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531-18-0

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  • Methanol,1,1',1'',1''',1'''',1'''''-(1,3,5-triazine-2,4,6-triyltrinitrilo)hexakis- Manufacturer/High quality/Best price/In stock

    Cas No: 531-18-0

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531-18-0 Usage

Uses

In fireproofing and creaseproofing of cottons, rayons.

Check Digit Verification of cas no

The CAS Registry Mumber 531-18-0 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,3 and 1 respectively; the second part has 2 digits, 1 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 531-18:
(5*5)+(4*3)+(3*1)+(2*1)+(1*8)=50
50 % 10 = 0
So 531-18-0 is a valid CAS Registry Number.
InChI:InChI=1/C9H18N6O6/c16-1-13(2-17)7-10-8(14(3-18)4-19)12-9(11-7)15(5-20)6-21/h16-21H,1-6H2

531-18-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 20, 2017

Revision Date: Aug 20, 2017

1.Identification

1.1 GHS Product identifier

Product name [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol

1.2 Other means of identification

Product number -
Other names Hexa(hydroxymethyl)melamine

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:531-18-0 SDS

531-18-0Synthetic route

formaldehyd
50-00-0

formaldehyd

2,4,6-triamino-s-triazine
108-78-1

2,4,6-triamino-s-triazine

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

Conditions
ConditionsYield
In water pH=7.5; Heating;86%
With hydrogenchloride
With sodium hydroxide
formaldehyd
50-00-0

formaldehyd

2,4,6-triamino-s-triazine
108-78-1

2,4,6-triamino-s-triazine

A

[1,3,5]triazine-2,4,6-triyltriamino-tris-methanol
1017-56-7

[1,3,5]triazine-2,4,6-triyltriamino-tris-methanol

B

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

linoleic acid
60-33-3

linoleic acid

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

hexa(linoleoylhydroxymethyl)melamine

hexa(linoleoylhydroxymethyl)melamine

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 24h; Inert atmosphere;95%
hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide
35948-25-5

9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide

N,N,N',N',N'',N''-Hexakis-(10-oxo-10H-9-oxa-10λ5-phospha-phenanthren-10-ylmethyl)-[1,3,5]triazine-2,4,6-triamine
66499-32-9

N,N,N',N',N'',N''-Hexakis-(10-oxo-10H-9-oxa-10λ5-phospha-phenanthren-10-ylmethyl)-[1,3,5]triazine-2,4,6-triamine

Conditions
ConditionsYield
With benzenesulfonic acid at 165 - 240℃;89%
methanol
67-56-1

methanol

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

hexakis-N-methoxymethyl-[1,3,5]triazine-2,4,6-triamine
3089-11-0

hexakis-N-methoxymethyl-[1,3,5]triazine-2,4,6-triamine

Conditions
ConditionsYield
With hydrogenchloride
With nitric acid In water at 45 - 55℃; for 1.5h; pH=1.5 - 3.8; Product distribution / selectivity;
With hydrogenchloride In water at 35℃; for 2h; pH=2.5; pH-value; Temperature;
hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

hexakis-N-chloromethyl-[1,3,5]triazine-2,4,6-triamine
50693-84-0

hexakis-N-chloromethyl-[1,3,5]triazine-2,4,6-triamine

Conditions
ConditionsYield
With phosphorus trichloride In N,N-dimethyl-formamide at 0℃;
hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

tetramethlyammonium chloride
75-57-0

tetramethlyammonium chloride

epichlorohydrin
106-89-8

epichlorohydrin

butan-1-ol
71-36-3

butan-1-ol

Hexamethylolmelamineglycidyl Ether

Hexamethylolmelamineglycidyl Ether

Conditions
ConditionsYield
With sodium hydroxide In water
With sodium hydroxide In water
hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

C9H24N12

C9H24N12

Conditions
ConditionsYield
With ammonia In methanol at 50 - 60℃; under 1140.08 Torr; for 2h; Inert atmosphere; Autoclave;
hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

