37366-09-9Relevant articles and documents
A convenient one-pot synthesis of a functionalized-arene ruthenium half-sandwich compound [RuCl2(η6-C6H 5OCH2CH2OH)]2
Soleimannejad, Janet,White, Colin
, p. 2538 - 2541 (2008/10/09)
Reaction of RuCl3·xH2O with 1-methoxy-1,4-cyclohexadiene in an alcohol solvent, ROH, gives [RuCl 2-(η6-C6H5OR)]2 (R = Me, Et, or HOCH2CH2) in up to 79% yield. The crystal structures of [Ru2(μ-Cl3)(η6-C 6H5-OEt)2]+[BPh4] - and [RuCl2(η6-C6H 5OCH2CH2OH)]2 are also reported.
SYNTHESIS AND REACTIONS OF SOME TRIPLE ALKOXO- AND THIOATO-BRIDGED ARENERUTHENIUM(II) COMPLEXES. X-RAY STRUCTURE DETERMINATION OF
Gould, R. O.,Stephenson, T. A.,Tocher, D. A.
, p. 375 - 384 (2007/10/02)
Reaction of 2> (arene = C6H6, 1,4-MeC6H4CHMe2) with NaNH2 in CH3CN gives a dark oil which upon treatment with ROH/NaBPh4 (R = Me, Et) gives the triple bridged complexes (BPh4>.The structure of the benzene complex (R = Me) has been verified by X-ray analysis.The crystals are monoclinic, space group P21/n with a 11.725(4), b 15.573(5), c 18.739(2) Angstroem; β 103.29(2)deg.These complexes undergo reactions with tertiary phosphines and hydrogen halides.There is also spectroscopic evidence for intermolecular exchange of the bridging alkoxo ligands on mixing pure solutions of the + cations (M = Ru, Os).Reaction of 2> with Pb(SEt) 2 in CH3CN gives the analogous + cations.