51114-72-8

Basic information

• Product Name: 2-(phenylsulfonyl)-3,4-dihydro-1(2H)-naphthalenone
• Synonyms: 2-(phenylsulfonyl)-3,4-dihydro-1(2H)-naphthalenone
• CAS NO: 51114-72-8
• Molecular Formula: C₁₆H₁₄O₃S
• Molecular Weight: 286.34556
• Mol File: 51114-72-8.mol
• Article Data: 8

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-(phenylsulfonyl)-3,4-dihydro-1(2H)-naphthalenone(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(phenylsulfonyl)-3,4-dihydro-1(2H)-naphthalenone(51114-72-8)
• EPA Substance Registry System: 2-(phenylsulfonyl)-3,4-dihydro-1(2H)-naphthalenone(51114-72-8)

Safety Data

• Hazardous Substances Data: 51114-72-8(Hazardous Substances Data)

Upstream product

• 117012-44-9 1-Benzenesulfonyl-1-diazo-4-phenyl-butan-2-one 
• 98-09-9 benzenesulfonyl chloride 
• 873-55-2 sodium benzenesulfonate 
• 1056246-70-8 2-bromo-1-tetralone 
• 69627-08-3 1-(phenylsulfonyl)-1-(trimethylsilyl)ethene 
• 62762-20-3 1-phenylthio-1-trimethylsilylethene 
• 117012-21-2 C₁₇H₁₈O₂S₂ 
• 117037-41-9 (2-Methylsulfanyl-prop-2-ene-1-sulfonyl)-benzene 
• 93434-80-1 1-phenyl-4-phenylsulphonylbutan-3-one 
• 2525-40-8 prop-2-ynylsulfonylbenzene 
• 128881-76-5 2-(3-Benzenesulfonyl-propyl)-N,N-diethyl-benzamide 

Downstream Products

• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 1191924-78-3 2-(3-oxobutyl)-2-(phenylsulfonyl)-3,4-dihydronaphthalen-1(2H)-one 
• 1130816-79-3 (1R,2S)-2-(phenylsulfonyl)-1,2,3,4-tetrahydronaphthalen-1-ol 

Relevant articles and documents

Controlled Synthesis of β-Keto Sulfones and Vinyl Sulfones under Electrochemical Oxidation

Selective sulfonylation and oxosulfonylation of alkenes with sulfinates have been developed via anodic oxidation in an undivided cell. The novel electrosynthetic method provided β-keto sulfones and vinyl sulfones with good to excellent yields in the absence of any transition metal catalyst and oxidants. Mechanism studies show that two different pathways involved in these two transformations.

Oxidative Sulfonylation of Hydrazones Enabled by Synergistic Copper/Silver Catalysis

A copper/silver-cocatalyzed protocol for oxidative sulfonylation of hydrazones is demonstrated. A wide range of β-ketosulfones and N-acylsulfonamides are directly synthesized in moderate to good yields. Our work provides a viable method for scalable preparation of β-ketosulfone derivatives that have found wide applications in the pharmaceutical industry.

Desulfonylative Methenylation of β-Keto Sulfones

A one-step strategy for the synthesis of α-methenyl ketones from β-keto sufones is reported. Success of the methodology is elaborated for the synthesis of chromanones and isoflavanones in one-step.