37593-94-5Relevant articles and documents
Kinetic study on aminolysis of 4-chloro-2-nitrophenyl X-substituted-benzoates in Acetonitrile and in 80 mol % H2O/20 mol % DMSO: Effect of medium on reactivity and reaction mechanism
Kim, Ha-Ram,Um, Tae-Il,Kim, Min-Young,Um, Ik-Hwan
, p. 1128 - 1132 (2014/05/06)
A kinetic study on aminolysis of 4-chloro-2-nitrophenyl X-substituted-benzoates (6a-i) in MeCN is reported. The Hammett plot for the reactions of 6a-i with piperidine consists of two intersecting straight lines, while the Yukawa-Tsuno plot exhibits an exc
N-(2-hydroxyaryl)benzamide synthesis from 2-nitroaryl benzoates via an Indium-mediated reduction-migration reaction
Lee, Hyejeong,Kim, Minki,Jun, Young Moo,Kim, Byeong Hyo,Lee, Byung Min
scheme or table, p. 158 - 167 (2011/10/08)
A one-pot reduction-triggered N-(2-hydroxyaryl)benzamide synthesis from 2-nitroaryl benzoate substrates was investigated. In the presence of indium/AcOH in THF/H2O, 2-nitroaryl benzoates produced reasonable yields of the benzo group migrated N-
Photolysis of 2-Nitrophenyl Benzyl Ethers in Neutral and Acidic Media
Jacob E. Dominic,Joshua, C. P.
, p. 808 - 810 (2007/10/02)
2-Nitrophenyl benzyl ethers (1a-d) on irradiation afford N-benzoyl-2-aminophenols (4) as the major products.The other minor products are 2-nitrophenol (2), 4-benzyl-2-nitrophenol (3), 2-phenylbenzoxazoles (5) and 2-nitrophenyl benzoate (6).A plausible mechanism to account for the formation of various products is discussed.