373-53-5Relevant articles and documents
[18F]FMDAA1106 and [18F]FEDAA1106: two positron-emitter labeled ligands for peripheral benzodiazepine receptor (PBR).
Zhang, Ming Rong,Maeda, Jun,Furutsuka, Kenji,Yoshida, Yuichiro,Ogawa, Masanao,Suhara, Tetsuya,Suzuki, Kazutoshi
, p. 201 - 204 (2003)
We synthesized and evaluated N-(5-fluoro-2-phenoxyphenyl)-N-(2-[(18)F]fluoromethyl-5-methoxybenzyl)acetamide ([(18)F]-FMDAA1106) and N-(5-fluoro-2-phenoxyphenyl)-N-(2-[(18)F]fluoroethyl-5-methoxybenzyl)acetamide ([(18)F]FEDAA1106) as two potent radioligan
Direct Monofluoromethylthiolation with S-(Fluoromethyl) Benzenesulfonothioate
Zhao, Qunchao,Lu, Long,Shen, Qilong
supporting information, p. 11575 - 11578 (2017/09/11)
An electrophilic shelf-stable monofluoromethylthiolating reagent S-(fluoromethyl) benezenesulfonothioate (1) was developed. In the presence of a copper catalyst, reagent 1 coupled with a variety of aryl boronic acids to give the corresponding monofluoromethylthiolated arenes in high yields. In addition, addition of reagent 1 to alkyl alkenes in the presence of a silver catalyst gave alkyl monofluoromethylthioethers in high yields.
Crystal Structure and Spectroscopic Investigation of Bromofluoro- and Fluoroiodomethane
Feller, Michael,Lux, Karin,Kornath, Andreas
, p. 5357 - 5362 (2016/01/25)
The solid states of bromofluoromethane (BFM) and fluoroiodomethane (FIM) are characterized by X-ray diffraction analysis and by Raman spectroscopy. The single crystals were obtained by crystallization in situ at low temperature. BFM and FIM crystallize in the space group I2/a and Abm2, respectively. The Raman spectra of both compounds were recorded in different aggregation states and at different temperatures. Quantum chemical calculations and the X-ray diffraction data are considered to describe the noncovalent interactions of both compounds in the solid state. These interactions are discussed in the context of the σ-hole concept.