53561-17-4Relevant articles and documents
Oxime ether containing active group and synthesis method thereof
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Paragraph 0049-0053; 0060-0062, (2020/01/04)
The invention relates to the technical field of organic matter synthesis, in particular to oxime ether containing an active group and a synthesis method thereof, and the oxime ether has a structure asshown in a general formula (I) which is described in th
Synthesis of ketone O-allyloximes and O-propargyloximes in KOH-DMSO system
Tarasova,Shmidt,Sinegovskaya,Petrova,Sobenina,Mikhaleva,Brandsma,Trofimov
, p. 1581 - 1586 (2007/10/03)
In reaction of ketone oximes with allyl bromide and propargyl chloride in KOH - DMSO system were obtained in good yield previously unknown ketone O-allyloximes and O-propargyloximes. The reactions are accompanied with minor regeneration of ketones (up to 12%, mainly 1-5%).
O-ALLYL ETHER AS A NEW PROTECTIVE GROUP FOR OXIMES AND ITS PALLADIUM-CATALYZED DEPROTECTION.
Yamada, Toshiro,Goto, Kuniaki,Mitsuda, Yasuhiro,Tsuji, Jiro
, p. 4557 - 4560 (2007/10/02)
Oximes are protected by O-allyl ether formation, and their palladium-catalyzed deallylation using triethylammonium formate as a reductant proceeds smoothly in boiling ethanol under mild conditions offering a good protective method for oximes.