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37746-17-1

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37746-17-1 Usage

General Description

1,5-Dibromo-3,3-dimethylpentane is a chemical compound with the molecular formula C7H14Br2. It is a colorless liquid with a boiling point of 172-173°C and a flash point of 96°C. 1,5-DIBROMO-3,3-DIMETHYLPENTANE is used in organic synthesis and research due to its ability to act as a reactant in various chemical reactions. It is also known to be an effective solvent for a variety of organic compounds. Due to its bromine atoms, 1,5-Dibromo-3,3-dimethylpentane is also used as a flame retardant in some applications. However, it is important to handle this compound with care as it is toxic and can cause irritation to the skin, eyes, and respiratory system.

Check Digit Verification of cas no

The CAS Registry Mumber 37746-17-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,7,7,4 and 6 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 37746-17:
(7*3)+(6*7)+(5*7)+(4*4)+(3*6)+(2*1)+(1*7)=141
141 % 10 = 1
So 37746-17-1 is a valid CAS Registry Number.

37746-17-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 1,5-DIBROMO-3,3-DIMETHYLPENTANE

1.2 Other means of identification

Product number -
Other names 3,3-dimethyl-1,5-dibromopentane

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:37746-17-1 SDS

37746-17-1Relevant articles and documents

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Miller,R.G. et al.

, p. 4211 - 4220 (1974)

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Enantioselective Synthesis of N-Alkylamines through β-Amino C-H Functionalization Promoted by Cooperative Actions of B(C6F5)3and a Chiral Lewis Acid Co-Catalyst

Chang, Yejin,Cao, Min,Chan, Jessica Z.,Zhao, Cunyuan,Wang, Yuankai,Yang, Rose,Wasa, Masayuki

supporting information, p. 2441 - 2455 (2021/02/16)

We disclose a catalytic method for β-C(sp3)-H functionalization of N-alkylamines for the synthesis of enantiomerically enriched β-substituted amines, entities prevalent in pharmaceutical compounds and used to generate different families of chiral catalysts. We demonstrate that a catalyst system comprising of seemingly competitive Lewis acids, B(C6F5)3, and a chiral Mg- or Sc-based complex, promotes the highly enantioselective union of N-alkylamines and α,β-unsaturated compounds. An array of δ-amino carbonyl compounds was synthesized under redox-neutral conditions by enantioselective reaction of a N-alkylamine-derived enamine and an electrophile activated by the chiral Lewis acid co-catalyst. The utility of the approach is highlighted by late-stage β-C-H functionalization of bioactive amines. Investigations in regard to the mechanistic nuances of the catalytic processes are described.

Iron-catalyzed oxidative C(3)-H functionalization of amines

Takasu, Noriaki,Oisaki, Kounosuke,Kanai, Motomu

supporting information, p. 1918 - 1921 (2013/06/04)

Fe-catalyzed direct dehydrogenative C(3)-functionalization of tertiary arylamines was developed via activation of the sp3 C(3)-H bond. The reaction is applicable to both cyclic and acyclic amines. The key process is the catalytic desaturative enamine formation from tertiary amines and position-selective C-C bond formation (addition to nitro olefins) at the β-carbon. Products can be converted to versatile and unique nitrogen-containing molecules.

Intramolecular and Intermolecular Reactions of Alkenylsilyl Radicals

Chatgilialoglu, Chryssostomos,Woynar, Helmut,Ingold, Keith U.

, p. 555 - 562 (2007/10/02)

The radicals formed during photolysis of di-t-butyl peroxide and a number of alkenyldimethylsilanes have been examined by e.s.r. spectroscopy.Only carbon-centred radicals were observed.These were either secondary alkyl radicals formed by the addition of the initially formed silyl radical to a double bond and/or allyl radicals formed by hydrogen-atom abstraction from the alkenyl group.In most cases addition to the double bond was an intermolecular process.However, pent-4-enylsilyl radicals undergo intramolecular addition with endo-cyclization to form the six-membered ring being strongly favoured over exo-cyclization to form the five-membered ring.This preference was confirmed by product studies on 3,3-dimethylpent-4-enyldimethylsilane.The factors that control homolytic exo:endo cyclization rates for species in which the radical centre is located on a second row element are adumbrated.

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