514222-44-7Relevant articles and documents
Transition metal coordination complexes based on V-shaped bis-triazole ligand: syntheses, structures, and properties
Shi, Xiu Juan,Chen, Peng Yun,Wu, Ming Ze,Cai, Dong Chen,Tian, Li
, p. 1063 - 1072 (2018)
Hydrothermal reactions of 1,3-bis(1,2,4-triazol-1-yl)benzene (btb) and M(NO3)2 (M?=?Co2+ (1), Cu2+ (2)) afforded two new coordination polymers, [Co(btb)2(NO3)(H2O)]n·NO3·H2O (1) and [Cu(btb)2(NO3)2]n (2), respectively. Single-crystal X-ray diffraction reveals that 1 crystallizes in the space group P21/m and 2 crystallizes in the space group Pī, both showing a double-stranded chain structure. The 1-D chains are interconnected via π?π interactions to lead to 2-D ladder-like supramolecular architectures. In addition, magnetic behavior and thermal stability of 1 and 2 have been investigated. For 1, weak antiferromagnetic interactions are observed at low temperature, and the data obey the Curie–Weiss law χM?=?C/(T?θ), with C?=?3.22?cm3·mol?1·K and θ?=??10.39?K. For 2, the decrease of the χT vs. T curve at low temperature is the result of intermolecular antiferromagnetic magnetic interactions.
Toward molecular rotors: Tetra-N-heterocyclic carbene Ag(i)-halide cubane-type clusters
Clark, Wesley D.,Tyson, Ginger E.,Keith Hollis,Valle, Henry U.,Valente, Edward J.,Oliver, Allen G.,Dukes, Matthew P.
, p. 7338 - 7344 (2013)
1,3-Bis(3′-butylimidazol-1′-yl)benzene diiodide (2a), 1,3-bis(3′-but-3′′-enyl-imidazolium-3′-yl)benzene diiodide (2b), 1,3-bis(3′-pent-4′′-enyl-imidazolium-3′- yl)benzene diiodide (2c), 1,3-bis(4′-butyl-1′,2′,4′- triazolium-1′-yl)benzene diiodide (2d), or
