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5447-97-2

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5447-97-2 Usage

Chemical Properties

clear colorless to pale yellow liquid

Check Digit Verification of cas no

The CAS Registry Mumber 5447-97-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,4,4 and 7 respectively; the second part has 2 digits, 9 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 5447-97:
(6*5)+(5*4)+(4*4)+(3*7)+(2*9)+(1*7)=112
112 % 10 = 2
So 5447-97-2 is a valid CAS Registry Number.
InChI:InChI=1/C3H6BrNO2/c1-3(2,4)5(6)7/h1-2H3

5447-97-2 Well-known Company Product Price

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  • Alfa Aesar

  • (A18385)  2-Bromo-2-nitropropane, 98%   

  • 5447-97-2

  • 5g

  • 326.0CNY

  • Detail
  • Alfa Aesar

  • (A18385)  2-Bromo-2-nitropropane, 98%   

  • 5447-97-2

  • 25g

  • 991.0CNY

  • Detail
  • Aldrich

  • (B74305)  2-Bromo-2-nitropropane  97%

  • 5447-97-2

  • B74305-25G

  • 1,067.04CNY

  • Detail

5447-97-2SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 19, 2017

Revision Date: Aug 19, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-BROMO-2-NITROPROPANE

1.2 Other means of identification

Product number -
Other names sNxhEVLQIijiP@

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5447-97-2 SDS

5447-97-2Relevant articles and documents

Electrooxidative coupling of salts of nitro compounds with halide, nitrite, cyanide, and phenylsulfinate anions

Ilovaisky,Merkulova,Ogibin,Nikishin

, p. 1585 - 1592 (2007/10/03)

Electrolysis of salts of primary and secondary nitro compounds (nitroethane, 1- and 2-nitropropanes, nitrocyclohexane, and nitrocycloheptane) in the presence of excess halide, nitrite, cyanide, and phenylsulfinate anions under undivided and divided amperostatic electrolysis conditions in a two-phase medium (CH2Cl2/H2O) produces geminal nitrohalides (35-85% yields), dinitro compounds (15-51%), nitronitriles (6-27%), and nitrosulfones (50-70%). The salts of secondary nitro compounds form the products of oxidative coupling with halide and phenylsulfinate anions under the undivided electrolysis conditions. In all other cases, divided electrolysis is required.

Reactions of 1-Aryl-1,2-dibromo-2-nitropropanes with 2-Nitro-2-propyl Anion in DMSO

Cho, Bong Rae,Suh, Young Sung,Lee, Seung Jae,Cho, Eun Jeong

, p. 3681 - 3682 (2007/10/02)

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Polynitro-Substituted Strained-Ring Compounds. Synthesis, Mechanism of Formation, and Structure of trans-Dinitrocyclopropanes

Wade, Peter A.,Dailey, William P.,Carroll, Patrick J.

, p. 5452 - 5456 (2007/10/02)

1,2-Dinitrocyclopropane, 1,2-dimethyl-1,2-dinitrocyclopropane, and 1,2-diethyl-1,2-dinitrocyclopropane have been prepared in 23-36percent yield by oxidative cyclization of the corresponding open-chain 1,3-dinitronate dianions with iodide in DMSO.In each case only the trans isomer of the dinitrocyclopropane was obtained.Treatment of 2,4-dibromo-2,4-dinitropentane with the lithium salt of 2-nitropropane gave trans-1,2-dimethyl-1,2-dinitrocyclopropane, suggesting the intermediacy of a halonitro nitronate intermediate in the oxidative cyclization process.Further mechanistic studies using m-dinitrobenzene suggest either an internal single-electron transfer, nonchain pathway or an internal SN2 process leading to the dinitrocyclopropanes.An X-ray crystallographic study performed on trans-1,2-dinitrocyclopropane indicates substantially shortened distal C-C bonds (1.47 Angstroem) and bisected conformations for each nitro group.Ab initio calculations using a 4-31G basis set are in agreement with the X-ray data, except longer distal C-C bonds (1.49 Angstroem) are calculated.Ab initio calculations using a variety of basis sets were performed on nitrocyclopropane as a model.

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