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5558-08-7

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5558-08-7 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 5558-08-7 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 5,5,5 and 8 respectively; the second part has 2 digits, 0 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 5558-08:
(6*5)+(5*5)+(4*5)+(3*8)+(2*0)+(1*8)=107
107 % 10 = 7
So 5558-08-7 is a valid CAS Registry Number.

5558-08-7SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name α-(Cyclopropyl)benzyl methyl ether

1.2 Other means of identification

Product number -
Other names Phenyl-cyclopropyl-carbinolmethylether

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:5558-08-7 SDS

5558-08-7Relevant articles and documents

Iron-catalyzed π-activated C-O ether bond cleavage with C-C and C-H bond formation

Fan, Xiaohui,Cui, Xiao-Meng,Guan, Yong-Hong,Fu, Lin-An,Lv, Hao,Guo, Kun,Zhu, Hong-Bo

supporting information, p. 498 - 501 (2014/02/14)

A novel and efficient allylic alkylation reaction between π-activated ethers and allylsilane was realized under mild conditions through iron(III)-catalyzed C sp 3-O ether bond cleavage. The present protocol provides an attractive approach for the construction of sp3-sp3 C-C bonds and can be potentially applied for the selective reduction of benzyl and allyl ethers to their corresponding hydrocarbon compounds by using triethylsilane as a hydride-transfer reagent. A mild, economical, and environmentally friendly method for the construction of C sp 3-C sp 3 bonds through iron-catalyzed π-activated C-O ether bond cleavage is developed. In addition, this catalytic system can be used for the selective reduction of benzylic and allylic C-O ether bonds to C-H bonds. Copyright

Iron-catalyzed N-alkylation using π-activated ethers as electrophiles

Fan, Xiaohui,Fu, Lin-An,Li, Na,Lv, Hao,Cui, Xiao-Meng,Qi, Yuan

supporting information, p. 2147 - 2153 (2013/04/10)

A new method for the synthesis of diverse N-alkylation compounds was developed via an iron-catalyzed etheric Csp3-O cleavage with the C-N bond formation in the reaction of π-activated ethers with various nitrogen-based nucleophiles. In addition, the mechanism of this reaction was investigated. The Royal Society of Chemistry 2013.

1,2-Hydrogen migration and alkene formation in the photoexcited states of alkylphenyldiazomethanes

?elebi, Sol,Leyva, Soccoro,Modarelli, David A.,Platz, Matthew S.

, p. 8613 - 8620 (2007/10/02)

Laser flash photolysis of alkylphenyldiazomethanes in the presence of pyridine produces easily detected ylides. The data indicate that photolysis of alkylphenyldiazomethanes leads to both carbene formation and direct formation of rearrangement products which do not derive from relaxed carbene intermediates.

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