51608-60-7

Basic information

• Product Name: N-tosyliMinobenzyliodinane
• Synonyms: N-tosyliMinobenzyliodinane;(E)-N-Benzylidene-4-MethylbenzensulfonaMide;(E)-N-Benzylidene-4-methylbenzensulfonamide 99%;N-Benzylidene-4-methylbenzensulfonamide;(NE)-N-benzylidene-4-methylbenzenesulfonamide
• CAS NO: 51608-60-7
• Molecular Formula: C₁₄H₁₃NO₂S
• Molecular Weight: 259.32
• Mol File: 51608-60-7.mol
• Article Data: 209

Chemical Properties

• Melting Point: 108-115°C
• Boiling Point: 415.7±38.0 °C(Predicted)
• Appearance: /
• Density: 1.15±0.1 g/cm3(Predicted)
• PKA: -4.71±0.50(Predicted)
• BRN: 2115660
• CAS DataBase Reference: N-tosyliMinobenzyliodinane(CAS DataBase Reference)
• NIST Chemistry Reference: N-tosyliMinobenzyliodinane(51608-60-7)
• EPA Substance Registry System: N-tosyliMinobenzyliodinane(51608-60-7)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 51608-60-7(Hazardous Substances Data)

Usage

General Description

N-tosylaminobenzyliodinane is a chemical compound commonly used as an organic oxidizing agent in synthetic chemistry. It is a reagent that is highly effective at converting primary alcohols to aldehydes, and secondary alcohols to ketones, with high selectivity and yield. N-tosyliMinobenzyliodinane is stable and easy to handle, making it a popular choice for oxidation reactions in the laboratory. Additionally, N-tosylaminobenzyliodinane is known for its mild reaction conditions and low toxicity, making it an attractive option for use in organic synthesis. Overall, N-tosylaminobenzyliodinane is a valuable reagent for the oxidation of alcohols in the production of various organic compounds.

Upstream product

• 70-55-3 toluene-4-sulfonamide 
• 941-55-9 4-toluenesulfonyl azide 
• 100-52-7 benzaldehyde 
• 19158-51-1 P-toluenesulfonyl cyanide 
• 932-90-1 Benzaldoxime 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 169330-83-0 (S)-N-benzyl-4-methylbenzenesulfinamide 
• 100-51-6 benzyl alcohol 
• 127-65-1 chloroamine-T 
• 108-88-3 toluene 
• 52962-79-5 4-Methyl-N-[phenyl-(toluene-4-sulfonyl)-methyl]-benzenesulfonamide 
• 3395-83-3 4-methylbenzaldehyde dimethylacetal 
• 92851-65-5 2-((4-methylphenyl)sulfonamido)-2-phenylacetic acid 

Downstream Products

• 130231-94-6 cis-N-tosyl 3-ethoxycarbonyl-2,2-dimethyl-4-phenyl-4-butanelactam 
• 130231-94-6 trans-N-tosyl 3-ethoxycarbonyl-2,2-dimethyl-4-phenyl-4-butanelactam 
• 74941-16-5 N-(Diphenylarsanyl-phenyl-methyl)-4-methyl-benzenesulfonamide 
• 155880-40-3 3-Ethenyl-1-(benzenesulfonyl)-2-methyl>indole 
• 142819-55-4 1-(benzotriazol-1-yl)-2-tosylamino-1-(p-tolyl)-2-phenylethane 
• 155495-87-7 tert-butyl 3-(4-toluenesulfonamido)-3-phenylpropanoate 
• 1576-37-0 N-benzyl-p-toluenesulfonamide 
• 164913-53-5 (4S,5R)-3-<(2R,3S)-2,3-diphenyl-3-(tosylamino)propionyl>-4-methyl-5-phenyloxazolidin-2-one 
• 165036-41-9 (4S,5R)-3-<(2R,3R)-2,3-diphenyl-3-(tosylamino)propionyl>-4-methyl-5-phenyloxazolidin-2-one 
• 165036-40-8 (4S,5R)-4-methyl-3-<(2R,3R)-2-methyl-3-phenyl-3-(tosylamino)propionyl>-5-phenyloxazolidin-2-one 
• 164913-51-3 (4S,5R)-4-methyl-3-<(2R,3S)-2-methyl-3-phenyl-3-(tosylamino)propionyl>-5-phenyloxazolidin-2-one 
• 164913-52-4 (4S,5R)-4-methyl-3-<(2R,3S)-2-ethyl-3-phenyl-3-(tosylamino)propionyl>-5-phenyloxazolidin-2-one 
• 96-09-3 styrene oxide 
• 174291-24-8 (1R,2R,3S,4S)-1,7,7-Trimethyl-3-methylsulfanyl-bicyclo[2.2.1]heptan-2-ol 

Relevant articles and documents

Probing the Diastereoselectivity of Staudinger Reactions Catalyzed by N-Heterocyclic Carbenes

The reaction of ethylphenylketene with 1,3-dimesitylimidazol-2-ylidene (IMes) or 1,3-dimesitylimidazolin-2-ylidene (SIMes) afforded the corresponding azolium enolates in high yields. The two zwitterions were fully characterized by various analytical techn

Copper-boryl mediated transfer hydrogenation of N-sulfonyl imines using methanol as the hydrogen donor

B2Pin2-assisted copper-catalyzed transfer hydrogenation of aromatic sulfonylimines has been achieved, delivering a variety of aryl/heteroaryl sulfonamides in good to excellent yields under mild reaction conditions and with methanol a

Synthesis and biological evaluation of substituted phenyl azetidine-2-one sulphonyl derivatives as potential antimicrobial and antiviral agents

In the present study, we intend to synthesize a series of novel substituted phenyl azetidine-2-one sulphonyl derivatives. The entire set of derivatives 5 (a-t) were screened for in-vitro antibacterial, and antifungal activity, and among them eleven compou