37857-41-3

Basic information

• Product Name: Benzenamine, N-(1-methyl-2-butenyl)-
• CAS NO: 37857-41-3
• Molecular Formula: C11H15N
• Molecular Weight: 161.247
• Mol File: 37857-41-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzenamine, N-(1-methyl-2-butenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N-(1-methyl-2-butenyl)-(37857-41-3)
• EPA Substance Registry System: Benzenamine, N-(1-methyl-2-butenyl)-(37857-41-3)

Safety Data

• Hazardous Substances Data: 37857-41-3(Hazardous Substances Data)

Upstream product

• 1458-99-7 4-chloropent-2-ene 
• 62-53-3 aniline 
• 18610-33-8 (E)-4-chloropent-2-ene 
• 55108-06-0 trans-crotonaldehyde phenylimine 
• 917-54-4 methyllithium 
• 2004-70-8 1-methylbuta-1,3-diene 
• 7294-89-5 4-(phenylamino)pent-3-en-2-one 
• 13154-14-8 1-propenylmagnesium bromide 
• 87876-84-4 (E)-acetophenone-O-ethoxycarbonyloxime 
• 1809-26-3 2-bromopent-3-ene 

Downstream Products

• 1394171-69-7 (E)-N-((E)-pent-3-en-2-ylidene)aniline oxide 
• 1394171-69-7 (Z)-N-((E)-pent-3-en-2-ylidene)aniline oxide 
• 133388-40-6 4-(1'-Methyl-2'-butenyl)anilin 
• 74266-80-1 {2-[(2E)-1-methylbut-2-en-1-yl]phenyl}amine 
• 74266-81-2 4-[(2E)-1-methylbut-2-en-1-yl]aniline 
• 83191-32-6 2,6-di(1-methyl-2-butenyl)aniline 
• 62-53-3 aniline 
• 2004-70-8 1-methylbuta-1,3-diene 
• 83191-35-9 2-methyl-4-[(2E)-1-methylbut-2-en-1-yl]aniline 
• 83191-34-8 2-methyl-6-(1-methylbut-2-ene-1-yl)aniline 
• 73676-95-6 2-(pent-3-en-2-yl)aniline hydrochloride 
• 1198-37-4 2,4-dimethylquinoline 
• 19013-49-1 2-ethyl-3-methylindole 

Relevant articles and documents

Regularities of the amino-Claisen rearrangement mechanism

The synthetic and kinetic regularities of the amino-Claisen rearrangement (ACR) were studied for the transformation of 2,5-dimethyl-N-(pent-3-en-2-yl) aniline. The ACR products are formed due to the conversion of a binary π-complex formed by the reaction of N-alkenylaniline hydrochloride with hydrochloride of the solvent (2,5-dimethylaniline).

A modular approach to α,β-unsaturated N-aryl ketonitrones

A modular approach to α,β-unsaturated N-aryl ketonitrones has been developed. Specifically, condensation of anilines and enals followed by alkylation of the resulting α,β-unsaturated imines provided N-allyl anilines, which were subjected to oxidation with

Synthesis of Aryl-Substituted Propanols, Pentanediols, and Tetrahydropyran

Oxidation of N- and C-alkenylanilines with ozone under conditions of alcohol formation was studied. Depending on the structure of the alkenyl moiety, the reaction yields aryl-substituted propanols, pentanediols, or tetrahydropyran.