36880-68-9

Basic information

• Product Name: 3-methyl-2-ethoxy-2-butene
• Synonyms: 3-methyl-2-ethoxy-2-butene
• CAS NO: 36880-68-9
• Molecular Weight: 114.188
• Mol File: 36880-68-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-methyl-2-ethoxy-2-butene(CAS DataBase Reference)
• NIST Chemistry Reference: 3-methyl-2-ethoxy-2-butene(36880-68-9)
• EPA Substance Registry System: 3-methyl-2-ethoxy-2-butene(36880-68-9)

Safety Data

• Hazardous Substances Data: 36880-68-9(Hazardous Substances Data)

Upstream product

• 80359-83-7 methyl isopropyl ketone diethyl acetal 

Downstream Products

• 6325-93-5 p-nitrobenzenesulfonamide 
• 121239-38-1 N-[1-Ethoxy-2,2-dimethyl-prop-(E)-ylidene]-4-nitro-benzenesulfonamide 
• 121239-41-6 N-(2-Ethoxy-1,1-dimethyl-allyl)-4-nitro-benzenesulfonamide 
• 56544-17-3 2-ethoxy-3-methyl-but-1-ene 
• 78-79-5 isoprene 
• 70-55-3 toluene-4-sulfonamide 
• 121239-36-9 ethyl N-tosyl-2,2-dimethylpropanimidate 
• 121239-39-2 N-(1,1-dimethyl-2-ethoxy-2-propenyl)-p-toluenesulfonamide 
• 121239-42-7 N-(1,1-dimethyl-2-oxopropyl)-p-toluenesulfonamide 

Relevant articles and documents

REACTION OF ORGANIC AZIDES WITH UNSATURATED COMPOUNDS. IX. PRODUCTS FROM REARRANGEMENT OF 1-ARYLSULFONYL-4,4,5-TRIMETHYL-5-ETHOXY-1,2,3-TRIAZOLINES

Ethyl N-arylsulfonyl-2,2-dimethylpropanimidates and N-(1,1-dimethyl-2-ethoxy-2-propenyl)arenesulfonamides are obtained in the reaction of arylsulfonyl azides with 2-methyl-3-ethoxy-2-butene.Thus, the intermediate 1-arylsulfonyl-4,4,5-trimethyl-5-ethoxy-1,2,3-triazolines not only rearrange to the imidates but are also converted into unstable 1-arylsulfonyl-2,2,3-trimethyl-3-ethoxyaziridines, which isomerize to the N-substituted arenesulfonamides.