392302-53-3

Basic information

• Product Name: 2-Propen-1-one, 1-[2-(acetyloxy)-4,6-dimethoxyphenyl]-2-bromo-3-(3,4-dimethoxyphenyl) -, (2Z)-
• CAS NO: 392302-53-3
• Molecular Formula: C21H21BrO7
• Molecular Weight: 465.298
• Mol File: 392302-53-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-one, 1-[2-(acetyloxy)-4,6-dimethoxyphenyl]-2-bromo-3-(3,4-dimethoxyphenyl) -, (2Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-one, 1-[2-(acetyloxy)-4,6-dimethoxyphenyl]-2-bromo-3-(3,4-dimethoxyphenyl) -, (2Z)-(392302-53-3)
• EPA Substance Registry System: 2-Propen-1-one, 1-[2-(acetyloxy)-4,6-dimethoxyphenyl]-2-bromo-3-(3,4-dimethoxyphenyl) -, (2Z)-(392302-53-3)

Safety Data

• Hazardous Substances Data: 392302-53-3(Hazardous Substances Data)

Upstream product

• 54987-77-8 3.4.4'.6'-tetramethoxy-2'-acetoxy-trans-chalcone 
• 95697-80-6 Acetic acid 2-[2,3-dibromo-3-(3,4-dimethoxy-phenyl)-propionyl]-3,5-dimethoxy-phenyl ester 

Downstream Products

• 855-97-0 2-(3,4-dimethoxyphenyl)-5,7-dimethoxy-4H-chromen-4-one 

Relevant articles and documents

An environmentally benign synthesis of aurones and flavones from 2′-acetoxychalcones using n-tetrabutylammonium tribromide

A wide variety of aurones (3a-f) can be prepared exclusively from 2′-acetoxychalcones (1a-f) in high yields in two steps, by bromination using n-tetrabutylammonium tribromide (TBATB) in the presence of CaCO3 in CH2Cl2-MeOH (5:2) at 0-5°C followed by cyclization of the brominated products 2a-f on treating with 0.2 M ethanolic KOH solution at 0-5°C, respectively. In contrast various flavone derivatives 6a-f can be obtained exclusively from compounds 1a-f in fairly good yields, by brominating with the same reagent in CH2Cl2, followed by dehydrobromination and finally cyclization on treating with 0.1 M NaOMe solution.