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4719-04-4

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    Cas No: 4719-04-4

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4719-04-4 Usage

Description

Grotan BK is a triazine derivative contained in cutting fluids. It is a formaldehyde releaser.

Chemical Properties

Light Yellow Solid

Uses

Hexahydro-l,3,5-tris-(2-hydroxyethyl)triazin is used in organic synthesis; as a bactericide in cooling fluids and various cosmetic products; formaldehyde liberator.

General Description

Viscous yellow liquid.

Air & Water Reactions

Water soluble.

Reactivity Profile

Hexahydro-1,3,5-tris(hydroxyethyl)-s-triazine is an amine and an alcohol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Fire Hazard

Hexahydro-1,3,5-tris(hydroxyethyl)-s-triazine is probably combustible.

Flammability and Explosibility

Notclassified

Contact allergens

Grotan BK is a triazine derivative contained as a bio cide in cutting fluids. It is a formaldehyde releaser. Dermatitis, delayed-type allergic conjunctivitis, and asthma were described.

Check Digit Verification of cas no

The CAS Registry Mumber 4719-04-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,7,1 and 9 respectively; the second part has 2 digits, 0 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 4719-04:
(6*4)+(5*7)+(4*1)+(3*9)+(2*0)+(1*4)=94
94 % 10 = 4
So 4719-04-4 is a valid CAS Registry Number.

4719-04-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 18, 2017

Revision Date: Aug 18, 2017

1.Identification

1.1 GHS Product identifier

Product name s-Triazine-1,3,5-triethanol

1.2 Other means of identification

Product number -
Other names 2-[3,5-bis(2-hydroxyethyl)-1,3,5-triazinan-1-yl]ethanol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only. Corrosion inhibitors and anti-scaling agents,Fuels and fuel additives,Functional fluids (closed systems),Odor agents,Processing aids, not otherwise listed,Processing aids, specific to petroleum production
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:4719-04-4 SDS

4719-04-4Synthetic route

formaldehyd
50-00-0

formaldehyd

ethanolamine
141-43-5

ethanolamine

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

Conditions
ConditionsYield
In methanol at 20℃; for 16h;100%
In methanol for 48h;86%
With water
In ethanol Cyclization;
at 50 - 80℃; for 1h;92 g
5-(2-hydroxyethyl)hexahydro-1,3,5-dithiazine
88891-55-8

5-(2-hydroxyethyl)hexahydro-1,3,5-dithiazine

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

Conditions
ConditionsYield
at 100℃; under 0.12 Torr;85%
1,3-oxazolidine
504-76-7

1,3-oxazolidine

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

Conditions
ConditionsYield
at 25 - 30℃; unter Selbsterwaermung;
1,3,5-Trioxan
110-88-3

1,3,5-Trioxan

ethanolamine
141-43-5

ethanolamine

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

Conditions
ConditionsYield
In methanol at 20℃;
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

C9H22N3O6P

C9H22N3O6P

Conditions
ConditionsYield
With phosphorus pentoxide at 0 - 80℃; for 1h;96%
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

(E)-benzil monooxime
574-15-2

(E)-benzil monooxime

1-(2-hydroxyethyl)-4,5-diphenyl-1H-imidazole 3-oxide

1-(2-hydroxyethyl)-4,5-diphenyl-1H-imidazole 3-oxide

Conditions
ConditionsYield
In ethanol for 3h; Heating;89%
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

2,3-Butanedione monoxime
57-71-6, 17019-25-9, 110828-81-4

2,3-Butanedione monoxime

4,5-dimethyl-1H-imidazole-1-ethanol 3-oxide

4,5-dimethyl-1H-imidazole-1-ethanol 3-oxide

Conditions
ConditionsYield
In ethanol for 3h; Heating;88%
1-hydroximino-1-phenylacetone
29024-92-8

