3978-58-3Relevant articles and documents
Bulatov et al.
, p. 995,999 (1963)
Method for stabilizing unsaturated organo-silicon compounds
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Page 7, (2008/06/13)
Process for stabilizing organosilicon compounds (II) containing an unsaturated group of the vinyl, acrylic ester or vinyl ether type, during production, distillation and/or storage, comprises preparing (II) by reacting a haloalkylsilane with a salt of an unsaturated organic acid in the presence of alkylene-bis(dialkylphenol) compounds (I). Process for stabilizing organosilicon compounds of formula (II) containing an unsaturated group of the vinyl, acrylic ester or vinyl ether type, during production, distillation and/or storage, comprises preparing (II) by reacting a haloalkylsilane with a salt of an unsaturated organic acid in the presence of alkylene-bis(dialkylphenol) compounds of formula (I); [Image] H2C=C(R4>)[C(O)O]w(O)x-(R5>)y-Si(R6>)z(OR7>)3-z (II); R4>H or linear or branched 1-10 C hydrocarbyl; R5>linear, cyclic or branched 1-40 C hydrocarbyl, optionally containing heteroatom(s) selected from N, O, S or P; R6>, R7>linear, cyclic or branched 1-10 C hydrocarbyl; w, x : 0 or, in one case only, 1; y : 0 or 1; z : 0, 1 or 2; R1>, R2>linear or branched 1-20 C alkyl; R3>H or linear or branched 1-20 C alkyl.