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51077-01-1

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51077-01-1 Usage

Chemical Properties

White powder

Check Digit Verification of cas no

The CAS Registry Mumber 51077-01-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,1,0,7 and 7 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 51077-01:
(7*5)+(6*1)+(5*0)+(4*7)+(3*7)+(2*0)+(1*1)=91
91 % 10 = 1
So 51077-01-1 is a valid CAS Registry Number.
InChI:InChI=1/C12H15NO4S/c1-9-4-6-10(7-5-9)18(16,17)13-8-2-3-11(13)12(14)15/h4-7,11H,2-3,8H2,1H3,(H,14,15)/t11-/m0/s1

51077-01-1 Well-known Company Product Price

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  • Alfa Aesar

  • (H66902)  N-Toluenesulfonyl-L-proline, 95%   

  • 51077-01-1

  • 5g

  • 564.0CNY

  • Detail
  • Alfa Aesar

  • (H66902)  N-Toluenesulfonyl-L-proline, 95%   

  • 51077-01-1

  • 25g

  • 2254.0CNY

  • Detail
  • Aldrich

  • (722553)  Tos-Pro-OH  97%

  • 51077-01-1

  • 722553-1G

  • 441.09CNY

  • Detail

51077-01-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name N-Toluenesulfonyl-L-proline

1.2 Other means of identification

Product number -
Other names TOS-PRO-OH

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:51077-01-1 SDS

51077-01-1Relevant articles and documents

Stereoselective total synthesis of (S)- and (R)-nuciferine using benzyne chemistry

Casagrande, Gleison A.,Deflon, Victor M.,Martins, Gabriel R.,Oliveira-Silva, Diogo,Perecim, Givago P.,Pinto, Leandro M. C.,Raminelli, Cristiano

, (2020/08/13)

Total syntheses of (S)- and (R)-nuciferine were accomplished through approach involving diastereoselective reaction between a chiral dihydroisoquinoline enamide and 2-(trimethylsilyl)phenyl trifluoromethanesulfonate promoted by CsF, affording a separable mixture of diastereoisomers, which provided (S)- and (R)-nuciferine via simple and efficient transformations.

Synthesis, characterization, in silico and in vitro evaluations of symmetrical 1,3-Diketones

Porchezhiyan,Kalaivani,Shobana,Noorjahan

, p. 853 - 864 (2020/03/24)

1,3-Dicarbonyl compounds have gained significant importance since they are abundantly available in the natural products and possess myriad biological activities. The new symmetrical 1,3-diketones bearing L-proline, 2-methyl-5-iodobenzoic acid, piperidine-3-carboxylic acid and naphthalene-1-acetic acid moieties were synthesized by coupling reaction of appropriate ketone with N-acyl triazole in the presence of MgBr2·Et2O and DIPEA. The chemical structure of the compounds were confirmed from the spectral data such as 1H, 13C NMR, FT-IR and HRMS. Molecular docking studies were carried out for all the compounds with tumor associated protein tyrosine kinase-6 (PTK6) and inflammatory protein cyclooxygenase-2 (COX2). The in vitro evaluation was carried out using breast cancer cell lines (MTT assay) and HRBC stabilization assays. During in silico studies, the ki values obtained against PTK6 and COX2 for (5a-d) compounds were in the range (-7.5 to -10.6) and (-7.6 to -9.8) kcal/mol, respectively. The compound 5d was selected for MTT assay, since it exhibited the highest binding affinity (-10.6 kcal/mol) against PTK6 and gave IC50 - 2.4 μg/mL against breast cancer cell lines. The HRBC stabilization of all the compounds (5a-5d) were in the range (59.28-93.4) %, with highest stabilization value by 5d, which also displayed higher binding affinity with -7.6 kcal/mol towards COX2. Thus, the synthesized symmetrical 1,3-diketones with suitable functionality can be both anticancer and anti-inflammatory agents.

New carboxamides bearing benzenesulphonamides: Synthesis, molecular docking and pharmacological properties

Eze, Florence Uchenna,Okoro, Uchechukwu Chris,Ugwu, David Izuchukwu,Okafor, Sunday N.

, (2019/09/18)

Ten new derivatives of benzenesulphonamide bearing carboxamide functionality were synthesized and investigated for their in vitro antimicrobial, antioxidant and in vivo anti-inflammatory activities. Compound 9d inhibited carrageenan induced rat-paw oedema

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