1-hydroximino-1-phenylacetone

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

5-methyl-4-phenyl-1H-imidazole-1-ethanol 3-oxide

5-methyl-4-phenyl-1H-imidazole-1-ethanol 3-oxide

Conditions
ConditionsYield
In ethanol for 3h; Heating;81%
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

1-(4-fluorophenyl)-2-(2-fluoro-4-pyridyl)ethane-1,2-dione 1-oxime
908382-43-4

1-(4-fluorophenyl)-2-(2-fluoro-4-pyridyl)ethane-1,2-dione 1-oxime

2-[4-(4-Fluorophenyl)-5-(2-fluoro-pyridin-4-yl)-3-oxy-imidazol-1-yl]-ethanol
1009308-69-3

2-[4-(4-Fluorophenyl)-5-(2-fluoro-pyridin-4-yl)-3-oxy-imidazol-1-yl]-ethanol

Conditions
ConditionsYield
In ethanol for 16h; Heating / reflux;80%
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

ethyl acetoacetate
141-97-9

ethyl acetoacetate

diethyl 3-acetyl-1-(2-hydroxyethyl)-6-methyl-1,2,3,4-tetrahydropyridine-3,5-dicarboxylate

diethyl 3-acetyl-1-(2-hydroxyethyl)-6-methyl-1,2,3,4-tetrahydropyridine-3,5-dicarboxylate

Conditions
ConditionsYield
In methanol at 65℃; for 5h; Reflux;80%
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

N-{4-[2-(4-fluorophenyl)-2-hydroxyliminoacetyl]pyridin-2-yl}acetamide
452056-82-5

N-{4-[2-(4-fluorophenyl)-2-hydroxyliminoacetyl]pyridin-2-yl}acetamide

N-{4-[5-(4-fluorophenyl)-1-oxy-3-(2-hydroxyethyl)-3H-imidazol-4-yl]pyridin-2-yl}acetamide
820241-16-5

N-{4-[5-(4-fluorophenyl)-1-oxy-3-(2-hydroxyethyl)-3H-imidazol-4-yl]pyridin-2-yl}acetamide

Conditions
ConditionsYield
In ethanol for 6h; Heating;71%
In ethanol Reflux;
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

acetic anhydride
108-24-7

acetic anhydride

A

1-acetoxy-2-nitro-2-aza-4-nitroxybutabe
71545-63-6

1-acetoxy-2-nitro-2-aza-4-nitroxybutabe

B

Hexahydro-1,3,5-trinitro-1,3,5-triazine
121-82-4

Hexahydro-1,3,5-trinitro-1,3,5-triazine

C

1-acetoxy-2,4,6-trinitro-2,4,6-triaza-8-nitroxyoctane
76237-14-4

1-acetoxy-2,4,6-trinitro-2,4,6-triaza-8-nitroxyoctane

Conditions
ConditionsYield
With ammonium nitrate; nitric acid In chloroform at 55 - 60℃; for 1h;A 41.3%
B n/a
C 62%
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

A

1-acetoxy-2-nitro-2-aza-4-nitroxybutabe
71545-63-6

1-acetoxy-2-nitro-2-aza-4-nitroxybutabe

B

Hexahydro-1,3,5-trinitro-1,3,5-triazine
121-82-4

Hexahydro-1,3,5-trinitro-1,3,5-triazine

C

1-acetoxy-2,4,6-trinitro-2,4,6-triaza-8-nitroxyoctane
76237-14-4

1-acetoxy-2,4,6-trinitro-2,4,6-triaza-8-nitroxyoctane

Conditions
ConditionsYield
With ammonium nitrate; nitric acid In chloroform; acetic anhydride at 55 - 60℃; for 1h;A 41.3%
B n/a
C 62%
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

