Welcome to LookChem.com Sign In|Join Free

CAS

  • or

488-69-7

Post Buying Request

488-69-7 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

488-69-7 Usage

Uses

Cardioprotectant for ischemic disorders.

Check Digit Verification of cas no

The CAS Registry Mumber 488-69-7 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 4,8 and 8 respectively; the second part has 2 digits, 6 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 488-69:
(5*4)+(4*8)+(3*8)+(2*6)+(1*9)=97
97 % 10 = 7
So 488-69-7 is a valid CAS Registry Number.
InChI:InChI=1/C6H14O11P2/c7-5-3(1-15-18(9,10)11)17-4(6(5)8)2-16-19(12,13)14/h3-8H,1-2H2,(H2,9,10,11)(H2,12,13,14)/t3-,4+,5-,6-/m1/s1

488-69-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name D-fructofuranose 1,6-bisphosphate

1.2 Other means of identification

Product number -
Other names Fmoc-D-propargyl-Gly-OH

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:488-69-7 SDS

488-69-7Synthetic route

D-glucose
50-99-7

D-glucose

fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

Conditions
ConditionsYield
mit Hilfe von Bier-Hefe;
Sucrose
57-50-1

Sucrose

fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

Conditions
ConditionsYield
With disodium phosphate mit Hilfe von Bier-Hefe;
With sodium dihydrogenphosphate mit Hilfe von Baecker-Hefe;
dihydroxyacetone phosphate
57-04-5

dihydroxyacetone phosphate

D-glyceraldehyde-3-phosphate
591-57-1

D-glyceraldehyde-3-phosphate

fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

Conditions
ConditionsYield
fructose-1,6-diphosphate aldolase Rate constant;
fructofuranose 1,6-bisphosphate
717817-28-2

fructofuranose 1,6-bisphosphate

A

α-D-fructofuranose 1,6-diphosphate
34693-23-7

α-D-fructofuranose 1,6-diphosphate

B

fructose 1,6-diphosphate
34693-15-7

fructose 1,6-diphosphate

C

fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

Conditions
ConditionsYield
In water; water-d2 Rate constant; by NMR method;A 13.1 % Spectr.
B 86.0 % Spectr.
C 0.9 % Spectr.
dioxyacetone(?)

dioxyacetone(?)

fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

Conditions
ConditionsYield
bei zellfreier alkoh. Gaerung;
dihydroxyacetone phosphate
57-04-5

dihydroxyacetone phosphate

fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

Conditions
ConditionsYield
Stage #1: dihydroxyacetone phosphate With triosephosphate isomerase Enzymatic reaction;
Stage #2: With Escherichia coli K-12 aldolase YdjI In aq. buffer for 24h; pH=8; Enzymatic reaction;
Conditions
ConditionsYield
With Tris-HCl buffer at 25℃; for 3h; aldolase, triosephosphate isomerase;90%
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

2-hydroxy-3-methoxypropionaldehyde
35830-93-4

2-hydroxy-3-methoxypropionaldehyde

D-arabino-1,3,4,5-Tetrahydroxy-6-methoxy-hexan-2-on
92345-09-0

D-arabino-1,3,4,5-Tetrahydroxy-6-methoxy-hexan-2-on

Conditions
ConditionsYield
In water for 24h; TPI, FDP aldolase, at pH 7.0;90%
D-arabinose 5-phosphate
13137-52-5

D-arabinose 5-phosphate

fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

D-glycero-D-ido-octulose 1,8-diphosphate
70005-40-2

D-glycero-D-ido-octulose 1,8-diphosphate

Conditions
ConditionsYield
With tris hydrochloride at 25℃; for 18h; aldolase, triosephosphate isomerase;65%
(R)-lactaldehyde
3946-09-6

(R)-lactaldehyde

fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

6-deoxy-D-fructose-1-phosphate disodium salt
103866-63-3

6-deoxy-D-fructose-1-phosphate disodium salt

Conditions
ConditionsYield
With sodium hydroxide; triose phosphate isomerase; fructose diphosphate aldolase In water for 22h;62%
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

3-O-methyl-D-glyceraldehyde
105121-51-5

3-O-methyl-D-glyceraldehyde

C7H13O9P(2-)*2Na(1+)

