40414-70-8

Basic information

• Product Name: 2-Propen-1-one, 3-ethoxy-1-phenyl-
• CAS NO: 40414-70-8
• Molecular Formula: C11H12O2
• Molecular Weight: 176.215
• Mol File: 40414-70-8.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 2-Propen-1-one, 3-ethoxy-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propen-1-one, 3-ethoxy-1-phenyl-(40414-70-8)
• EPA Substance Registry System: 2-Propen-1-one, 3-ethoxy-1-phenyl-(40414-70-8)

Safety Data

• Hazardous Substances Data: 40414-70-8(Hazardous Substances Data)

Upstream product

• 98-86-2 acetophenone 
• 109-94-4 formic acid ethyl ester 
• 98-88-4 benzoyl chloride 
• 109-92-2 ethyl vinyl ether 
• 74-96-4 ethyl bromide 

Downstream Products

• 1034638-31-7 3-hydroxy-4-(3-phenylpropyl)biphenyl-2-carboxylic acid methyl ester 
• 1034638-35-1 C₁₁H₁₁BrO₂ 
• 606-86-0 1,3,3-triphenylpropan-1-one 
• 1443678-71-4 2-iodo-3-ethoxy-1-phenylprop-2-en-1-one 
• 1443678-84-9 4-iodo-2-phenyl-5-(4-methoxy)phenylfuran-3-carbaldehyde 
• 1443678-83-8 4-iodo-2,5-diphenylfuran-3-carbaldehyde 
• 1443678-87-2 3-benzoyl-4-iodo-5-phenylfuran 
• 1443678-74-7 (E)-3-ethoxy-1-phenyl-2-(phenylethynyl)prop-2-en-1-one 
• 1140530-70-6 methyl 3-phenylsulfanylbiphenyl-2-carboxylate 
• 1140530-71-7 methyl 3-(4-chlorophenylsulfanyl)biphenyl-2-carboxylate 
• 69413-39-4 3-phenyl-pyrazole-1-carboxylic acid amide 
• 1006-65-1 3-phenylisoxazole 
• 4492-01-7 1,3-diphenyl-1H-pyrazole 
• 3617-16-1 Benzoylacetaldehyde ω-semicarbazone 

Relevant articles and documents

Enol ethers and acetals: Acylation with dichloroacetyl, acetyl and benzoyl chloride in ionic liquid medium

Synthesis of 4-alkoxy-1,1-dichloro-3-alken-2-ones [CHCl2C(O) C(R2)C(R1)-OR, where R, R1, R2 = Et, H, H; Me, Me, H; Et, H, Me; Me, -(CH2)2-; Me, -(CH 2)3-; Et, Et, H; Et, Bu, H; Et, i-Pr, H; Et, i-Bu, H; Me, Ph, H; Me, thien-2-yl, H] from acylation of enol ethers and acetals with dichloroacetyl chloride, in ionic liquid ([BMIM][BF4] or [BMIM][PF6]) is reported. The synthesis of alkenones [R 3-C(O)C(R2)C(R1)-OR], where R/R 1/R2/R3 = Et/H/H/Ph, t-Bu/H/H/Ph, Me/-(CH 2)4/Ph, Me/-(CH2)4/Me] from the reaction of enol ethers with benzoyl chloride or acetyl chloride, in ionic liquid [BMIM][BF4], is also reported. Last products are described for the first time.

Cyclo-ruthenated and -platinated complexes bearing phosphonate substituents

Two new, potentially cyclometalating terdentate ligands bearing phosphonate substituents, Et2O3P-N^C(H)^N (5) and Et2O3P-C(H)^N^N (7), have been prepared. The corresponding ruthenium complexes, [1]+ and [2]+, respectively, were obtained by reaction with [RuCl3(tpy)]. Complexes [1]+ and [2]+ display electronic properties characteristic for cyclometalated ruthenium complexes. The platinum complex [3], of N^C(H)^N ligand 5, was also prepared and is highly phosphorescent in solution. In general, the phosphonate group electronically behaves equivalent to a carboxylate moiety.

Synthesis of functionalized biaryls based on a heck cross-coupling-[3+3] cyclization strategy

6-Arylsalicylates were regioselectively prepared by formal [3+3] cyclization of 1,3-bis(silyloxy)-1,3-butadienes with 1-aryl-3-ethoxyprop-2-en-1- ones which are available by Heck reaction of benzoyl chlorides with ethylvinyl ether. In this context, the first [3+3] cyclizations of brominated substrates are reported. Georg Thieme Verlag Stuttgart.