39602-93-2

Basic information

• Product Name: 4-aMino-1-Methyl-4H-1,2,4-triazol-1-iuM iodide
• Synonyms: 4-aMino-1-Methyl-4H-1,2,4-triazol-1-iuM iodide;4H-1,2,4-TriazoliuM, 4-aMino-1-Methyl-, iodide;4-Amino-1-methyl-1,2,4-triazolium iodide;4-AMino-1-Methyl-1,2,4-triazoliuM iodid
• CAS NO: 39602-93-2
• Molecular Formula: C₃H₇N₄*I
• Molecular Weight: 226.01895
• EINECS: -0
• Mol File: 39602-93-2.mol
• Article Data: 10

Chemical Properties

• Melting Point: 101℃
• Appearance: /
• Density: 1.98 g/cm3
• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C
• CAS DataBase Reference: 4-aMino-1-Methyl-4H-1,2,4-triazol-1-iuM iodide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-aMino-1-Methyl-4H-1,2,4-triazol-1-iuM iodide(39602-93-2)
• EPA Substance Registry System: 4-aMino-1-Methyl-4H-1,2,4-triazol-1-iuM iodide(39602-93-2)

Safety Data

• Hazardous Substances Data: 39602-93-2(Hazardous Substances Data)

Usage

General Description

4-Amino-1-methyl-4H-1,2,4-triazol-1-ium iodide is a chemical compound with the formula C4H7N4I. It is a quaternary ammonium salt that has applications in organic synthesis and pharmaceutical research. The compound is a derivative of 1,2,4-triazole, which is a five-membered heterocyclic compound containing three nitrogen atoms and two carbon atoms. 4-Amino-1-methyl-4H-1,2,4-triazol-1-ium iodide is used as a precursor in the synthesis of other organic compounds, and its properties make it suitable for use in various chemical reactions. It is important to handle this compound with care and follow safety protocols when working with it in a laboratory setting.

Upstream product

• 584-13-4 4-amino-1,2,4-triazole 
• 74-88-4 methyl iodide 

Downstream Products

• 7727-37-9 nitrogen 
• 7664-41-7 ammonia 
• 10034-85-2 hydrogen iodide 
• 7553-56-2 iodine 
• 74-88-4 methyl iodide 
• 1382039-29-3 N-(1-methyl-1H-1,2,4-triazol-4-ium-4-yl)(tosyl)amide 
• 817177-66-5 1-methyl-4-amino-1,2,4-triazolium nitrate 
• 817177-67-6 1-methyl-4-amino-1,2,4-triazolim perchlorate 

Relevant articles and documents

Pairing heterocyclic cations with closo-lcosahedral borane and carborane anions. i. benchtop aqueous synthesis of binary triazolium and imidazolium salts with limited water solubility

Ten new salts that pair triazolium and imidazolium cations with c/oso-icosahedral anions [B12H12]2 and [B 11H12]-were synthesized in water solvent using an open-air, benchtop method. These unreported [Heterocyclium] 2[B12H12] and [Heterocyclium][CB 12H12] salts extend reports of [Imidazolium][CB 12H12] and [Pyridinium][CB12H12] salts that were synthesized in anhydrous organic solvents under an inert atmosphere with glovebox or Schlenk techniques. Spectroscopic data, melting points, and densities are reported for each salt. Single-crystal X-ray structures are provided for the five new [B12H12] 2- salts.

Halogen free 1,2,3- and 1,2,4-triazolide based ionic liquids: Synthesis and properties

Triazoles have been successfully used as building blocks to create "fully organic" ILs featuring on both sides organic ions, i.e., 1,2,3- or 1,2,4-triazolide anions and 1,2,4-triazolium or imidazolium cations. Glass transition temperatures, densities and viscosities of these ILs were determined. Their electrochemical and thermal stability, and also conductivity, are higher than those for known ILs.

Pairing heterocyclic cations with closo-icosahedral borane and carborane anions, II: Benchtop alternative synthetic methodologies for binary triazolium and tetrazolium salts with significant water solubility

Two efficient processes for the synthesis of 12 relatively water-soluble binary triazolium and the first tetrazolium borane [B12H12] and carborane [CB11H12] salts by a one-step, open-air metathesis reaction have been developed. First, a combination of exhaustive trituration of the two solid reactant salts with refluxing anhydrous acetonitrile followed by flash filtration through a plug of silica gel afforded excellent recovery for a broad series of otherwise water-soluble heterocyclium salts. Second, an alternative aqueous metathesis, driven to completion by precipitation of silver halides, followed by removal of water, redissolution in acetonitrile, and filtration through a silica-gel plug, also yielded such heterocyclium borane and carborane salts. Mixed 1:1 dication heterocyclium borane salts were first synthesized using this second procedure, and one example showed melting-point depression behavior. Taylor & Francis Group, LLC.