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4017-38-3

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4017-38-3 Usage

Type of compound

Cyclic amine an amine compound that forms a ring structure.

Substitution

Substituted aziridine a derivative of aziridine with a tert-butyl group attached.

Usage

Building block in organic synthesis used as an intermediate to create more complex organic compounds.

Applications

Production of pharmaceuticals, agrochemicals, and other fine chemicals utilized as an intermediate in the synthesis of various chemical products.

Chiral auxiliary potential

Asymmetric synthesis the presence of a stereogenic center makes it useful in the creation of chiral molecules.

Reactivity

Nucleophiles and electrophiles the compound can react with both nucleophilic and electrophilic reagents, making it versatile in organic synthesis.

Safety precautions

Potential to cause irritation can cause skin, eye, and respiratory system irritation, requiring careful handling.

Check Digit Verification of cas no

The CAS Registry Mumber 4017-38-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,0,1 and 7 respectively; the second part has 2 digits, 3 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 4017-38:
(6*4)+(5*0)+(4*1)+(3*7)+(2*3)+(1*8)=63
63 % 10 = 3
So 4017-38-3 is a valid CAS Registry Number.
InChI:InChI=1/C6H13N/c1-6(2,3)7-4-5-7/h4-5H2,1-3H3

4017-38-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-tert-butylaziridine

1.2 Other means of identification

Product number -
Other names 1-tert-Butyaziridine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4017-38-3 SDS

4017-38-3Upstream product

4017-38-3Downstream Products

4017-38-3Relevant articles and documents

Acid-Catalyzed Decomposition of 1-Alkyltriazolines: A Mechanistic Study

Smith, Richard H.,Wladkowski, Brian D.,Taylor, Jesse E.,Thompson, Erin J.,Pruski, Brunon,et al.

, p. 2097 - 2103 (2007/10/02)

1-Alkyltriazolines are five-membered cyclic triazenes containing the unusual Z-configuration for the triazene moiety.The hydrolytic decomposition of these compounds in aqueous or mixed acetonitrile-aqueous buffers leads predominantly to the formation of the corresponding 1-alkylaziridines and lesser amounts of 2-(alkylamino)ethanols, alkylamines, and acetaldehyde.The latter two products presumably result from hydrolysis of a rearrangement produkt, N-ethylidenealkylamine.Neither the nature of the 1-alkyl group nor the pH of the medium greatly influences the product distribution, although decomposition in purely aqueous buffers slightly reduces the aziridine yields.The rate of hydrolysis of 1-alkyltriazolines is about twice as fast as that of the analogous acyclic 1,3,3-trialkyltriazenes and varies in the order tert-butyl > isopropyl > ethyl > butyl > methyl > propyl > benzyl.The mechanism of the decomposition is specific acid-catalyzed (A1) involving rapid reversible protonation followed by rate-limiting formation of a 2-(alkylamino)ethyldiazonium ion.The slopes of the log kobs versus pH plots are near -1.0.The solvent deuterium isotope effect, kH2O/kD2O, is in all cases methyl > ethyl.

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