4422-95-1Relevant articles and documents
Synthesis and geometric structure of N, N, N'-tris(Benzoyl)trimesinic acid dihydrazide
Cai, Yan-Hua,Zhao, Li-Sha,Ren, Li-Ping,Wang, Feng
, p. 9356 - 9358 (2013)
N, N, N'-Tris(benzoyl) trimesinic acid dihydrazide was synthesized from benzoyl hydrazine and trischloride and the structures of N,N,N'- tris(benzoyl) trimesinic acid dihydrazide had been characterized by Fourier transform infrared spectroscopy, 1H nuclear magnetic resonance techniques. The reaction condition was investigated by orthogonal experiment and the optimized reaction condition by orthogonal experiment is molar ratio of benzoyl hydrazine: trischloride 5:1, reaction time 4 h, reaction temperature 70°C, the yield is 65.7 %. SEM showed the particles of N,N,N'-tris(benzoyl)trimesinic acid dihydrazide were not completely regular and the average size of the particles was 3-4 μm. At the same time, the optimized geometric structure of N,N,N'-tris(benzoyl)trimesinic acid dihydrazide was carried out by theoretical calculations using the semiempirical method PM3.
Uncommon hexagonal microtubule based gel from a simple trimesic amide
Shi, Naien,Yin, Gui,Li, Hongbian,Han, Min,Xu, Zheng
, p. 2011 - 2015 (2008)
A small molecule of N,N′,N″-tris(3-methylpyridyl)-trimesic amide was assembled into a novel hexagonal microtube through intermolecular hydrogen bonds, and simultaneously formed a gel system in H2O-THF mixed solvent. Tuning gelator concentration or the preparation method can effectively control the size of the hexagonal tubes. The Royal Society of Chemistry and the Centre National de la Recherche Scientifique 2008.
Cobalt Metallogel Interface for Selectively Sensing l -Tryptophan among Essential Amino Acids
Malviya, Novina,Sonkar, Chanchal,Ganguly, Rakesh,Mukhopadhyay, Suman
, p. 7324 - 7334 (2019)
The development of metallogels widens the span of sensing activity as it opens new opportunities to develop chemosensors through metal-ligand interactions. Herein, a new nitrile-substituted 1,3,5-tricarboxamide-based gelator G4 has been fabricated and shows aggregate-induced enhanced emission (AIEE) after gelation in the presence of water. A dimethylformamide (DMF) solution of the gelator shows rapid crystallization, but addition of water to a DMF solution of gelator G4 leads to gelation at room temperature. In addition, gelator G4 was used for the formation of metallogels, and among them, the cobalt metallogel has been found to be effective for sensing l-tryptophan in the gel state through the quenching of AIEE. Interestingly, the gel is also effective in sensing bovine serum albumin protein at the nanomolar level, which contains an l-tryptophan residue. The limit of detection of Co(II)G4 for selective sensing of tryptophan has been found to be 2.4 × 10-8 M. To the best of our knowledge, there have been no reports to date of a metallogel being utilized to discriminate and selectively sense an amino acid and a protein. The gelation properties of the organic gelator molecule and metallogels have been explored through various spectroscopic tools and physicochemical experiments.
Tuning of Bistability, Thermal Stability of the Metastable States, and Application Prospects in the C3-Symmetric Designs of Multiple Azo(hetero)arenes Systems
Gupta, Debapriya,Gaur, Ankit Kumar,Kumar, Pravesh,Kumar, Himanshu,Mahadevan, Anjali,Devi, Sudha,Roy, Saonli,Venkataramani, Sugumar
supporting information, p. 3463 - 3472 (2021/01/21)
Light-responsive molecular systems with multiple photoswitches in C3-symmetric designs have enormous application potential. The design part of such molecular systems is critical due to its influence in several properties associated with the photoswitches. In order to tune, and in the evaluation of the design–property relationship, we synthesized 18 tripodal systems with variations in the core, linkers, connectivity, and azo(hetero)arene photoswitches. Through extensive spectroscopic and computational studies, we envisaged the factors controlling near-quantitative photoisomerization in both the directions (bistability) and the thermal stability of the metastable states. Furthermore, we also evaluated the impact of designs in obtaining reversible photo-responsive sol-gel phase transitions, solvatochromism, photo- and thermochromism.
Instant Photochromism Caused by Radical Formation in Photocatalytic Decarboxylation of Dihydrothiazole Derivative?
Xu, Zhen,Malik, Abaid Ullah,Shu, Mouhai,Cui, Yong
, p. 2774 - 2780 (2021/08/09)
A pair of new enantiomeric compounds, (R)/(S)-1,3,5-benzene-triyl-2,2',2”-tris(4,5-dihydrothiazole-4-carboxylic acid) (H3LRRR and H3LSSS) are synthesized in one step synthetic route with high yield. Instant photochromism has been investigated to elaborate the photocatalytic decarboxylation of the dihydrothiazole derivative by electron paramagnetic resonance spectroscopy (EPR), photoluminescence (PL), FT-IR, high resolution mass spectra, X-ray photoelectron spectroscopy and UV-Vis spectroscopic techniques. The results indicate that the photochromic transformation is originated from the formation of the radical during the photocatalytic decarboxylation of the 4,5-dihydrothiazole-4-carboxylic acid units.
C3 The symmetry contains a chiral ligand H3L of an amide bond. Preparation method and application
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Paragraph 0071-0074, (2021/09/08)
The invention discloses C. 3 Chiral ligand H with symmetric amide bond3 L Relates to the technical field of material chemistry and chiral chemistry. The invention further provides the chiral ligand H. 3 L Preparation method and application thereof. The present invention has the advantage that the chiral ligand H of the present invention is a chiral ligand. 3 The L has a higher C. 3 The symmetric and flexible amide group enables coordination of the lanthanide metal ions with high coordination number and high oxygen affinity to be assembled into a novel structure-structure lanthanide metal chiral porous coordination cage. Moreover, the abundant chiral amide groups and amino acid residues on the ligand framework can be directly introduced into the synthesized lanthanide metal chiral porous coordination cage, thereby being beneficial to generating multiple chiral recognition sites and unique chiral microenvironments which mimic the biological enzyme binding pocket and further realize the purpose of high enantioselectivity separation of a series of chiral small molecule compounds.