,5-DIACETOXYACETOPHENONE;3',5'-DIACETYLOXYACETPHENONE;3-ACETYL-5-(ACETYLOXY)PHENYL ACETATE;5-ACETYL-1,3-PHENYLENE DIACETATE;3,5-Diacetoxyacetophonone;3',5'-Diacetoxyacetophenone 3-Acetyl-5-(Acetyloxy)phenyl Acetate
• CAS NO: 35086-59-0
• Molecular Formula: C₁₂H₁₂O₅
• Molecular Weight: 236.22068
• EINECS: 252-354-2
• Product Categories: Aromatic Acetophenones & Derivatives (substituted);Building Blocks for Dendrimers;Functional Materials;Aromatics
• Mol File: 35086-59-0.mol
• Article Data: 4

Chemical Properties

• Melting Point: 91-94 °C(lit.)
• Boiling Point: 165-168 °C (0.7501 mmHg)
• Flash Point: 168.7 °C
• Appearance: yellow to brown powder
• Density: 1.3026 (rough estimate)
• Vapor Pressure: 6.63E-06mmHg at 25°C
• Refractive Index: 1.5140 (estimate)
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 3,5-Diacetoxyacetophenone(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-Diacetoxyacetophenone(35086-59-0)
• EPA Substance Registry System: 3,5-Diacetoxyacetophenone(35086-59-0)

Safety Data

• Hazard Codes: Xi
• Safety Statements: 22-24/25
• WGK Germany: 3
• F: 9-21
• Hazardous Substances Data: 35086-59-0(Hazardous Substances Data)

Usage

Chemical Properties

Yellow to brown powder

Uses

3’,5’-Diacetyloxyacetophenone (cas# 35086-59-0) is a compound useful in organic synthesis.

InChI:InChI=1/C12H12O5/c1-7(13)10-4-11(16-8(2)14)6-12(5-10)17-9(3)15/h4-6H,1-3H3

Upstream product

• 39192-49-9 3,5-diacetoxybenzoyl chloride 
• 506-82-1 dimethylcadmium 
• 75-36-5 acetyl chloride 
• 51863-60-6 3,5-dihydroxyacetophenone 
• 108-24-7 acetic anhydride 
• 676-58-4 methylmagnesium chloride 
• 99-10-5 3,5-Dihydroxybenzoic acid 

Downstream Products

• 144660-11-7 1-(3,5-diacetoxyphenyl)-2,2-dichloro-1-ethanone 
• 94109-62-3 C₁₉H₂₃NO₃*0.5H₂O₄S 
• 81732-49-2 1-[bis-3′,5′-(N,N-dimethylcarbamoyloxy)-phenyl]-2-bromoethanone 
• 788821-30-7 (R)-2-(tert-butylamino)-1-[3,5-bis(dimethylcarbamoyloxy)phenyl]ethanol 
• 1050279-04-3 (R)-2-[3,5-di(N,N-dimethylcarbamyloxy)phenyl]oxirane 
• 81732-48-1 bis-3,5-(N,N-dimethylcarbamoyloxy)-acetophenone 
• 39878-43-8 2-chloro-1-(3,5-dihydroxy-phenyl)-ethanone 

Relevant articles and documents

Preparation method of terbutaline sulphate

The invention relates to a preparation method of terbutaline sulphate. The technical problems that according to an existing preparation method of terbutaline sulphate, high-pressure hydrogenation and other high-risk operations, and lithium methide, azomethane and other high-risk reagents exist, and cost is high are solved through the preparation method. 3,5-resacetophenone serves as a raw material, and terbutaline sulphate is obtained through hydroxyl protection, the bromination reaction, carbonyl reduction, the condensation reaction and sulphating. The preparation method can be suitable for industrially-produced terbutaline sulphate.

PREPARATION METHOD OF ACYLBENZENES

A process for the production of acylbenzenes, comprising reacting diacetoxybenzoyl chloride with a Grignard reagent in the presence of an iron-containing catalyst. The acylbenzenes are useful intermediates in a multistep process for the preparation of resveratrol.