5558-08-7Relevant articles and documents
Iron-catalyzed π-activated C-O ether bond cleavage with C-C and C-H bond formation
Fan, Xiaohui,Cui, Xiao-Meng,Guan, Yong-Hong,Fu, Lin-An,Lv, Hao,Guo, Kun,Zhu, Hong-Bo
supporting information, p. 498 - 501 (2014/02/14)
A novel and efficient allylic alkylation reaction between π-activated ethers and allylsilane was realized under mild conditions through iron(III)-catalyzed C sp 3-O ether bond cleavage. The present protocol provides an attractive approach for the construction of sp3-sp3 C-C bonds and can be potentially applied for the selective reduction of benzyl and allyl ethers to their corresponding hydrocarbon compounds by using triethylsilane as a hydride-transfer reagent. A mild, economical, and environmentally friendly method for the construction of C sp 3-C sp 3 bonds through iron-catalyzed π-activated C-O ether bond cleavage is developed. In addition, this catalytic system can be used for the selective reduction of benzylic and allylic C-O ether bonds to C-H bonds. Copyright
Iron-catalyzed N-alkylation using π-activated ethers as electrophiles
Fan, Xiaohui,Fu, Lin-An,Li, Na,Lv, Hao,Cui, Xiao-Meng,Qi, Yuan
supporting information, p. 2147 - 2153 (2013/04/10)
A new method for the synthesis of diverse N-alkylation compounds was developed via an iron-catalyzed etheric Csp3-O cleavage with the C-N bond formation in the reaction of π-activated ethers with various nitrogen-based nucleophiles. In addition, the mechanism of this reaction was investigated. The Royal Society of Chemistry 2013.
1,2-Hydrogen migration and alkene formation in the photoexcited states of alkylphenyldiazomethanes
?elebi, Sol,Leyva, Soccoro,Modarelli, David A.,Platz, Matthew S.
, p. 8613 - 8620 (2007/10/02)
Laser flash photolysis of alkylphenyldiazomethanes in the presence of pyridine produces easily detected ylides. The data indicate that photolysis of alkylphenyldiazomethanes leads to both carbene formation and direct formation of rearrangement products which do not derive from relaxed carbene intermediates.