383-73-3

Basic information

• Product Name: BIS(TRIFLUOROACETYL)PEROXIDE
• CAS NO: 383-73-3
• Molecular Formula: C4F6O4
• Molecular Weight: 226.032
• Mol File: 383-73-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: BIS(TRIFLUOROACETYL)PEROXIDE (CAS DataBase Reference)
• NIST Chemistry Reference: BIS(TRIFLUOROACETYL)PEROXIDE (383-73-3)
• EPA Substance Registry System: BIS(TRIFLUOROACETYL)PEROXIDE (383-73-3)

Safety Data

• Safety Statements: A poison. May explode spontaneously at room temperature. Upon decomposition it emits toxic fumes of Fsup xmlns="">−/sup>. See also a target="_blank" href="lom/card_sa.tes?href=content/sax0021/sdp20097.xml&view=print">PEROXIDES, INORGANIC/a>; a target="_blank" href="lom/card_sa.tes?href=content/sax0021/sdp20098.xml&view=print">PEROXIDES, ORGANIC/a>.
• HazardClass: 3
• Hazardous Substances Data: 383-73-3(Hazardous Substances Data)

Upstream product

• 407-25-0 trifluoroacetic anhydride 

Downstream Products

• 75-46-7 trifluoromethan 
• 124-38-9 carbon dioxide 
• 146459-08-7 4-(5'-heptafluoropropyl-2'-thiazolylazo)-N,N-dimethylaniline 
• 402-52-8 methyl 4-(trifluoromethyl)phenyl ether 
• 454-90-0 3-(trifluoromethyl)anisole 
• 395-48-2 1-methoxy-2-(trifluoromethyl)benzene 
• 98-08-8 α,α,α-trifluorotoluene 
• 209333-86-8 8-(4-Benzyloxy-phenyl)-7-oxo-2-trifluoromethyl-7H-thieno[2,3-a]-quinolizine-10-carboxylic acid (2-methoxy-ethyl)-phenyl-amide 
• 98-56-6 4-chlorobenzotrifluoride 
• 98-15-7 3-chlorotrifluoromethylbenzene 
• 88-16-4 1-chloro-2-(trifluoromethyl)benzene 
• 2154-71-4 bis-trifluoromethyl-aminooxyl 
• 2923-18-4 sodium 2,2,2-trifluoroacetate 
• 334-99-6 trifluoronitrosomethane 

Relevant articles and documents

A novel catalytic pathway for perfluoroacyl peroxide synthesis

matrix presented A new catalytic method for synthesis of bis(perfluoroacyl) peroxides (BPFAP) was elaborated by using hydrogen peroxide and perfluoroacyl anhydrides. The desired BPFAP were formed quantitatively in situ when perfluoroacyl anhydride was mixed with hydrogen peroxide (ratio ≥ 2:1) in the presence of a catalytic amount of the carboxylate RfCOO- M+. The essentially irreversible character of this process was shown experimentally and supported on the basis of DFT calculations. The synthesis of new acetyltrifluoroacetyl peroxides is also described.