5324-06-1Relevant articles and documents
HOLOGRAPHIC RECORDING MATERIALS AND METHODS OF MAKING THE SAME
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Page/Page column 28-30, (2021/12/31)
Provided herein are compositions suitable for recording holograms containing thiol and/or thioether functionality, and optionally including additional allyl and/or propargyl functional groups. These monomers can be used to synthesize holographic polymers having high Δn values. Also provided herein are methods of making holographic polymers and methods recording holograms using these polymers.
METHOD FOR PRODUCING POLYTHIOL COMPOUND, METHOD FOR PRODUCING CURABLE COMPOSITION, AND METHOD FOR PRODUCING CURED PRODUCT
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Paragraph 0106-0107, (2020/12/13)
A method for producing a polythiol compound includes reacting a polyol compound with thiourea in which a content of ammonium thiocyanate is 0.05% by mass or less to obtain an isothiuronium salt.
PRODUCTION METHOD FOR POLYTHIOL COMPOUND, POLYMERIZABLE COMPOSITION FOR OPTICAL MATERIAL AND USE THEREFOR
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Paragraph 0091, (2015/03/18)
Provided is a method for producing a polythiol compound, comprising: a step for reacting 2-mercaptoethanol with an epihalohydrin compound represented by the following formula (1) at a temperature of 10°C to 50°C to obtain a polyalcohol compound represented by the following formula (2); a step for reacting the polyalcohol compound thus obtained with thiourea in the presence of hydrogen chloride to obtain an isothiuronium salt; a step for adding, while maintaining a reaction solution containing the isothiuronium salt thus obtained at a temperature of 15°C to 60°C, aqueous ammonia to the reaction solution within 80 minutes, thereby hydrolyzing the isothiuronium salt to obtain a polythiol compound represented by the following formula (5) ; and a step for adding hydrochloric acid which is a concentration of 25% to 36% to the solution containing the polythiol compound thus obtained, washing the solution at a temperature of 10°C to 50°C to purify the polythiol compound.