4044-58-0

Basic information

• Product Name: 1-BROMO-8-IODONAPHTHALENE
• Synonyms: 1-BROMO-8-IODONAPHTHALENE;BIN;8-Bromo-1-iodonaphthalene
• CAS NO: 4044-58-0
• Molecular Formula: C₁₀H₆BrI
• Molecular Weight: 332.961
• Mol File: 4044-58-0.mol
• Article Data: 6

Chemical Properties

• Melting Point: 99.0 to 103.0 °C
• Boiling Point: 168°C/0.7mmHg(lit.)
• Appearance: /
• Density: 2.057±0.06 g/cm3(Predicted)
• CAS DataBase Reference: 1-BROMO-8-IODONAPHTHALENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-BROMO-8-IODONAPHTHALENE(4044-58-0)
• EPA Substance Registry System: 1-BROMO-8-IODONAPHTHALENE(4044-58-0)

Safety Data

• Hazardous Substances Data: 4044-58-0(Hazardous Substances Data)

Usage

General Description

1-Bromo-8-iodonaphthalene is a chemical compound with the molecular formula C10H6BrI. It is a naphthalene derivative that contains both bromine and iodine atoms. 1-Bromo-8-iodonaphthalene is commonly used as a building block in organic synthesis and as a reagent in various chemical reactions. It is also employed in the synthesis of pharmaceuticals and agrochemicals. 1-Bromo-8-iodonaphthalene has been studied for its potential applications in fields such as medicinal chemistry and materials science due to its unique chemical properties. Additionally, it is important to handle this compound with care as it can be hazardous if not properly managed.

Upstream product

• 17135-74-9 1,8-dibromonaphthalene 
• 479-27-6 naphthalene-1,8-diamine 
• 1730-04-7 1,8-diiodonaphthalene 
• 1729-99-3 8-bromonaphthalene-1-carboxylic acid 
• 62456-34-2 1-amino-8-bromonaphthalene 

Downstream Products

• 4044-55-7 1-bromo-8-(phenylethynyl)naphthalene 
• 569-41-5 1,8-dimethylnaphthalene 
• 33295-37-3 1-bromo-8-methylnaphthalene 
• 350600-06-5 1-bromo-8-(5-tert-butyl-2,3-bis(trimethylsilylethynyl)phenyl)naphthalene 
• 321148-68-9 (8-bromo-naphth-1-yl)di(phenyl)phosphine 
• 372112-69-1 di(4-fluorophenyl)(8-bromo-1-naphthyl)phosphine 
• 372112-70-4 1-[8-(diethylphosphino)-1-naphthyl]-1-fluoro-1,2-dimethyl-2,2-diphenyldisilane 
• 372112-71-5 1-fluoro-1,2-dimethyl-2,2-diphenyl-1-[8-(diphenylphosphino)-1-naphthyl]disilane 
• 372112-72-6 1-fluoro-1-[8-[di(4-fluorophenyl)phosphino]-1-naphthyl]-1,2-dimethyl-2,2-diphenyldisilane 
• 130818-38-1 2-(8-Bromo-1-naphthyl)benzoic acid 

Relevant articles and documents

Photodissociation of B-N Lewis adducts: A partially fused trinaphthylborane with dual fluorescence

The synthesis of a planarized trinaphthylborane with partially fused structure is presented. This compound shows not only high chemical and thermal stability but also sufficient Lewis acidity to form Lewis adducts with pyridine derivatives in solution. The B-N Lewis adducts exhibit unprecedented photodissociation behavior in the excited state, reminiscent of the photogeneration of carbenium ions from triarylmethane leuco dyes. Consequently, these B-N Lewis adducts exhibit dual fluorescence emission arising from the initial tetracoordinate B-N adducts and the photodissociated tricoordinate boranes.

Divergent intramolecular reactions between phosphines and alkynes

A divergent intramolecular reaction of phosphine tethered alkyne in protic solvent was developed. This provided a novel and simple access to a large variety of (Z)-alkenylphosphine oxides and phospholane oxides. Our preliminary studies suggested that these divergent reactions are closely related to the reaction condition and molecular structure. A possible mechanism of C-P bond cleavage of a pentacoordinated hydroxyphosphorane intermediate was proposed.

Paving the Way to Novel Phosphorus-Based Architectures: A Noncatalyzed Protocol to Access Six-Membered Heterocycles

Phosphorus-based heterocycles provide access to materials with properties that are inaccessible from all-carbon architectures. The unique hybridization of phosphorus gives rise to electron-accepting capacities, a large variety of coordination reactions, a