C7H13O9P(2-)*2Na(1+)

Conditions
ConditionsYield
With sodium hydroxide; triose phosphate isomerase; fructose diphosphate aldolase In water for 22h;62%
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

2(S)-hydroxypropanal
3913-64-2

2(S)-hydroxypropanal

6-deoxy-D-fructose 1-phosphate

6-deoxy-D-fructose 1-phosphate

Conditions
ConditionsYield
In water for 22h; triose phosphate isomerase, at pH 7.0;62%
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

5-deoxy-D-fructose 1-phosphate

5-deoxy-D-fructose 1-phosphate

Conditions
ConditionsYield
With 3-Hydroxypropanal In water for 192h; aldolase, triose phosphate isomerase, in the dark, at pH 6.9;42%
Conditions
ConditionsYield
With sodium fluoride; acetaldehyde; toluene bei der Vergaerung durch Propionsaeurebakterien in Phosphat-Loesung;
With sodium fluoride; acetaldehyde bei der Einw. von Trockenhefe, Hefe-Macerationssaft oder mit Toluol vergifteter frischer Hefe in Phosphat-Loesung;
With phosphoric acid; acetaldehyde durch Einw. gereinigter Enzympraeparate aus Hefe und Muskel;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

LACTIC ACID
849585-22-4

LACTIC ACID

Conditions
ConditionsYield
With GLUTATHIONE bei der Einw. von Clostridium acetobutylicum;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

D-Fructose
57-48-7

D-Fructose

Conditions
ConditionsYield
Hydrolysis.Bei Durchblutung der Hundeleber unter Zusatz von d-Sorbit;
With Acinetobacter baumannii recombinant acid phosphatase; nickel dichloride; bovine serum albumin In water pH=6; Cooling with ice; Enzymatic reaction;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

(3S,4R)-1,3,4-trihydroxypentan-2-one
80648-97-1

(3S,4R)-1,3,4-trihydroxypentan-2-one

Conditions
ConditionsYield
With aldolase-substances from peas; phosphatase-substances from peas; acetaldehyde Reagens 4: Wasser; vom pH 8;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

phosphoric acid mono-(2-oxo-ethyl) ester
870-55-3

phosphoric acid mono-(2-oxo-ethyl) ester

Conditions
ConditionsYield
With periodic acid
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

2-deoxy-D-ribose 5-phosphate
7685-50-9

2-deoxy-D-ribose 5-phosphate

Conditions
ConditionsYield
With deoxyriboaldolase-substances; muscle aldolase-substances; acetaldehyde in gepufferten wss. Loesungen vom pH 6.3 bis pH 7.4;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

5-deoxy-D-threo-pent-2-ulose 1-phosphate
16709-34-5

5-deoxy-D-threo-pent-2-ulose 1-phosphate

Conditions
ConditionsYield
With aldolase-substances from rabbit-muscle; sodium hydrogencarbonate; acetaldehyde Reagens 4: Kohlendioxid;
With yeast; sodium hydrogencarbonate; acetaldehyde Reagens 4: Kohlendioxid;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

O1-phosphono-D-threo-5,6-dideoxy-[2]hexulose
29024-88-2

O1-phosphono-D-threo-5,6-dideoxy-[2]hexulose

Conditions
ConditionsYield
With water; propionaldehyde bei der Einw. esines Enzym-Praeparats aus Kaninchen-Muskel;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

L-Lactic acid
79-33-4

L-Lactic acid

Conditions
ConditionsYield
With GLUTATHIONE; toluene durch Colibakterien;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

D-Lactic acid
10326-41-7

D-Lactic acid

Conditions
ConditionsYield
With GLUTATHIONE; toluene bei der Vergaerung durch Hefe;
With GLUTATHIONE; toluene bei der Vergaerung durch Hefe; in diesen Gaerensaetzen entsteht vielleicht intermediaer Methylglyoxal durch einen nichtfermentativen Prozess;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

sn-glycerol 3-phosphate
17989-41-2

sn-glycerol 3-phosphate

Conditions
ConditionsYield
With sodium hydrogencarbonate; sodium fluoride durch Einw. von Kaninchenmuskelbrei;
With sodium hydrogencarbonate; sodium sulfite durch Einw. von Muskelextrakt;
durch Einw. von Hefemacerationssaft;
at 37℃; durch Einw. von untergaeriger Hefe;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