2,2'-iminobis[ethanol]
111-42-2

2,2'-iminobis[ethanol]

C33H72N12O12
1609117-63-6

C33H72N12O12

Conditions
ConditionsYield
In ethanol at 60 - 80℃; for 3h;
hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

2,2'-iminobis[ethanol]
111-42-2

2,2'-iminobis[ethanol]

C17H36N8O8

C17H36N8O8

Conditions
ConditionsYield
In ethanol at 30 - 60℃; for 3h;
docosanoyl chloride
21132-76-3

docosanoyl chloride

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

C97H184N6O16S2(2-)*2Na(1+)

C97H184N6O16S2(2-)*2Na(1+)

Conditions
ConditionsYield
Stage #1: docosanoyl chloride; hexa(hydroxymethyl)melamine With chlorosulfonic acid In tetrahydrofuran at 30 - 70℃; for 2h;
Stage #2: With sodium hydrogencarbonate In tetrahydrofuran
docosanoyl chloride
21132-76-3

docosanoyl chloride

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

C97H184N6O16P2(4-)*4Na(1+)

C97H184N6O16P2(4-)*4Na(1+)

Conditions
ConditionsYield
Stage #1: docosanoyl chloride; hexa(hydroxymethyl)melamine With chlorophosphonic acid In tetrahydrofuran at 30 - 70℃; for 2h;
Stage #2: With sodium hydrogencarbonate In tetrahydrofuran
docosanoyl chloride
21132-76-3

docosanoyl chloride

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

oxalic acid
144-62-7

oxalic acid

C101H184N6O16(2-)*2Na(1+)

C101H184N6O16(2-)*2Na(1+)

Conditions
ConditionsYield
Stage #1: docosanoyl chloride; hexa(hydroxymethyl)melamine; oxalic acid In tetrahydrofuran at 30 - 70℃; for 2h;
Stage #2: With sodium hydrogencarbonate In tetrahydrofuran
N,N-dimethylheneicosylamine

N,N-dimethylheneicosylamine

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

C147H306N12(6+)*6HO(1-)

C147H306N12(6+)*6HO(1-)

Conditions
ConditionsYield
In methanol at 30℃; for 2h;
methanol
67-56-1

methanol

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

C12H24N6O6

C12H24N6O6

Conditions
ConditionsYield
With hydrogenchloride In water at 38 - 42℃; pH=5; pH-value;
methanol
67-56-1

methanol

antimony(III) trioxide

antimony(III) trioxide

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

butan-1-ol
71-36-3

butan-1-ol

C16H31N6O7Sb

C16H31N6O7Sb

Conditions
ConditionsYield
Stage #1: methanol; hexa(hydroxymethyl)melamine; butan-1-ol With nitric acid at 65℃; for 0.5h; pH=5.5;
Stage #2: With potassium hydroxide at 50℃; pH=9;
Stage #3: antimony(III) trioxide In water at 110℃; for 0.5h;
methanol
67-56-1

methanol

sodium molybdate

sodium molybdate

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

butan-1-ol
71-36-3

butan-1-ol

C19H36MoN6O8

C19H36MoN6O8

Conditions
ConditionsYield
Stage #1: methanol; hexa(hydroxymethyl)melamine; butan-1-ol With hydrogenchloride In water at 55℃; for 1.5h; pH=4.5;
Stage #2: at 50℃; pH=8.6; Alkaline conditions;
Stage #3: sodium molybdate In water at 100℃; for 1.5h;
methanol
67-56-1

methanol

sodium molybdate

sodium molybdate

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

butan-1-ol
71-36-3

butan-1-ol

C52H102MoN12O14

C52H102MoN12O14

Conditions
ConditionsYield
Stage #1: methanol; hexa(hydroxymethyl)melamine; butan-1-ol With hydrogenchloride In water at 65℃; for 1.66667h; pH=4.5;
Stage #2: With sodium hydrogencarbonate at 50℃; pH=8.2;
Stage #3: sodium molybdate In water at 100℃; for 1.5h;
methanol
67-56-1

