4548-25-8Relevant articles and documents
Tomato-produced 7-epizingiberene and R-curcumene act as repellents to whiteflies
Bleeker, Petra M.,Diergaarde, Paul J.,Ament, Kai,Schütz, Stefan,Johne, Bettina,Dijkink, Jan,Hiemstra, Henk,De Gelder, René,De Both, Michiel T.J.,Sabelis, Maurice W.,Haring, Michel A.,Schuurink, Robert C.
, p. 68 - 73 (2011)
How whiteflies (Bemisia tabaci) make the choice for a host plant prior to landing, is not precisely known. Here we investigated whether they respond to specific volatiles of tomato. Zingiberene and curcumene were purified from Solanum habrochaites (PI1278
Stereospecific Hydrogenolysis of Lactones: Application to the Total Syntheses of (R)-ar-Himachalene and (R)-Curcumene
Spielmann, Kim,De Figueiredo, Renata Marcia,Campagne, Jean-Marc
, p. 4737 - 4743 (2017/05/12)
A straightforward strategy for the syntheses of curcumene and ar-himachalene is reported. Synthetic highlights include a catalytic and asymmetric vinylogous Mukaiyama reaction and a stereospecific hydrogenolysis of a tertiary benzylic center using Pd/C or Ni/Raney catalysts. Notably, using Ni/Raney, the stereoselectivity outcome (inversion vs retention) of the hydrogenolysis depends on the tertiary benzylic alcohol substitution.
PLANT VOLATILES BASED ON R-CURCUMENE
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Page/Page column 39; 40, (2010/09/18)
The invention provides a method for controlling whiteflies which comprises the steps of: providing a composition comprising or consisting of R-curcumene and optionally further beta-myrcene, para-cymene, gamma-terpinene, alpha-terpinene, alpha-phellandrene zingiberene and/or 7-epi-zingiberene; and adding said composition one or more times to a plurality of crop plants. The method can be combined with the use of attractant compositions comprising beta-phellandrene, limonene and/or 2-carene, and optionally adding said composition one or more times to one or more trap plants and/or trap materials.