42858-50-4

Basic information

• Product Name: Cyclohexanone, 2-methyl-6-methylene-
• CAS NO: 42858-50-4
• Molecular Formula: C8H12O
• Molecular Weight: 124.183
• Mol File: 42858-50-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-methyl-6-methylene-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-methyl-6-methylene-(42858-50-4)
• EPA Substance Registry System: Cyclohexanone, 2-methyl-6-methylene-(42858-50-4)

Safety Data

• Hazardous Substances Data: 42858-50-4(Hazardous Substances Data)

Upstream product

• 62791-24-6 tert-butyl((2,6-dimethylcyclohex-1-en-1-yl)oxy)dimethylsilane 
• 19980-33-7 6-methyl-1-trimethylsiloxycyclohex-1-ene 
• 1194-91-8 3-methyl-2-oxo-cyclohexanecarbaldehyde 
• 63547-53-5 2,6-dimethyl-1-(trimethylsiloxy)cyclohexene 
• 50338-51-7 Trimethyl-(2-methyl-bicyclo[4.1.0]hept-1-yloxy)-silane 
• 69843-61-4 2-Methoxymethyl-6-methylcyclohexanon 

Relevant articles and documents

Synthesis of α,β-unsaturated carbonyl compounds via a visible-light-promoted organocatalytic aerobic oxidation

α,β-Unsaturated ketones and aldehydes have been synthesized from their corresponding silyl enol ethers in a straightforward protocol involving a visible-light promoted organocatalytic, aerobic oxidation reaction. A cheap organic dye was used catalytically in these reactions as the photosensitizer.

A Simple, Effective, New, Palladium-Catalyzed Conversion of Enol Silanes to Enones and Enals

Enol silanes derived from aldehydes and ketones are readily converted to the corresponding α,β-unsaturated carbonyl compounds by 10percent Pd(OAc)2 in the presence of one atmosphere of oxygen in DMSO as the solvent.