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40709-82-8

40709-82-8

Identification

Synonyms:2-Chloroethylvinyl sulfoxide

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Safety information and MSDS view more

  • Signal Word:no data available

  • Hazard Statement:no data available

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician. In case of skin contact Wash off with soap and plenty of water. Consult a physician. In case of eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. If swallowed Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

  • Fire-fighting measures: Suitable extinguishing media Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Pick up and arrange disposal. Sweep up and shovel. Keep in suitable, closed containers for disposal.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

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Relevant articles and documentsAll total 2 Articles be found

N-doped, S-doped TiO2 nanocatalysts: Synthesis, characterization and photocatalytic activity in the presence of sunlight

Ramacharyulu,Nimbalkar, Dipak Bapurao,Kumar, J. Praveen,Prasad,Ke, Shyue-Chu

, p. 37096 - 37101 (2015/05/13)

N doped and S doped nano TiO2 catalysts were synthesized by a sol-gel process followed by hydrothermal treatment at low temperature and tested for catalytic activity by natural sunlight photocatalytic degradation of a toxic chemical warfare agent. It is observed that sulfate groups were anchored on the surface of titania upon doping, and also create active surface oxygen vacancies, both of which are responsible for sunlight absorption and the promotion of electrons to the conduction band. The formation of a superoxide radical (O2-) and hydroxyl radicals may be mainly responsible for the photodegradation of sulfur mustard under sunlight.

Sunlight assisted photocatalytic detoxification of sulfur mustard on vanadium ion doped titania nanocatalysts

Ramacharyulu,Praveen Kumar,Prasad,Singh,Sreedhar,Dwivedi

, p. 38 - 44 (2014/04/03)

Photocatalytic detoxification of sulfur mustard was studied on vanadium ion doped titania nanocatalysts under the irradiation of sunlight. Data obtained on vanadium ion doped titania nanocatalyst was compared with that of bare and commercial TiO2/su

Process route upstream and downstream products

Process route

bis(2-chloroethyl)sulfoxide
5819-08-9

bis(2-chloroethyl)sulfoxide

divinyl sulfoxide
1115-15-7

divinyl sulfoxide

Divinyl sulfone
77-77-0

Divinyl sulfone

1-(2-Chloroethylsulfinyl)ethene
40709-82-8

1-(2-Chloroethylsulfinyl)ethene

bis(2-chloroethyl)sulfone
471-03-4

bis(2-chloroethyl)sulfone

Conditions
Conditions Yield
Prod.5:<2-Chlor-aethyl>-vinyl-sulfon;
bis (2-chloroethyl) sulphide
505-60-2

bis (2-chloroethyl) sulphide

β-chloroethyl vinyl sulfide
81142-02-1

β-chloroethyl vinyl sulfide

1-(2-Chloroethylsulfinyl)ethene
40709-82-8

1-(2-Chloroethylsulfinyl)ethene

carbon dioxide
124-38-9,18923-20-1

carbon dioxide

acetaldehyde
75-07-0,9002-91-9

acetaldehyde

Conditions
Conditions Yield
With S-doped TiO2; In dichloromethane;
bis (2-chloroethyl) sulphide
505-60-2

bis (2-chloroethyl) sulphide

β-chloroethyl vinyl sulfide
81142-02-1

β-chloroethyl vinyl sulfide

bis(2-chloroethyl)disulfide
1002-41-1

bis(2-chloroethyl)disulfide

1-(2-Chloroethylsulfinyl)ethene
40709-82-8

1-(2-Chloroethylsulfinyl)ethene

carbon dioxide
124-38-9,18923-20-1

carbon dioxide

acetaldehyde
75-07-0,9002-91-9

acetaldehyde

Conditions
Conditions Yield
With V0.001Ti0999O2; Reagent/catalyst; Catalytic behavior; Irradiation;

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