methanol

Sodium borate

Sodium borate

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

butan-1-ol
71-36-3

butan-1-ol

C34H67BN12O13

C34H67BN12O13

Conditions
ConditionsYield
Stage #1: methanol; hexa(hydroxymethyl)melamine; butan-1-ol With hydrogenchloride In water at 55℃; for 1.66667h; pH=3.5;
Stage #2: With sodium hydrogencarbonate at 50℃; pH=8.6;
Stage #3: Sodium borate In water at 105℃; for 1h;
methanol
67-56-1

methanol

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

butan-1-ol
71-36-3

butan-1-ol

Sodium octoborate tetrahydrate

Sodium octoborate tetrahydrate

C19H37BN6O7

C19H37BN6O7

Conditions
ConditionsYield
Stage #1: methanol; hexa(hydroxymethyl)melamine; butan-1-ol With hydrogenchloride In water at 35℃; for 2h; pH=2.5;
Stage #2: With sodium hydroxide at 50℃; pH=8;
Stage #3: Sodium octoborate tetrahydrate In water at 100℃; for 2h;
antimony(III) trioxide

antimony(III) trioxide

2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

C41H81N6O7Sb

C41H81N6O7Sb

Conditions
ConditionsYield
Stage #1: 2-Ethylhexyl alcohol; hexa(hydroxymethyl)melamine With nitric acid at 65℃; for 0.5h; pH=5.5; Large scale;
Stage #2: antimony(III) trioxide In water at 110℃; for 0.5h; Large scale;
sodium molybdate

sodium molybdate

2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

C98H194MoN12O14

C98H194MoN12O14

Conditions
ConditionsYield
Stage #1: 2-Ethylhexyl alcohol; hexa(hydroxymethyl)melamine With hydrogenchloride In water at 55℃; for 1.66667h; pH=4.5; Large scale;
Stage #2: sodium molybdate In water at 105℃; for 1.5h; Large scale;
sodium molybdate

sodium molybdate

2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

C41H80MoN6O8

C41H80MoN6O8

Conditions
ConditionsYield
Stage #1: 2-Ethylhexyl alcohol; hexa(hydroxymethyl)melamine With hydrogenchloride In water at 55℃; for 1.33333h; pH=4.5; Large scale;
Stage #2: sodium molybdate In water at 100℃; for 1.5h; Large scale;
Sodium borate

Sodium borate

2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

C98H195BN12O13

C98H195BN12O13

Conditions
ConditionsYield
Stage #1: 2-Ethylhexyl alcohol; hexa(hydroxymethyl)melamine With hydrogenchloride In water at 65℃; for 1.5h; pH=5.5; Large scale;
Stage #2: Sodium borate In water at 105℃; for 1h; Large scale;
2-Ethylhexyl alcohol
104-76-7

2-Ethylhexyl alcohol

disodium octaborate tetrahydrate

disodium octaborate tetrahydrate

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

C41H81BN6O7

C41H81BN6O7

Conditions
ConditionsYield
Stage #1: 2-Ethylhexyl alcohol; hexa(hydroxymethyl)melamine With hydrogenchloride In water at 35℃; for 2h; pH=2.5; Large scale;
Stage #2: disodium octaborate tetrahydrate In water at 100℃; for 2h; Large scale;
sodium molybdate

sodium molybdate

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

trimethyleneglycol
504-63-2

trimethyleneglycol

C48H94MoN12O24

C48H94MoN12O24

Conditions
ConditionsYield
Stage #1: hexa(hydroxymethyl)melamine; trimethyleneglycol at 55℃; for 1h; pH=4; Acidic conditions; Large scale;
Stage #2: sodium molybdate In water at 105℃; for 1.5h; Large scale;
Sodium borate

