53834-50-7

Basic information

• Product Name: (Z)-1,2-dichloro-3-phenyl-2-propene
• Synonyms: (Z)-1,2-dichloro-3-phenyl-2-propene
• CAS NO: 53834-50-7
• Molecular Weight: 187.069
• Mol File: 53834-50-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (Z)-1,2-dichloro-3-phenyl-2-propene(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1,2-dichloro-3-phenyl-2-propene(53834-50-7)
• EPA Substance Registry System: (Z)-1,2-dichloro-3-phenyl-2-propene(53834-50-7)

Safety Data

• Hazardous Substances Data: 53834-50-7(Hazardous Substances Data)

Upstream product

• 2327-99-3 1-phenylpropadiene 
• 53783-57-6 2-chloro-3-phenyl-2-propen-1-ol 

Downstream Products

• 2327-99-3 1-phenylpropadiene 
• 13099-50-8 2-methyl-1-phenyl-1-propene, β,β-dimethylstyrene 
• 131342-46-6 <3-(diethoxyphosphinyloxy)-3-phenylallyl>trimethylammonium chloride 
• 673-32-5 1-Phenylprop-1-yne 
• 79-14-1 glycolic Acid 
• 100-52-7 benzaldehyde 
• 65-85-0 benzoic acid 

Relevant articles and documents

Selectfluor-mediated mild oxidative halogenation and thiocyanation of 1-aryl-allenes with TMSX (X = Cl, Br, I, NCS) and NH4SCN

Presence of TMSX (X = Cl, Br, I) unleashes the oxidative character of Selectfluor and provides a mild dihalogenation method for 1-arylallenes. Preference for 2,3-addition was observed with TMSCl in MeCN irrespective of the nature of the substituent on the aryl moiety, whereas 1,2-addition was preferred in [BMIM][BF4]. With TMSBr and TMSI only products corresponding to 2,3-addition were observed. Reactions carried out with TMSBr in IL solvents gave the corresponding monobromoalkenes as a major product along with the isomeric dibromo-alkenes. Reaction with NH4SCN provided convenient access to dithiocyanate derivatives. The same products were formed via TMS-NCS/Selectfluor. Formation of common products via TMSNCS and NH 4SCN points to the formation and interplay of SCN+/ NCS+ as incipient electrophiles.