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5469-44-3

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5469-44-3 Usage

General Description

The chemical compound "(2E)-N-{2-[(2E)-2-(furan-2-ylmethylidene)hydrazino]-2-oxoethyl}-3-phenylprop-2-enamide (non-preferred name)" is a synthetic organic compound with a molecular formula C19H16N4O3. It is a hydrazide derivative containing a furan ring and a phenylprop-2-enamide moiety. (2E)-N-{2-[(2E)-2-(furan-2-ylmethylidene)hydrazino]-2-oxoethyl}-3-phenylprop-2-enamide (non-preferred name) may have potential applications in medicinal and pharmaceutical research due to its structural features and potential biological activities. However, further research and testing are needed to determine its exact properties and potential uses.

Check Digit Verification of cas no

The CAS Registry Mumber 5469-44-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,4,6 and 9 respectively; the second part has 2 digits, 4 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 5469-44:
(6*5)+(5*4)+(4*6)+(3*9)+(2*4)+(1*4)=113
113 % 10 = 3
So 5469-44-3 is a valid CAS Registry Number.

5469-44-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-benzyl-2-methyl-4H-oxazol-5-one

1.2 Other means of identification

Product number -
Other names 4-Benzyl-2-methyl-4H-oxazol-5-on

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5469-44-3 SDS

5469-44-3Relevant articles and documents

The Enantioselective Dakin-West Reaction

Wende, Raffael C.,Seitz, Alexander,Niedek, Dominik,Schuler, S?ren M. M.,Hofmann, Christine,Becker, Jonathan,Schreiner, Peter R.

supporting information, p. 2719 - 2723 (2016/02/27)

Here we report the development of the first enantioselective Dakin-West reaction, yielding α-acetamido methylketones with up to 58 % ee with good yields. Two of the obtained products were recrystallized once to achieve up to 84 % ee. The employed methylimidazole-containing oligopeptides catalyze both the acetylation of the azlactone intermediate and the terminal enantioselective decarboxylative protonation. We propose a dispersion-controlled reaction path that determines the asymmetric reprotonation of the intermediate enolate after the decarboxylation.

Diastereochemical diversity of imidazoline scaffolds via substrate controlled TMSCI mediated cycloaddition of azlactones

Sharma, Vasudha,Tepe, Jetze J.

, p. 5091 - 5094 (2007/10/03)

(Chemical Equation Presented) We report herein a trimethylsilyl chloride mediated substrate controlled 1,3-dipolar cycloaddition for the diastereoselective synthesis of either syn- or anti-imidazolines. This method provides scaffolds with four points of diversity and control over two stereocenters.

ASYMMETRIC SYNTHESIS OF AMINO ACIDS VIA THE CATALYTIC REDUCTION OF SUBSTITUTED ACYLAMINOACRYLIC ACID AZLACTONE DERIVATIVES. 25. REDUCTIVE AMINOLYSIS OF 2-PHENYL- AND 2-METHYL-Δ2-OXAZOLIN-5-ONES UPON TREATMENT WITH A CHIRAL PdCl2-R-PHENYLGLYCINE

Chel'tsova, G. V.,Karpeiskaya, E. I.,Klabunovskii, E. I.

, p. 727 - 731 (2007/10/02)

We have studied the reaction of Δ2-oxazolin-5-ones with R-phenylglycine methyl ester in the presence of PdCl2; the reaction gives phenylalanine or valine dipeptide derivatives with the RS-configuration.The presence of triethylamine during the r

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