3927-60-4

Basic information

• Product Name: Methylhydrogenhendecanedioate
• Synonyms: Methylhydrogenhendecanedioate;Undecanedioic acid 1-methyl ester;Undecanedioic acid hydrogen 1-methyl ester;Nsc38783;Undecanedioic acid, monomethyl ester;11-METHOXY-11-OXOUNDECANOIC ACID
• CAS NO: 3927-60-4
• Molecular Formula: C₁₂H₂₂O₄
• Molecular Weight: 228.2848
• Mol File: 3927-60-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 340.2 °C at 760 mmHg
• Flash Point: 121 °C
• Appearance: /
• Density: 1.024 g/cm³
• Vapor Pressure: 1.6E-05mmHg at 25°C
• Refractive Index: 1.455
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: Methylhydrogenhendecanedioate(CAS DataBase Reference)
• NIST Chemistry Reference: Methylhydrogenhendecanedioate(3927-60-4)
• EPA Substance Registry System: Methylhydrogenhendecanedioate(3927-60-4)

Safety Data

• Hazardous Substances Data: 3927-60-4(Hazardous Substances Data)

Usage

General Description

Methylhydrogenhendecanedioate, also known as methyl 11-oxohendecanedioate, is a chemical compound with the molecular formula C13H24O4. It is a diester and is derived from the condensation of 1,11-undecanedioic acid with methanol. Methylhydrogenhendecanedioate is used in the synthesis of various organic compounds and can also be used as a precursor for the preparation of pharmaceuticals, agrochemicals, and specialty chemicals. Methylhydrogenhendecanedioate is a colorless liquid with a slightly fruity odor and is slightly soluble in water. It is important to handle this chemical compound with care as it may cause irritation to the skin, eyes, and respiratory system if not properly handled.

InChI:InChI=1/C12H22O4/c1-16-12(15)10-8-6-4-2-3-5-7-9-11(13)14/h2-10H2,1H3,(H,13,14)

Upstream product

• 112-62-9 Methyl oleate 

Downstream Products

• 50816-21-2 12-tetrahydropyranyloxy-3-dodecyne 
• 19754-59-7 tetrahydro-2-(9-tetradecynyloxy)pyran 
• 16974-11-1 (Z)-9-dodecenyl acetate 
• 17643-36-6 9-decyn-1-ol 
• 35153-15-2 (Z)-9-tetradecen-1-ol 
• 53939-27-8 (Z)-9-tetradecenal 
• 60037-69-6 9-tetradecyn-1-ol 
• 61319-25-3 9-tetradecyn-1-yl acetate 
• 1642-49-5 dec-9-ynoic acid 
• 19754-58-6 2-dec-9-ynyloxy-tetrahydro-pyran 
• 113976-33-3 2-{4-[(2,4-Diamino-pteridin-6-ylmethyl)-methyl-amino]-benzoylamino}-undecanedioic acid dimethyl ester 
• 113976-25-3 2-{4-[(2,4-Diamino-pteridin-6-ylmethyl)-methyl-amino]-benzoylamino}-undecanedioic acid 
• 18417-00-0 (12S)-12-hydroxyoctadecanoic acid 
• 106-14-9 12-Hydroxystearic acid 

Relevant articles and documents

A detailed identification study on high-temperature degradation products of oleic and linoleic acid methyl esters by GC-MS and GC-FTIR

GC-MS and GC-FTIR were complementarily applied to identify oxidation compounds formed under frying conditions in methyl oleate and linoleate heated at 180 °C. The study was focused on the compounds that originated through hydroperoxide scission that remain attached to the glyceridic backbone in fats and oils and form part of non-volatile molecules. Twenty-one short-chain esterified compounds, consisting of 8 aldehydes, 3 methyl ketones, 4 primary alcohols, 5 alkanes and 1 furan, were identified. In addition, twenty non-esterified volatile compounds, consisting of alcohols, aldehydes and acids, were also identified as major non-esterified components. Furanoid compounds of 18 carbon atoms formed by a different route were also identified in this study. Overall, the composition of the small fraction originated from hydroperoxide scission provides a clear idea of the complexity of the new compounds formed during thermoxidation and frying.