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51693-17-5

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51693-17-5 Usage

Chemical Properties

colorless to beige powder

Uses

Serves as a building block in the synthesis of (R)- and (S)-diaminovaleric acids and of 5-azasemicorrin bidentate nitrogen ligands for enantioselective catalysis.

Check Digit Verification of cas no

The CAS Registry Mumber 51693-17-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 5,1,6,9 and 3 respectively; the second part has 2 digits, 1 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 51693-17:
(7*5)+(6*1)+(5*6)+(4*9)+(3*3)+(2*1)+(1*7)=125
125 % 10 = 5
So 51693-17-5 is a valid CAS Registry Number.
InChI:InChI=1/C12H15NO4S/c1-9-2-5-11(6-3-9)18(15,16)17-8-10-4-7-12(14)13-10/h2-3,5-6,10H,4,7-8H2,1H3,(H,13,14)/t10-/m0/s1

51693-17-5 Well-known Company Product Price

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  • Aldrich

  • (444537)  (S)-(+)-5-(Hydroxymethyl)-2-pyrrolidinonep-toluenesulfonate  95%

  • 51693-17-5

  • 444537-5G

  • 2,334.15CNY

  • Detail

51693-17-5SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name (S)-(+)-5-(Hydroxymethyl)-2-pyrrolidinone p-toluenesulfonate

1.2 Other means of identification

Product number -
Other names (S)-5-tosyloxymethyl-2-pyrrolidinone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:51693-17-5 SDS

51693-17-5Relevant articles and documents

Synthesis of N-aminomethylpyrrolidin-2-ones

Chen, Ping,Suh, Dong-Jin,Smith, Michael B.

, p. 1317 - 1322 (1995)

Pyrrolidin-2-ones react with formaldehyde and chlorotrimethylsilane to give 1-chloromethylpyrrolidin-2-ones which upon subsequent reaction with primary and secondary amines give 1-aminomethylpyrrolidin-2-ones in good yield.

Photoredox-Catalyzed Synthesis of α-Amino Acid Amides by Imine Carbamoylation

Cardinale, Luana,Jacobi Von Wangelin, Axel,Konev, Mikhail O.,Schmotz, Mattis-Ole W. S.

supporting information, (2022/01/20)

An operationally simple protocol for the photocatalytic carbamoylation of imines is reported. Easily available, bench-stable 4-amido Hantzsch ester derivatives serve as precursors to carbamoyl radicals that undergo rapid addition to N-aryl imines. The reaction proceeds under blue light irradiation in the presence of the photocatalyst 3DPAFIPN and Br?nsted/Lewis acid additives. Mechanistic studies indicated a photoredox mechanism that involves carbamoyl radicals.

A class of histone acetylase p300 inhibitors, and application thereof

-

Paragraph 1087-1091, (2020/06/17)

The invention discloses a class of histone acetylase p300 inhibitors, and application thereof, and belongs to the technical field of medicinal chemistry. The invention discloses a compound representedby a formula (I), or a stereochemical isomer, a solvate or a pharmaceutically acceptable salt thereof. According to the invention, the compound can effectively inhibit the activity of histone acetylase p300 and can effectively inhibit the proliferation activity of various tumor cells; the compound is combined with a CDK4/6 inhibitor to play a synergistic role in inhibiting proliferation of tumorcells; and the compound has good application prospects in preparation of histone acetylase inhibitors, preparation of drugs for preventing and/or treating cancers, metabolic diseases, neurological diseases or inflammations, and combination of drugs.

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