367-46-4Relevant articles and documents
A Chiroptical Molecular Switch with Distinct Chiral and Photochromic Entities and Its Application in Optical Switching of a Cholesteric Liquid Crystal
Van Delden, Richard A.,Mecca, Tommaso,Rosini, Carlo,Feringa, Ben L.
, p. 61 - 70 (2004)
Two new structurally related photoswitches are described, in which azobenzene photochromism is combined with the chirality of a 2,2′-dihydroxy-1,1′-binaphthyl unit. In system 1 the chiral binaphthyl moiety is bridged by a methylene tether, locking the biaryl chirality while in system 2 the biaryl core is unbridged and has considerable conformational flexibility. Both compound are capable of inducing cholesteric liquid crystalline phases and proved to be good photoswitches both in solution and in a liquid crystalline matrix. Compound 2 is capable of completely reversing the liquid crystalline chirality which is unique for a chiroptical molecular switch where the switching unit and the chiral moiety are separate entities.
N- [6-AMINO-S- (PHENYL) PYRAZIN-2-YL] -ISOXAZOLE-4-CARBOXAMIDE DERIVATIVES AND RELATED COMPOUNDS AS NAV1.8 CHANNEL MODULATORS FOR THE TREATMENT OF PAIN
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Page/Page column 56-57, (2009/01/20)
The present invention relates to compounds of the formula (I) and pharmaceutically acceptable salts and solvates thereof, to processes for the preparation of, intermediates used in the preparation of, and compositions containing such compounds and the uses of such compounds for the treatment of pain.
Dehydrotriphenylenes for the generation of bent molecular ribbons
Meier, Herbert,Rose, Bernd
experimental part, p. 536 - 543 (2011/10/17)
The synthetic sequences 1→11 and 17→23a lead to highly reactive mono- and bisdienophiles whose cycloaddition processes with in situ generated isobenzofuran 13 were studied: 11 + 13 → 15 and 23a + 2×13 → 24a.