528-64-3Relevant articles and documents
Asymmetric synthesis of: Trans -4,5-disubstituted γ-butyrolactones involving a key allylboration step. First access to (-)-nicotlactone B and (-)-galbacin
Henrion,Macé,Vallejos,Roisnel,Carboni,Villalgordo,Carreaux
, p. 1672 - 1678 (2018/03/21)
An efficient asymmetric synthesis of trans-4,5-disubstituted γ-butyrolactones from aldehydes and enantioenriched γ-carbamate alkenylboronates is reported. The cornerstone of this strategy is the implementation of sequential [3,3]-allyl cyanate rearrangement/allylboration/nucleophilic addition/cyclisation reactions. Diverse γ-butyrolactones such as the flavouring compounds, (+)-trans-whiskey lactone and (+)-trans-cognac lactone, as well as an advanced intermediate towards the first synthesis of natural products, (-)-nicotlactone B and (-)-galbacin, have thus been obtained.
Lignans from the roots of Saururus chinensis
Seo, Chang-B,Zheng, Ming-Shan,Woo, Mi-Hee,Lee, Chong-Soon,Lee, Sung-Ho,Jeong, Byeong-Seon,Chang, Hyeun-Wook,Jahng, Yurngdong,Lee, Eung-Seok,Son, Jong-Keun
experimental part, p. 1771 - 1774 (2009/08/07)
Four new lignans, saucerneol F (1), saucerneol G (2), saucerneol H (3), and saucerneol I (4), were isolated from the EtOAc extract of the roots of Saururus chinensis, together with one known compound, saucerneol D (5). The structures of compounds 1-4 were