50586-77-1

Basic information

• Product Name: Carbamothioic acid, acetylethyl-, S-[(4-chlorophenyl)methyl] ester
• CAS NO: 50586-77-1
• Molecular Formula: C12H14ClNO2S
• Molecular Weight: 271.768
• Mol File: 50586-77-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Carbamothioic acid, acetylethyl-, S-[(4-chlorophenyl)methyl] ester(CAS DataBase Reference)
• NIST Chemistry Reference: Carbamothioic acid, acetylethyl-, S-[(4-chlorophenyl)methyl] ester(50586-77-1)
• EPA Substance Registry System: Carbamothioic acid, acetylethyl-, S-[(4-chlorophenyl)methyl] ester(50586-77-1)

Safety Data

• Hazardous Substances Data: 50586-77-1(Hazardous Substances Data)

Upstream product

• 28249-77-6 Thiobencarb 

Relevant articles and documents

Thiobencarb degradation by TiO2 photocatalysis: Parameter and reaction pathway investigations

The present study deals with the photocatalytic degradation of the thiocarbamate herbicide, thiobencarb (TBC), in the presence of TiO2 particles and UV-A (λ = 365 nm) radiation. Results show rapid and complete oxidation of TBC after 90 min, and slightly over 70% of TBC was mineralized after 32-h treatment. Factors such as solution pH, TiO2 dosage, and the presence of anions are found to influence the degradation rate. The establishment of the reaction pathway is made possible by a thorough analysis of the reaction mixture identifying the main intermediate products generated. Results suggest that possible transformation pathways may include hydroxylation, dealkylation and C-S bond cleavage processes. The possible degradation pathways are proposed and discussed on the basis of the evidence of oxidative intermediate formation.