D-(-)-3-phosphoglyceric acid
820-11-1, 3443-58-1, 73358-94-8, 111614-09-6

D-(-)-3-phosphoglyceric acid

Conditions
ConditionsYield
With lactate; sodium fluoride bei der Einw. von Muskelbrei;
With oxalate dianion; sodium fluoride bei der Einw. von Muskelbrei;
With phosphoric acid; calcium chloride bei der Einw. von Muskelbrei;
With phosphoric acid; sodium fluoride durch Einw. von Herzmuskelbrei;
durch Einw. von Hirnbrei;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

acetaldehyde
75-07-0

acetaldehyde

Conditions
ConditionsYield
With calcium sulfite bei Einw. von Leber-Brei;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

A

2-oxo-propionic acid
127-17-3

2-oxo-propionic acid

B

glycerol
56-81-5

glycerol

Conditions
ConditionsYield
With ethanol bei der Gaerung;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

5'-adenosine monophosphate
61-19-8

5'-adenosine monophosphate

Conditions
ConditionsYield
With yeast-maceration juice
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

Sucrose
57-50-1

Sucrose

D-(-)-3-phosphoglyceric acid
820-11-1, 3443-58-1, 73358-94-8, 111614-09-6

D-(-)-3-phosphoglyceric acid

Conditions
ConditionsYield
With sodium fluoride; acetaldehyde bei der Einw. von Trockenhefe, Hefe-Macerationssaft oder mit Toluol vergifteter frischer Hefe in Phosphat-Loesung;
fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

Glucosaccharinsaeure-6-phosphat
92986-77-1, 92986-81-7

Glucosaccharinsaeure-6-phosphat

Conditions
ConditionsYield
With sodium hydroxide
furfural
98-01-1

furfural

fructose-1,6-bisphosphate
488-69-7

fructose-1,6-bisphosphate

Phosphoric acid mono-((3S,4S)-4-furan-2-yl-3,4-dihydroxy-2-oxo-butyl) ester

Phosphoric acid mono-((3S,4S)-4-furan-2-yl-3,4-dihydroxy-2-oxo-butyl) ester

Conditions
ConditionsYield
Rate constant; fructose-1,6-diphosphate aldolase (from spinach leaves), triose phosphate isomerase; disappearance of fructose-1,6-diphosphate;

488-69-7Relevant articles and documents

Harden,Young

, p. 476 (1912)

v.Lebedew

, (1911)

Synthese von Dihydroxyacetonphosphat (und isosteren Analoga) durch enzymatische Oxidation: Zucker aus Glycerin

Fessner, Wolf-Dieter,Sinerius, Gudrun

, p. 217 - 220 (2007/10/02)

-

Reversible and in Situ Formation of Organic Arsenates and Vanadates as Organic Phosphate Mimics in Enzymatic Reactions: Mechanistic Investigation of Aldol Reactions and Synthetic Applications

Drueckhammer, Dale G.,Durrwachter, J. Robert,Pederson, Richard L.,Crans, Debbie C.,Daniels, Lacy,Wong, Chi-Huey

, p. 70 - 77 (2007/10/02)

A synthetic strategy is developed that uses organic phosphate utilizing enzymes as catalysts and a mixture of an organic alcohol and inorganic arsenate or vanadate to replace the organic phosphate substrate.In this process, inorganic arsenate or vanadate reacts with the alcohol reversibly in situ to form a mixture of esters, one of which is accepted by the enzyme as a substrate.Examples of the utility of this approach are demonstrated in enzymatic aldol condensations catalyzed by fructose-1,6-diphosphate aldolase, fuculose-1-phosphate aldolase, and rhamnulose-1-phosphate aldolase with a mixture of dihydroxyacetone and inorganic arsenate as substrate.Several uncommon sugars and deoxy sugars are prepared on 5-17-mmol scales.Mechanistic studies on an aldol reaction indicate that the redox reaction between dihydroxyacetone and inorganic vanadate prohibits the use of such a mixture to replace dihydroxyacetone phosphate in enzymatic aldol condensations.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 488-69-7