544-00-3

Basic information

• Product Name: DIISOAMYLAMINE
• Synonyms: 1-Butanamine, 3-methyl-N-(3-methylbutyl)-;1-Butanamine,3-methyl-N-(3-methylbutyl)-;3-methyl-n-(3-methylbutyl)-1-butanamin;Bis(3-methylbutyl)amine;di(3-methyl-1-butyl)amine;Di(3-Methylbutyl)amine;N-(3-Methylbutyl)-3-methyl-1-butanamine;N-Isopentyl-3-methyl-1-butanamine
• CAS NO: 544-00-3
• Molecular Formula: C₁₀H₂₃N
• Molecular Weight: 157.3
• EINECS: 208-856-9
• Mol File: 544-00-3.mol
• Article Data: 5

Chemical Properties

• Melting Point: -44°C
• Boiling Point: 187-188°C
• Flash Point: 58°C
• Appearance: /
• Density: 0,767 g/cm3
• Vapor Pressure: 0.613mmHg at 25°C
• Refractive Index: 1.4230
• PKA: 11.10±0.19(Predicted)
• Water Solubility: Soluble in ethanol, ethyl ether and chloroform. Slightly soluble in water.
• Merck: 14,3193
• BRN: 1719663
• CAS DataBase Reference: DIISOAMYLAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: DIISOAMYLAMINE(544-00-3)
• EPA Substance Registry System: DIISOAMYLAMINE(544-00-3)

Safety Data

• Statements: 34
• Safety Statements: 26-36/37/39-45
• RIDADR: 2734
• TSCA: Yes
• HazardClass: 3
• PackingGroup: II
• Hazardous Substances Data: 544-00-3(Hazardous Substances Data)

Usage

Uses

Intermediate for organic synthesis

InChI:InChI=1/C10H23N/c1-9(2)5-7-11-8-6-10(3)4/h9-11H,5-8H2,1-4H3

Upstream product

• 123-51-3 i-Amyl alcohol 
• 107-82-4 i-pentyl bromide 
• 7664-41-7 ammonia 
• 110-46-3 isopentyl nitrite 
• 20615-02-5 bis-(3-methyl-butylidene)-hydrazine 
• 107-84-6 1-chloro-3-methylbutane 
• 590-86-3 isovaleraldehyde 
• 625-28-5 Isovaleronitrile 
• 107-85-7 1-amino-3-methylbutane 
• 64-17-5 ethanol 
• 141-78-6 ethyl acetate 
• 590-28-3 potassium cyanate 
• 7647-01-0 hydrogenchloride 
• 69366-98-9 diisopentyl-carbamonitrile 

Downstream Products

• 645-41-0 triisoamylamine 
• 625-28-5 Isovaleronitrile 
• 28023-74-7 diisopentyl-nitroso-amine 
• 56438-21-2 N,N-diisopentyl-N'-phenyl-thiourea 
• 2765-31-3 N,N-Diisopentylglycinethylester 

Relevant articles and documents

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Conversion of Primary Amines to Symmetrical Secondary and Tertiary Amines using a Co-Rh Heterobimetallic Nanocatalyst

Symmetrical tertiary amines have been efficiently realized from amine and secondary amines via deaminated homocoupling with heterogeneous bimetallic Co2Rh2/C as catalyst (molar ratio Co:Rh=2:2). Unsymmetric secondary anilines were produced from the reaction of anilines with symmetric tertiary amines. The Co2Rh2/C catalyst exhibited very high catalytic activity towards a wide range of amines and could be conveniently recycled ten times without considerable leaching. (Figure presented.).

A method of manufacturing a tertiary amine

PROBLEM TO BE SOLVED: To provide a method for producing a tertiary amine selectively with a high yield by a reductive amination reaction in a batch system. SOLUTION: In this method for producing the tertiary amine, an aldehyde expressed by formula R-CHO (in the formula, R shows a 2-20C aliphatic hydrocarbon group, 3-20C alicyclic hydrocarbon group or 6-20C aromatic hydrocarbon group), ammonia and hydrogen are reacted together in a batch system in the presence of a hydrogenation catalyst, to thereby produce the tertiary amine expressed by formula (R-CH2)3N (in the formula, R is defined above), wherein a palladium catalyst is used as the hydrogenation catalyst, and the reaction is performed under the condition of a hydrogen pressure of 0.1-6.5 MPa. COPYRIGHT: (C)2012,JPOandINPIT