(E)-2-(hydroxyimino)-1-phenylpropan-1-one
17019-26-0

(E)-2-(hydroxyimino)-1-phenylpropan-1-one

4-methyl-5-phenyl-1H-imidazole-1-ethanol 3-oxide

4-methyl-5-phenyl-1H-imidazole-1-ethanol 3-oxide

Conditions
ConditionsYield
In ethanol for 3h; Heating;55%
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

chromium(0) hexacarbonyl
199620-14-9, 13007-92-6

chromium(0) hexacarbonyl

Cr(CO)3(C9H21N3O3)
228705-18-8

Cr(CO)3(C9H21N3O3)

Conditions
ConditionsYield
In tetrahydrofuran; acetonitrile refluxing Cr(CO)6 in MeCN for 18 h, filtration, concn., addn. of org. ligand in THF, diln. with Et2O, reflux (16 h); collection, washing (ether), drying (vac.); elem. anal.;54%
formaldehyd
50-00-0

formaldehyd

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

allyl alcohol
107-18-6

allyl alcohol

3-(2-oxa-4-penten-1-yl)oxazolidine

3-(2-oxa-4-penten-1-yl)oxazolidine

Conditions
ConditionsYield
In benzene Heating;51%
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

acetic anhydride
108-24-7

acetic anhydride

ethanolamine
141-43-5

ethanolamine

A

1-acetoxy-2-nitro-2-aza-4-nitroxybutabe
71545-63-6

1-acetoxy-2-nitro-2-aza-4-nitroxybutabe

B

3,5-dinitro-3,5-diazaheptane-1,7-diyl dinitrate
71545-64-7

3,5-dinitro-3,5-diazaheptane-1,7-diyl dinitrate

Conditions
ConditionsYield
With nitric acid In 1,2-dichloro-ethane at 20 - 25℃; for 1h; Product distribution;A 33%
B 30%
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

1,3-oxazolidine
504-76-7

1,3-oxazolidine

Conditions
ConditionsYield
Destillation unter vermindertem Druck;
Heating;
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

acetic anhydride
108-24-7

acetic anhydride

1-acetoxy-2-nitro-2-aza-4-nitroxybutabe
71545-63-6

1-acetoxy-2-nitro-2-aza-4-nitroxybutabe

Conditions
ConditionsYield
With nitric acid In chloroform
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

3,5-dinitro-3,5-diazaheptane-1,7-diyl dinitrate
71545-64-7

3,5-dinitro-3,5-diazaheptane-1,7-diyl dinitrate

Conditions
ConditionsYield
With nitric acid; ethanolamine In 1,2-dichloro-ethane
(Z)-9-octadecenoyl chloride
112-77-6

(Z)-9-octadecenoyl chloride

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

1,3,5-Triazine-1,3,5(2H, 4H, 6H)triethanol Monooleate
105263-49-8

1,3,5-Triazine-1,3,5(2H, 4H, 6H)triethanol Monooleate

Conditions
ConditionsYield
With potassium carbonate In dichloromethane; water
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

2-(hydroxyimino)-1,2-diphenylethanone
28478-24-2

2-(hydroxyimino)-1,2-diphenylethanone

1-(2-hydroxyethyl)-4,5-diphenyl-1H-imidazole 3-oxide

1-(2-hydroxyethyl)-4,5-diphenyl-1H-imidazole 3-oxide

Conditions
ConditionsYield
In methanol for 3h; Reflux;
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

3,5-bis(2-hydroxyethyl)hexahydro-1,3,5-thiadiazine

3,5-bis(2-hydroxyethyl)hexahydro-1,3,5-thiadiazine

Conditions
ConditionsYield
With sodiumsulfide nonahydrate; acetic acid In acetonitrile pH=5.58 - 7.73; Mechanism; Solvent; pH-value; Reagent/catalyst;
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

A

hexamethylenetetramine
100-97-0

hexamethylenetetramine

B

1-(2-hydroxyethyl)-3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7]decane

1-(2-hydroxyethyl)-3,5,7-triaza-1-azoniatricyclo[3.3.1.13,7]decane

Conditions
ConditionsYield
With ammonium hydroxide; sodiumsulfide nonahydrate; acetic acid In water; acetonitrile for 5h; pH=8.45 - 9.43; Mechanism; pH-value;
1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

