56158-15-7

Basic information

• Product Name: (±)-((4-chlorophenyl)imino)(methyl)(phenyl)-λ⁶-sulfanone
• Synonyms: (±)-((4-chlorophenyl)imino)(methyl)(phenyl)-λ⁶-sulfanone
• CAS NO: 56158-15-7
• Molecular Weight: 265.763
• Mol File: 56158-15-7.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: (±)-((4-chlorophenyl)imino)(methyl)(phenyl)-λ⁶-sulfanone(CAS DataBase Reference)
• NIST Chemistry Reference: (±)-((4-chlorophenyl)imino)(methyl)(phenyl)-λ⁶-sulfanone(56158-15-7)
• EPA Substance Registry System: (±)-((4-chlorophenyl)imino)(methyl)(phenyl)-λ⁶-sulfanone(56158-15-7)

Safety Data

• Hazardous Substances Data: 56158-15-7(Hazardous Substances Data)

Upstream product

• 1073-70-7 4-chlorophenylhydrazine hydrochloride 
• 4381-25-3 S-methyl-S-phenylsulfoximine 
• 1679-18-1 4-Chlorophenylboronic acid 
• 35692-30-9 (4-chlorophenyl)trimethoxysilane 
• 917-54-4 methyllithium 
• 83706-28-9 N-(4-Chlorophenyl)benzenesulfonimidoyl Fluoride 
• 14934-02-2 N-(4-Chlorophenyl)benzenesulfinamide 
• 69726-88-1 (±)-N-(4-chlorophenyl)methanesulfinamide 

Relevant articles and documents

Cu(OAc)2-catalyzed N-arylations of sulfoximines with aryl boronic acids

(Chemical Equation Presented) A simple and mild copper salt-catalyzed N-arylation of sulfoximines in high yields is reported. Cu(OAc)2 activates aryl boronic acids for the reaction with NH-sulfoximines without additional base or heating. Furthe

Copper-Catalyzed N -Arylation of Sulfoximines with Arylboronic Acids under Mild Conditions

N -Arylation of sulfoximines with different arylboronic acids, including sterically hindered boronic acids, is achieved using copper(I) iodide and 4-DMAP at room temperature. Moreover, N -arylation of biologically relevant l -methionine sulfoximine is demonstrated for the first time. All these reactions provided the desired products in excellent yields within a short span of time. The optimized reaction conditions are well suited to the task of N -vinylation of sulfoximine with trans -2-phenylvinylboronic acid.

N-Arylated Sulfoximines as Cross-Coupling Building Blocks

The application of borylated N-aryl sulfoximines as newly designed synthetic building blocks in Suzuki-type cross coupling reactions offers rapid access to a wide range of N-biaryl derivatives with potential relevance for medicinal chemistry and crop protection in good to excellent yields (up to 98%). (Figure presented.).