542-58-5

Basic information

• Product Name: ACETIC ACID 2-CHLOROETHYL ESTER
• Synonyms: ACETIC ACID 2-CHLOROETHYL ESTER;2-CHLOROETHYL ACETATE;1-Acetoxy-2-chloroethane;2-Acetoxy-1-chloroethane;2-Acetoxyethyl chloride;2-Chlorethylacetat;2-chloro-ethanoacetate;2-Chloroethanol acetate
• CAS NO: 542-58-5
• Molecular Formula: C₄H₇ClO₂
• Molecular Weight: 122.55
• EINECS: 208-820-2
• Mol File: 542-58-5.mol
• Article Data: 29

Chemical Properties

• Boiling Point: 145°C
• Flash Point: 54°C
• Appearance: /
• Density: 1,16 g/cm3
• Vapor Pressure: 4.77mmHg at 25°C
• Refractive Index: 1.4220-1.4250
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility: Insoluble in water
• CAS DataBase Reference: ACETIC ACID 2-CHLOROETHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETIC ACID 2-CHLOROETHYL ESTER(542-58-5)
• EPA Substance Registry System: ACETIC ACID 2-CHLOROETHYL ESTER(542-58-5)

Safety Data

• Hazard Codes: T+
• Statements: 10-23/24/25-26/27/28
• Safety Statements: 26-36/37/39-45-36/37-28
• RIDADR: 2929
• RTECS: KK1010000
• HazardClass: 6.1/3
• PackingGroup: II
• Hazardous Substances Data: 542-58-5(Hazardous Substances Data)

Usage

Uses

Gasoline additive, Henderson, US 3179506 (1965 to Shell).

InChI:InChI=1/C4H7ClO2/c1-4(6)7-3-2-5/h2-3H2,1H3

Upstream product

• 75-21-8 oxirane 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 
• 107-07-3 2-chloro-ethanol 
• 107-21-1 ethylene glycol 
• 64-19-7 acetic acid 
• 2916-31-6 2,2-dimethyl-1,3-dioxolane 
• 31247-24-2 1-Chloro-5,8-dioxa-2-thia-spiro[3.4]octane 2,2-dioxide 
• 497-26-7 2-methyl-1,3-dioxolane 
• 87334-60-9 3,3,7,7-tetrachlorotricyclo<4.1.0.0^2,4>heptane 
• 177-10-6 1,3-dioxolane-2-spirocyclohexane 
• 75-77-4 chloro-trimethyl-silane 
• 3674-77-9 2-methyl-2-phenyl-1,3-dioxolane 
• 127-08-2 potassium acetate 

Downstream Products

• 87-23-0 1-acetoxy-2-salicyloyloxy-ethane 
• 75-21-8 oxirane 
• 75-01-4 chloroethylene 
• 64-19-7 acetic acid 
• 1064-74-0 1,2-bis(triphenylphosphonio)ethane dichloride 
• 181824-35-1 2-(2-acetoxyethoxy)-4-methoxybenzaldehyde 
• 119844-66-5 (S)-5-methylmorpholin-3-one 
• 119844-67-6 (5R)-5-methylmorpholin-3-one 
• 82231-59-2 ethyl 2-(4-iodo-1H-pyrazol-1-yl)acetate 
• 1385073-61-9 diethyl 4-(4-(2-ethoxy-2-oxoethoxy)phenyl)-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate 
• 1210311-61-7 C₁₅H₁₅N₅O₃S 
• 1210311-60-6 C₁₅H₁₅N₅O₃ 
• 1210311-46-8 4-(2-acetoxyethyl)-6-phenyl-1,2,4-triazolo[3,2-c][1,2,4]triazin-7-one 

Relevant articles and documents

A potential “green” organotin: Bis-(methylthiopropyl)tin dichloride, [MeS (CH2)3]2SnCl2

The tetravalent organotin compound [MeS(CH2)3]2SnCl2, 1, has been synthesized in high yield and structurally characterized as being hexa-coordinate at tin with two intramolecular Sn-S bonds. The specific structure has been shown by theoretical calculations to be the low energy geometric structure available, and the differences associated with the experimental and calculated Sn-S bond lengths ascribed to crystal packing issues. The intramolecular Sn-S bonding produces a benign organotin compound with respect to its interactions with human natural killer cells; however, this blocking of coordination sites at Sn does not reduce its capacity to act as an efficient esterification catalyst.

Chemoselective palladium-catalyzed oxidation of vinyl ether to acetate using hydrogen peroxide

A practical and environmental-friendly method was developed to convert vinyl ether into acetate by using a palladium complex with phosphine ligand and hydrogen peroxide. The only by-product is water. Chemoselective oxidation of vinyl ether and tert-enamides to form acetate and N-acetyl amide with hydrogen peroxide in the presence of palladium complex having phosphine ligand was developed under mild reaction conditions. This process is environmentally friendly because it uses hydrogen peroxide as a clean oxidant, with water being the only byprocuct.

Synthesis of acyloxyalkyl esters of thiocarbonic and dithiocarbamic acids

Reactions of acyloxyalkyl chloride with alkaline salts of alkylxanthic, butyltrithiocarbonic, and diethyldithiocarbamic acids afforded a series of acyloxyalkyl esters of various nature and positions of the acyl groups in the molecule.