444-40-6

Basic information

• Product Name: Lithium, [2,4,6-tris(trifluoromethyl)phenyl]-
• CAS NO: 444-40-6
• Molecular Formula: C9H2F9Li
• Molecular Weight: 288.042
• Mol File: 444-40-6.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Lithium, [2,4,6-tris(trifluoromethyl)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Lithium, [2,4,6-tris(trifluoromethyl)phenyl]-(444-40-6)
• EPA Substance Registry System: Lithium, [2,4,6-tris(trifluoromethyl)phenyl]-(444-40-6)

Safety Data

• Hazardous Substances Data: 444-40-6(Hazardous Substances Data)

Upstream product

• 729-81-7 1,3,5-tris(trifluoromethyl)benzene 

Downstream Products

• 137364-24-0 bis{2,4,6-tris(trifluoromethyl)phenyl}zinc 
• 114071-31-7 bis{2,4,6-tris(trifluoromethyl)phenyl}mercury 
• 147530-92-5 ((CF₃)3C₆H₂)2InIn(C₆H₂(CF₃)3)2 
• 147530-93-6 In((CF₃)3C₆H₂)3 
• 114071-30-6 trimethyl{2,4,6-tris(trifluoromethyl)phenyl}tin 
• 508194-38-5 chlorobis[2,4,6-tris(trifluoromethyl)phenyl]germane 
• 801319-55-1 trans-[Pd(Fmes)2(SMe₂)2] 
• 681294-36-0 trans-[PdCl(2,4,6-tris(trifluoromethyl)phenyl)(SMe₂)2] 
• 681459-85-8 [Pd(μ-Cl)(2,4,6-tris(trifluoromethyl)phenyl)(SMe2)]2 
• 650583-81-6 trichloro[2,4,6-tris(trifluoromethyl)phenyl]germane 
• 650583-80-5 dichlorobis[2,4,6-tris(trifluoromethyl)phenyl]germane 
• 681294-41-7 [PdCl(2,4,6-tris(trifluoromethyl)phenyl)(N,N,N',N'-tetramethylethylenediamine)] 
• 192823-42-0 BCl(C₆H₂(CF₃)3)2 
• 192823-39-5 [(BO(C₆H₂(CF₃)3)2)Li(C₄H₈O)]2 

Relevant articles and documents

Crystallization-induced emission enhancement of highly electron-deficient dicyanomethylene-bridged triarylboranes

A highly electron-deficient dicyanomethylene-bridged triarylborane,FMesB-TCN, was reported with a low-lying LUMO and crystallization-induced emission enhancement in its block-shape crystal. DFT calculations revealed lower re-organization energy

Highly Electron-Deficient Dicyanomethylene-Functionalized Triarylboranes with Low-Lying LUMO and Strong Lewis Acidity

A series of dicyanomethylene-functionalized triarylboranes is reported in this work, with low-lying LUMO energy levels at ca. -3.66 eV for FMesB-ACN. The single-crystal structures of the mono- and dianion of Mes*B-ACN were obtained via chemical reduction,

Synthesis and characterisation of some new boron compounds containing the 2,4,6-(CF3)3C6 H2 (fluoromes = Ar), 2,6-(CF3)2C6H3 (fluoroxyl = Ar′), or 2,4-(CF3)2 C6H3 (Ar″) ligands

Several new boron compounds containing the 2,4,6- (CF3)3C6H2 (fluoromes = Ar), 2,6-(CF3)2C6H3 (fluoroxyl = Ar′) or 2,4-(CF3)2C6H3 (Ar″) ligands have been synthesised from reactions of ArLi, Ar′Li or Ar″Li with BCl3, and characterised by 19F and 11B NMR spectroscopy. Chlorine/fluorine exchanges are evident in these reactions. The crystal and molecular structures of Ar2BF, Ar″3B, Ar2B(OH), Ar′B(OH)2 and Mes2BF (Mes = 2,4,6-Me3C6H2) have been determined by single crystal X-ray diffraction. Ar″3B represents the first example of a compound containing three Ar″ ligands to be structurally characterised. Molecular geometries and GIAO-NMR shifts for several new boron compounds have been calculated at the HF/6-31G* level of theory, and compared with the available experimental results.