A

3,5-bis(2-hydroxyethyl)hexahydro-1,3,5-thiadiazine

3,5-bis(2-hydroxyethyl)hexahydro-1,3,5-thiadiazine

B

ethanolamine
141-43-5

ethanolamine

C

5-(2-hydroxyethyl)hexahydro-1,3,5-dithiazine
88891-55-8

5-(2-hydroxyethyl)hexahydro-1,3,5-dithiazine

Conditions
ConditionsYield
With carbon dioxide; hydrogen sulfide for 7.16667h; Time;
methanol
67-56-1

methanol

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane
4719-04-4

1,3,5-tris(2-hydroxyethyl)-1,3,5-triazacyclohexane

manganese(II) bromide tetrahydrate

manganese(II) bromide tetrahydrate

[MnIII12MnII6(O)6(OH)2(OMe)6(L)4(LH)2Br12]

[MnIII12MnII6(O)6(OH)2(OMe)6(L)4(LH)2Br12]

Conditions
ConditionsYield
for 0.5h;

4719-04-4Relevant articles and documents

Regioselective synthesis of 1,5-Diaryl-2-(Hydroxyalkyl)-8-Methylglycolurils

Antonova,Baranov,Nelyubina,Kravchenko

, p. 503 - 513 (2014)

The cyclocondensation of N-methylurea with derivatives of tetrahydroimidazooxazolone, tetrahydro-imidazooxazinone, dihydroimidazooxazinone, and tetrahydroimidazooxazepinone was studied for the first time. It was shown that the reactions take place with high regioselectivity, are regular in character, and lead to the formation of previously inaccessible 1,5-diaryl-2-(hydroxyalkyl)-8-methylglycolurils with high yields.

HEXAHYDROTRIAZINES, SYNTHESIS AND USE

-

Paragraph 0021, (2013/05/23)

Methods for making asymmetrical triazines are provided. The methods comprise first forming a mixture of at least two primary amines then reacting the mixture with an aldehyde. Methods for removing sulfides from hydrocarbon streams are also provided. The triazines may be added to the hydrocarbon stream in a molar ratio of triazine:H2S of about 10:1 to about 1:2 wherein R1, R2, and R3 are chosen from alkyls, hydroxyl-substituted alkyls, and alkoxy-substituted alkyl of 1 to 10 carbon atoms, with the proviso that R1, R2, and R3 are not all the same.

2-(1,3,5-Dithiazinan-5-yl)ethanol heterocycles, structure and reactivity

Gálvez-Ruiz, Juan Carlos,Jaen-Gaspar, Javier C.,Castellanos-Arzola, Indira G.,Contreras, Rosalinda,Flores-Parra, Angelina

, p. 2269 - 2285 (2007/10/03)

Treatment of 2-(1,3,5-dithiazinan-5-yl)ethanol (1), 2-(1,3,5-dithiazinan-5- yl)-1-phenylethanol (2), 2-(1,3,5-dithiazinan-5-yl)-1-methylethanol (3) and 2-(1,3,5-dithiazinan-5-yl)-2-methyl-1-phenylethanol (4) with TsCl and NEt 3 in CH2Cl2 afforded the corresponding 3-tosyl-1,3-oxazolidine derivatives (5-8), whereas tosylation of 1-4 in the presence of NHMe3Cl gave the corresponding O-tosyl-2-(1,3,5- dithiazinan-5-yl)ethanol derivatives (11-14). The direct preparation of 5 and 7 from formaldehyde and N-tosylethanolamine (9) or N-tosyl-2-propanolamine was not successful. Reactions of 1 or 3 with benzylamine furnish 1,3,5-tribenzyl-1,3,5- triazinane. Heating of 1 and 2 affords the corresponding 1,3,5-tri(2- hydroxyethyl)-1,3,5-triazinanes. X-Ray diffraction studies of compounds (1-9 and 11) are reported.

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