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1,2-Dibromo-3,4,5,6-tetramethylbenzene is a complex organic compound that belongs to the class of organobromides. It is characterized by the presence of bromine atoms, which allows it to interact with a variety of other substances. Despite its potential applications in various industries, information about its specific uses is limited, possibly due to its synthetic complexity or limited commercial demand.

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  • 36321-73-0 Structure
  • Basic information

    1. Product Name: 1,2-DIBROMO-3,4,5,6-TETRAMETHYLBENZENE
    2. Synonyms: 1,2-DIBROMO-3,4,5,6-TETRAMETHYLBENZENE;DIBROMOPREHNITENE;Benzene,1,2-dibroMo-3,4,5,6-tetraMethyl-;5,6-Dibromoprehnitene;5,6-Dibromo-1,2,3,4-tetramethylbenzene;1,2-Dibromotetramethylbenzene
    3. CAS NO:36321-73-0
    4. Molecular Formula: C10H12Br2
    5. Molecular Weight: 292.01
    6. EINECS: N/A
    7. Product Categories: API intermediates
    8. Mol File: 36321-73-0.mol
  • Chemical Properties

    1. Melting Point: 204-205 °C
    2. Boiling Point: 324.1 °C at 760 mmHg
    3. Flash Point: 173.4 °C
    4. Appearance: /
    5. Density: 1.562 g/cm3
    6. Vapor Pressure: 0.000475mmHg at 25°C
    7. Refractive Index: 1.565
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: 1,2-DIBROMO-3,4,5,6-TETRAMETHYLBENZENE(CAS DataBase Reference)
    11. NIST Chemistry Reference: 1,2-DIBROMO-3,4,5,6-TETRAMETHYLBENZENE(36321-73-0)
    12. EPA Substance Registry System: 1,2-DIBROMO-3,4,5,6-TETRAMETHYLBENZENE(36321-73-0)
  • Safety Data

    1. Hazard Codes: Xi
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: IRRITANT
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 36321-73-0(Hazardous Substances Data)

36321-73-0 Usage

Uses

Used in Pharmaceutical Industry:
1,2-Dibromo-3,4,5,6-tetramethylbenzene is used as a chemical intermediate for the synthesis of various pharmaceutical compounds. Its reactivity with other substances makes it a valuable component in the development of new drugs.
Used in Agricultural Industry:
In agriculture, 1,2-Dibromo-3,4,5,6-tetramethylbenzene is used as a precursor for the production of certain agrochemicals. Its ability to react with other chemicals enables the creation of effective pesticides and herbicides.
Used in Manufacturing Industry:
1,2-Dibromo-3,4,5,6-tetramethylbenzene is employed as a raw material in the manufacturing of various industrial products. Its versatility in chemical reactions contributes to the production of a range of consumer goods and materials.

Check Digit Verification of cas no

The CAS Registry Mumber 36321-73-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,6,3,2 and 1 respectively; the second part has 2 digits, 7 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 36321-73:
(7*3)+(6*6)+(5*3)+(4*2)+(3*1)+(2*7)+(1*3)=100
100 % 10 = 0
So 36321-73-0 is a valid CAS Registry Number.
InChI:InChI=1/C10H12Br2/c1-5-6(2)8(4)10(12)9(11)7(5)3/h1-4H3

36321-73-0 Well-known Company Product Price

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  • Alfa Aesar

  • (H33558)  1,2-Dibromo-3,4,5,6-tetramethylbenzene, 98%   

  • 36321-73-0

  • 1g

  • 1201.0CNY

  • Detail
  • Alfa Aesar

  • (H33558)  1,2-Dibromo-3,4,5,6-tetramethylbenzene, 98%   

  • 36321-73-0

  • 5g

  • 3998.0CNY

  • Detail

36321-73-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,2-Dibromo-3,4,5,6-tetramethylbenzene

1.2 Other means of identification

Product number -
Other names 1,2-DIBROMO-3,4,5,6-TETRAMETHYLBENZENE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:36321-73-0 SDS

36321-73-0Relevant articles and documents

Significantly improved method for the pd-catalyzed coupling of phenols with aryl halides: Understanding ligand effects

Burgos, Carlos H.,Barder, Timothy E.,Huang, Xiaohua,Buchwald, Stephen L.

, p. 4321 - 4326 (2007/10/03)

(Chemical Equation Presented) A variety of diaryl ethers were synthesized by the Pd-catalyzed reaction of (hetero)-aryl halides and phenols. These reactions were achieved through the use of two new di-tert-butylphosphino biaryl ligands that overcome several limitations of previously described methods.

Use of tunable ligands allows for intermolecular Pd-catalyzed C-O bond formation

Vorogushin, Andrei V.,Huang, Xiaohua,Buchwald, Stephen L.

, p. 8146 - 8149 (2007/10/03)

Bulky biaryl phosphine ligands facilitate Pd-catalyzed C-O coupling reactions of aryl halides with primary and secondary alcohols by promoting reductive elimination at the expense of β-hydride elimination. The key to their success is the ability to match the size of the ligand to that of the combination of substrates. The efficient coupling of a number of unactivated aryl chlorides and bromides with cyclic and acyclic secondary alcohols was achieved. This included the coupling of allylic alcohols for the first time in a Pd-catalyzed coupling process.

Pd catalyzed coupling of 1,2-dibromoarenes and anilines: Formation of N,N-diaryl-o-phenylenediamines

Wenderski, Todd,Light, Kenneth M.,Ogrin, Doug,Bott, Simon G.,Harlan, C. Jeff

, p. 6851 - 6853 (2007/10/03)

1,2-Dibromoarenes were coupled with aniline derivatives to yield N,N-diaryl-o-phenylenediamines in moderate to good yield using a palladium/phosphine or palladium/carbene catalyst system. Under similar conditions, 1,2,4,5-tetrabromobenzene was coupled with aniline derivatives to produce the corresponding tetrasubstituted derivatives which are oxidized on workup to yield azophenines. The sequential reaction of two different anilines with 1-chloro-2-iodobenzene afforded mixed N,N-diaryl-o-phenylenediamines.

Synthesis of annulated dioxins as electron-rich donors for cation radical salts

Hellberg, Jonas,Dahlstedt, Emma,Pelcman, Margit E.

, p. 8899 - 8912 (2007/10/03)

The synthesis of a series of new alkoxylated linearly annulated dioxins is described together with their cyclic voltammetric behavior and some preliminary result on their ability to form cation radical salts. Of these dioxins, seven (8, 12, 19, 21, 27, 33, 34) are the first representatives of entirely new heterocyclic systems. Dioxins 8, 21, 22 and 27 gave good quality cation radical salts upon electrocrystallization. Graphical Abstract

Halogenation Using Quaternary Ammonium Polyhalides. XIV. Aromatic Bromination and Iodination of Arenes by Use of Benzyltrimethylammonium Polyhalides-Zinc Chloride System

Kajigaeshi, Shoji,Kakinami, Takaaki,Moriwaki, Masayuki,Tanaka, Toshio,Fujisaki, Shizuo,Okamoto, Tsuyoshi

, p. 439 - 443 (2007/10/02)

The reaction of arenes with benzyltrimethylammonium tribromide or benzyltrimethylammonium dichloroiodate in acetic acid in the presence of ZnCl2 at room temperature or at 70 deg C gave brome- or iodo-substituted arenes in good yield, respectively.

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