Sodium borate

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

trimethyleneglycol
504-63-2

trimethyleneglycol

C48H95BN12O23

C48H95BN12O23

Conditions
ConditionsYield
Stage #1: hexa(hydroxymethyl)melamine; trimethyleneglycol at 40℃; for 1.5h; pH=3.5; Acidic conditions; Large scale;
Stage #2: Sodium borate In water at 105℃; for 1h; Large scale;
disodium octaborate tetrahydrate

disodium octaborate tetrahydrate

hexa(hydroxymethyl)melamine
531-18-0

hexa(hydroxymethyl)melamine

trimethyleneglycol
504-63-2

trimethyleneglycol

C21H41BN6O11

C21H41BN6O11

Conditions
ConditionsYield
Stage #1: hexa(hydroxymethyl)melamine; trimethyleneglycol at 35℃; for 2h; pH=2.5; Acidic conditions; Large scale;
Stage #2: disodium octaborate tetrahydrate In water at 100℃; for 2h; Large scale;

531-18-0Relevant articles and documents

High surface area metal salt templated carbon aerogels via a simple subcritical drying route: Preparation and CO2 uptake properties

Masika, Eric,Mokaya, Robert

, p. 17677 - 17681 (2013)

We describe a very simple method for the formation of high surface area carbon aerogels from melamine-formaldehyde resins, via metal salt (CaCl 2) templating, wherein subcritical drying is used and no activation is required. The metal salt acts as a porogen to generate carbon aerogels with surface area of up to 1100 m2 g-1, which exhibit significant CO2 uptake of up to 2.2 mmol g-1 at 298 K and 1 bar. The Royal Society of Chemistry.

Method for improving acyl methyl melamine methylol content method

-

Paragraph 0021-0044, (2017/08/08)

The invention relates to a method of increasing the hydroxymethyl content of hexahydroxymethyl melamine. The method concretely comprises the following steps: (1) according to the molar ratio of melamine, formaldehyde and water to be 1 to (6-7) to (30-35), adding the amount of the water into a reaction kettle, regulating the rotary speed of a stirrer of the reaction kettle to be 80-120rpm, adding the amount of the formaldehyde, raising the temperature, regulating the temperature to be 45-50 DEG C, adding the amount of the melamine, stirring for 10-30 minutes, keeping the temperature to be 55-60 DEG C, wherein in the whole process, a pH value of a reaction system to be 8.3-8.4 is kept by using a buffer liquid, and the buffer liquid is a sodium carbonate-sodium bicarbonate buffer liquid; (2) after the melamine in the reaction system is completely dissolved, lowering the stirring speed of the reaction kettle to 50-70rpm, and keeping reaction for 2-3h; and (3) stopping stirring, standing for crystallization for 1-1.5h, carrying out air pump filtration separation, removing a waste liquid, and drying to obtain the finished hexahydroxymethyl melamine. According to the method disclosed by the invention, the hydroxymethyl content of the hexahydroxymethyl melamine achieves 59-61 percent.

LIQUID CRYSTAL ALIGNING AGENT, LIQUID CRYSTAL ALIGNMENT FILM AND LIQUID CRYSTAL DISPLAY DEVICE

-

Paragraph 0207-0208, (2021/01/07)

The invention provides a liquid crystal aligning agent, a liquid crystal aligning film, a liquid crystal display element, a compound and a manufacture method of the compound. The liquid crystal aligning agent can be used as the forming material of the liquid crystal aligning film and has excellent performance suitable for printing; completely satisfy the properties as the liquid crystal display element required by the practicality aspect such as: vertical aligning property, voltage keeping rate and weathering resistance and also easily peel off when the product has defect. The liquid crystal aligning agent contains (A) at least one polymer selected from a group consisting of a polyamic acid and a polymide and (B) a compound represented by the formula (1).

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